Classification of Matter and Solutions Notes Part 1 I. Classification of Matter Yes Matter Can it be physically separated? Mixtures Is the composition uniform? Yes Homogeneous Mixtures (Solutions) (air, sugar water, salt water) No Heterogeneous Mixtures (Suspensions or Colliods) (granite, wood, muddy water) No Pure Substances Can it be decomposed by an ordinary chemical reaction? Yes No Compounds Elements (water, sodium chloride, sucrose) (gold, oxygen, carbon) Mixtures: matter that can be physically separated into component parts. a. homogeneous mixture –has uniform composition; also called a solution b. heterogeneous mixture – does not have a uniform composition; suspensions or colloids Pure Substances: when component parts of a mixture can no longer be physically separated into simpler substances. Pure substances are either compounds or elements. a. Compounds – can be decomposed by a chemical change. b. Elements – cannot be decomposed by a chemical change. II. Types of Mixtures (Solutions, Suspensions, and Colloids) Table 13-3 page 398 1. Solution (homogeneous mixture)- any substance (solid, liquid, gas) that is evenly dispersed throughout another substance. Ex: sugar water, salt water (do not scatter light) Components of a Solution 1. Solute – substance dissolved 2. Solvent – substance that does the dissolving (water is the universal solvent) 2. Suspensions (heterogeneous mixtures) – particles in a solvent are so large that they settle out unless the mixture is constantly stirred Ex: muddy water, vegetable soup, page 398 (may scatter light, but are transparent) 3. Colloids (heterogeneous mixtures) – particles are intermediate in size between those in solutions and suspensions. Example: After large soil particles settle out of muddy water the water is often still cloudy because colloidal particles remain dispersed in the water. Ex: milk, mayonnaise , page 398 (do scatter light – Tyndall Effect) III. The Solution Process (Solvation) Solvation is the process by which a solute dissolves in a solvent. Miscible: when solutes and solvents are soluble in each other (solvation occurs) Immiscible: when solutes and solvents are not soluble in each other (solvation does not occur) Aqueous solutions – solvent is water. IV. Like Dissolves Like We don’t always use water as the solvent! Solutions can be made from various substances – a rule of thumb to follow when trying to determine if two substances will form a solution is “like dissolves like.” Solubility: the maximum amount of a substance that will dissolve in a solvent (at a specific temperature) According to solubility, solutions can be either: unsaturated – a solution that is able to dissolve more solute (not enough) saturated – a solution that cannot dissolve any more solute (just enough) supersaturated – a solution that contains more solute than can be dissolved (too much!!) The solubility of substances varies widely. For example 0.189 grams of Ca(OH)2 dissolves in 100 grams of water at 0C. 122 grams of AgNO3 dissolves in 100 grams of water at 0C. (page 404 in your book) VI. Factors Effecting Rate and Solubility A. Factors Effecting Rate: 1. Agitation – stirring or mixing the solution will increase the rate or how fast the solute dissolves, but it will not change how much solute can be dissolved. If you add 35.9 grams of salt to water (at 20C) it will all eventually dissolve, but if you stir the solution it will dissolve much quicker. (As you stir the particles are constantly being moved, allowing for interactions between solute and solvent to occur more quickly.) 2. Surface Area – increasing the surface area of the solute will increase the rate or how fast the solute dissolves, but it will not change how much solute can be dissolved. 3. Temperature – increasing temperature will increase the rate or how fast the solute dissolves in the solvent. (As temperature increases the particles begin to move faster and faster and collide with more particles quicker, which means the solute and solvent particles have an increased chance of coming into contact with each other.) B. Factors Effecting Solubility: 1. Increasing Temperature - solubility of a solid solute in a liquid solvent generally increases with an increase in temperature. At 20C 35.9 grams of salt will dissolve in 100 grams of water, but at 100 C 39.2 grams of salt will dissolve in 100 grams of water! 2. Decreasing Temperatureincreases the solubility of a gaseous solute in a liquid solvent. What would you rather drink, a hot coke or a cold coke? 3. Pressure – The solubility of a gas increases as the pressure of the gas above the liquid increases. Carbonated drinks have CO2 dissolved in them. They are also bottled under a high pressure of CO2, which forces the CO2 into solution. When the bottle is opened, the pressure above the solution decreases, and bubbles of CO2 form in the liquid, then escape. Eventually, most of the CO2 escapes and the drink becomes “flat.” Henry’s Law- “At a given temperature, the solubility, S, of a gas in a liquid is directly proportional to the pressure, P, of the gas above the liquid.” S1 = S2 P1 P2 VII. Electrolyte VS Nonelectrolyte 1. Electrolyte – compounds that conduct an electric current in an aqueous solution OR in the molten state. An electrolyte solution contains charged particles (ions), which can move. Any salt dissolved in water is an electrolyte: NaCl, KI, etc. Some polar molecules also conduct electricity (most acids are electrolytes because H is the only nonmetal that has a + charge). Types of Electrolytes 1. Strong electrolytes – a large portion of the solute exists as ions: a. aqueous solutions of all ionic compounds b. strong acids: have at least 2 oxygens per hydrogen (H2SO4, HNO3) c. strong bases – these are hydroxides from Group I and II, except Be. (NaOH, CsOH, etc) 2. Weak electrolytes – these are solutions in which only a small portion of the solute exists as ions a. weak acids: -all binary acids – HF, H2S, etc -weak acids that have less than 2 oxygen's per hydrogen b. weak bases – hydroxides of everything else not in Group I or II, including Be(OH)2 2. Non-Electrolytes- compounds that do NOT conduct electricity in either aqueous solution or when melted: distilled water gases molecular compounds (2 nonmetals) organic compounds – alcohols, sugars, etc. anything containing a Carbon Practice Problems: Tell whether each of the following aqueous solutions would be a STRONG, WEAK, or NON electrolyte. 1. NaCl 2. CH3Br (l) 3. HMnO4 4. HC2H3O2 5. LiOH 6. HC6H7O6 7. CO2 (l) 8. HF VIII. Concentration: the concentration of a solution is a measure of the amount of solute in a given amount of solvent or solution.