ASSESSING THE FEASIBILITY OF WASTEWATER REUSE FOR A CARBON SEQUESTRATION FOREST IN DAVIS, CA A Project Presented to the faculty of the Department of Civil Engineering California State University, Sacramento Submitted in partial satisfaction of the requirements for the degree of MASTER OF SCIENCE in Civil Engineering (Environmental Engineering) by Heta Shah FALL 2013 © 2013 Heta Shah ALL RIGHTS RESERVED ii ASSESSING THE FEASIBILITY OF WASTEWATER REUSE FOR A CARBON SEQUESTRATION FOREST IN DAVIS, CA A Project by Heta Shah Approved by: __________________________________, Committee Chair John Johnston, Ph.D., P.E. __________________________________, Second Reader Ed Dammel, Ph.D. __________________________ Date iii Student: Heta Shah I certify that this student has met the requirements for format contained in the University format manual, and that this project is suitable for shelving in the Library and credit is to be awarded for the project. __________________________, Graduate Coordinator Matthew Salveson, P.E. Department of Civil Engineering iv ___________________ Date Abstract of ASSESSING THE FEASIBILITY OF WASTEWATER REUSE FOR A CARBON SEQUESTRATION FOREST IN DAVIS, CA by Heta Shah The National Pollutant Discharge Elimination System (NPDES) permit for the City of Davis was renewed in 2007with strict effluent quality requirements. These permit requirements prompted a plan to upgrade the city’s existing wastewater system to tertiary treatment. The city government is also working to meet greenhouse gas emission reduction goals. This project is a feasibility study of using treated municipal wastewater to irrigate long- lived trees on a city-owned 770-acre site to incorporate carbon from atmospheric carbon dioxide (CO2) into biomass. The major components of this study are: choosing a crop based on the amount of carbon it can sequester per year and its climate and water quality requirements; determining the degree of wastewater treatment needed under California law for this application; performing a water balance based on the irrigation requirements of the tree crop and potential threats to groundwater such as nitrogen or salinity loading; and determining the mass of carbon that can be sequestered annually by this facility. Based on the preliminary analysis contained herein, up to 569 acres of redwood trees could be irrigated with the city’s wastewater flow. A forest of this size would capture 2236 Metric v Tons annually, which would more than offset the city’s CO2 emissions associated with its water and wastewater utilities. _______________________________, Committee Chair John Johnston, Ph.D., P.E. _______________________ Date vi ACKNOWLEDGEMENTS The author would like to thank Dr. John Johnston, Dr. Ed Dammel and Dr. Ken Shackel for their support, input, guidance and review of this project. Lastly, the author would like to thank her family for their support throughout the program. vii TABLE OF CONTENTS Acknowledgements………………………………………………………................ vii List of Tables………………………………………………………………………...x List of Figures……………………………………………………………………….xiii Chapter 1. INTRODUCTION…………………………………………………………......... 1 2. BACKGROUND………………………………………………………………... 4 Carbon Sequestration…………………………………………………………... 4 Forest-Based Carbon Sequestration……………………………………………. 6 Irrigating Forest with Reclaimed Wastewater…………………………………. 12 City of Davis Wastewater Treatment Plant and Wetlands……………………...17 Future Reuse Opportunities……………………………………………………. 27 3. PROJECT CALCULATIONS...............................................................................31 Slow Rate (SR) Forest Treatment……………………………………………… 31 Site Characteristics and Climate………………………………………………...32 Carbon Sequestration Plan……………………………………………………... 36 Water Balance and Storage Requirement……………………………………… 47 Agro-Forestry Management Plan……………………………………………..... 78 4. DISCUSSION…………………………………………………………………… 80 Potential Benefits………………………………………………………………. 80 Uncertainties…………………………………………………………………….83 Unsettled Questions……………………………………………………………. 85 viii 5. CONCLUSION………………………………………………………………….. 86 References………………………………………………………………………….. 88 ix LIST OF TABLES Tables Page 2.1 List of Available Carbon Accounting Tools…………………………………. 11 2.2 Forested Slow Rate Treatment Systems in the United States……………….. 13 2.3 Water Recycling Types and its Criteria……………………………………… 15 2.4 Approved Recycled Water Treatment and Uses……………………………... 16 2.5 Summary of Davis WPCP Secondary Treatment Ponds…………………….. 20 2.6 Average Annual WPCP Influent Flow Statistics for 2000-2004…………….. 21 2.7 WPCP Average Influent Water Quality Characteristics……………………... 22 2.8 Summary of 2007 NPDES Permit at Discharge Location-Willow Slough Bypass…………………………………………………………………………23 2.9 Summary of Disposal/Reuse Alternatives Evaluate…………………………..28 3.1 Soil Type Classification of Study Area in Davis, California………………….35 3.2 Site Characteristics of Study Area in Davis, California……………………….35 3.3 List of Native Trees in the Area……………………………………………….37 3.4 Characteristics of Trees Selected for the Agro-Forestry Plan…………………38 3.5 Categorical Variables Available in COLE-EZ for the Filtering Analysis………………………………………………………………………..40 3.6 Cumulative Carbon Storage in Different Pools (in Metric Tons of Carbon per Tree) Generated using COLE-EZ for Douglas fir………………...42 3.7 Cumulative Carbon Storage in Different Pools (in Metric Tons of Carbon per Tree) Generated using COLE-EZ for Ponderosa pine…………….43 3.8 Cumulative Carbon Storage in Different Pools (in Metric Tons of Carbon per Tree) Generated using COLE-EZ for Redwood………………….44 3.9 Determination of Harvesting Age of each Selected Trees……………………..46 3.10 Average Monthly Pan Evapotranspiration, ETo in Inches for City of Davis………………………………………………………………………...50 3.11 Average Monthly Precipitation, Pr in Inches for City of Davis………………..50 x 3.12 Average Monthly Pan Evaporation, Epan in Inches for City of Davis……….50 3.13 Threshold Salinity of Douglas fir, Ponderosa pine and Redwood…………..52 3.14 Leaching requirement of Douglas fir, Ponderosa pine and Redwood……….53 3.15 Nitrogen Uptake for Selected Forest Ecosystems with Whole Tree Harvesting…………………………………………………………………… 58 3.16 Process Effluent Performance Criteria for Future Effluent Requirements for the WPCP………………………………………………… 59 3.17 Nitrogen Loss Factor for Varying C:N Ratios………………………………. 60 3.18 Estimation of Monthly Hydraulic Loading Rate for Irrigating Douglas fir and Redwood…………………………………………………… 62 3.19 Estimation of Monthly Hydraulic Loading Rate for Irrigating Redwood…………………………………………………………………….. 63 3.20 Adjustment of Design Loading Rate to Meet the Nitrogen Requirement of Douglas fir and Redwood to Achieve Maximum Tree Growth…………..66 3.21 Adjustment of Design Loading Rate to Meet the Nitrogen Requirement of Ponderosa pine to Achieve Maximum Tree Growth………67 3.22 WPCP Improvements Project Design Flows………………………………... 69 3.23 WPCP Seasonal Average Influent Flow Statistics for 2000-2004…………...70 3.24 Flow Prediction of Average Monthly Inflows through 2030 at WPCP……………………………………………………………………..71 3.25 Determination of Acreage that could be Irrigated for Growing Different Trees without Storage…………………………………... 73 3.26 Determination of Area Irrigated for Douglas fir, Ponderosa pine and Redwood Using Wastewater Storage and Maximizing Nitrogen Applications to the Tree Crop……………………………………………….. 77 4.1 Annual Mass of Carbon Captured in Biomass……………………………….80 4.2 2007-2010 CO2 Emissions of Davis, California……………………………...81 4.3 Percentage Community Carbon Emissions Potentially Offset by This Project……………………………………………………………………81 xi 4.4 Comparison of Forest Alternative with Reuse Alternatives Considered by City of Davis…………………………………………………82 5.1 Hydraulic Loading and Irrigated Area Results………………………………86 xii LIST OF FIGURES Figures Page 1.1 Map showing City of Davis in California……………………………………..1 2.1 Carbon-Storing Components of Trees…………………………………………7 2.2 Water Pollution Control Plant Facilities and Proposed Forest, City of Davis, CA……………………………………………………………..18 2.3 Existing WPCP Facilities Treatment Schematic……………………………....19 2.4 Proposed Process Flow Diagram For The City Of Davis Wastewater Treatment Plant………………………………………………………………...25 3.1 Site Area Location of Proposed Forest Plan………………………………….. 33 3.2 Soil Map of Study Area in Davis, California…………………………………. 34 3.3 Sample Report Generated by COLE-EZ………………………………………41 3.4 Graph of Carbon Storage in Different Pools for Douglas fir…………………. 42 3.5 Graph of Carbon Storage in Different Pools for Ponderosa pine……………...44 3.6 Graph of Carbon Storage in Different Pools for Redwood…………………...45 3.7 Graph showing Average Annual Growth Rate for Selected Trees…………….47 3.8 Leaching Requirement as a Function of Applied Salinity and ECe of Crop Salinity Threshold……………………………………………………52 3.9 Nitrogen Cycle in the soil……………………………………………………..55 3.10 Seasonal Prediction of Average Monthly WPCP Inflows through 2030…………………………………………………………………………...71 xiii 1 Chapter 1 INTRODUCTION Carbon sequestration is a process of capturing and storing atmospheric carbon dioxide (CO2) over the long term to mitigate global warming and avoid dangerous climate change. This project is a feasibility study of using treated municipal wastewater from the City of Davis, CA to irrigate a carbon sequestration forest which would incorporate atmospheric CO2 into biomass. Davis is a city in Yolo County, California 18 km (11 mi) west of Sacramento and 70 mi (113 km) northeast of San Francisco as shown in Figure 1.1. The city lies in the Sacramento Valley at an elevation of about 16 m (52 ft.) above sea level. The local topography is flat and the city is surrounded by rural land devoted to agriculture. Figure 1.1- Map showing City of Davis in California (Google map) The City of Davis provides wastewater treatment for all residents and businesses within the city limits and two unincorporated areas - North Davis Meadows and El 2 Macero. The city’s Wastewater Pollution Control Plant (WPCP) currently serves a population of approximately 65,000. The city’s National Pollutant Discharge Elimination System (NPDES) permit was renewed in 2007 with strict effluent quality requirements (SWRCB, 2007). These permit requirements prompted a search for options to upgrade the existing wastewater system. The city government also has a plan to reduce greenhouse gas emissions and as part of this effort it has conducted an inventory of greenhouse gas emissions from various sources in community. The Davis Climate Action and Adaption Plan (D-CAAP) contains the greenhouse gas emission reduction targets adopted by the City Council in November 2008 (City of Davis, 2008). The City is working with the University of California, Davis and other organizations to come up with solutions for greenhouse gas reductions (City of Davis, 2010b). One strategy for reducing greenhouse gas is carbon sequestration. Carbon sequestration is a process of capturing and storing atmospheric carbon. The storage can be underground, in ocean beds, in soil, or in the form of timber in trees. Using reclaimed water from the WPCP to irrigate trees is a potential means of both offsetting greenhouse gas emissions and meeting NPDES regulations. The WPCP is located in a rural area outside the city. The effluent from secondary treatment can be used to irrigate forest on 770 acres of land already owned by the city. An additional potential benefit is that applying wastewater to land may reduce the volume of water needing costly tertiary treatment for surface water discharge as specified in the NPDES permit. 3 The major components of this study are: (1) Choosing a crop based on the amount of carbon it can sequester per year, and its climate and water quality requirements, (2) Determining the degree of wastewater treatment needed under California law for this application, (3) Performing a water balance based on the irrigation requirements of the tree crop and potential threats to groundwater such as nitrogen or salinity loading, and (4) Determining the mass of carbon dioxide that can be sequestered annually by this facility. 4 Chapter 2 BACKGROUND This chapter contains background information on carbon sequestration by forests, irrigating forests with wastewater, California water reuse regulations, plans for upgrading the Davis WPCP, and other wastewater reuse options considered by city officials in past planning activities. 2.1 Carbon Sequestration There is a strong concern to reduce the concentration of atmospheric CO2 and other greenhouse gases (GHGs) to mitigate the risks of global warming and ocean acidification. Out of the few strategies listed below for mitigation of CO2 concentrations, one of the strategies is to sequester CO2 from point sources or the atmosphere through natural and engineered systems. There are several definitions used in the industry to define carbon sequestration. One is “the process of transferring and securing storage of atmospheric CO2 that would otherwise be emitted or remain in the atmosphere” (Lal, 2008). Lal (2008) described the following natural phenomena and engineering techniques to achieve carbon sequestration: 1. Oceanic Injection: Liquefied CO2 is injected at approximately 3000 m depth under ocean beds. CO2 injection may, however, have adverse effects on deep-sea biota. There are questions regarding the stability of injection, and the process is expensive. 2. Geologic Injection: Liquefied industrial CO2 is injected into deep geologic strata such as coal seams, old oil wells, stable rock strata or saline aquifers. 5 3. Scrubbing and Mineral Carbonation: This involves capturing industrial CO2 from emissions (scrubbing) and converting it into geologically and thermodynamically stable carbonate minerals (mineral carbonation). 4. Oceanic Sequestration: This is a biological process in which phytoplankton photosynthesis captures carbon dioxide in organic material which settles to the ocean floor and is thus sequestered. 5. Wetlands: Wetland restoration techniques, such as adding municipal secondary effluent and managing hydrologic conditions to promote enhanced carbon sequestration in aboveground vegetation and belowground organic soil. 6. Agriculture: Carbon sequestration is achieved by modifying management practices in farming applications such as avoiding tillage, using organic manure and other techniques which promote carbon storage in soil layers. 7. Terrestrial Sequestration: The forest ecosystem stores carbon in the forms of harvestable timber, wood debris, wood products and other woody plants. CO2 injection in the deep ocean, geological strata, old coal mines, oil wells, and saline aquifers, are expensive and have issues with measurement and monitoring, leakage, adverse ecological impacts and regulatory measures (Lal, 2008). These techniques are still being developed and may be available for use in future. This project is focusing on terrestrial sequestration as a strategy to reduce atmospheric CO2 concentrations. 6 2.2 Forest-Based Carbon Sequestration Forest systems with enhanced woody growth are well-suited to long term carbon sequestration. This implies transfer of atmospheric CO2 into long-lived carbon reservoirs in tree biomass. 2.2.1 Forest vs. Agricultural Crop Carbon Sequestration Agricultural crops have roots, stems, branches and leaves. Trees vertically expand into roots, trunk, branches, stem and foliage such that each component is bigger in height, width and depth than agricultural crops. Trees store larger magnitudes of carbon as lignin and other relatively resistant polymeric carbon compounds than conventional agricultural crops (IFPC, 2012). Agricultural crops accumulate carbon mostly in the 0-30 cm effective depth of the root zone. Deep-seated root system of trees can attach more carbon for up to several feet in the ground. Figure 2.1 shows the different parts of the tree which can store carbon. The amount of carbon stored trees is approximately 17% in roots, 50% in trunk, 30% in branches and stems and 3% in foliage (Lal and Augustin, 2012). The large numbers of leaves in the foliage or crown of evergreen trees, compared to crops, stores more carbon in the trees’ biomass. 7 Live Tree - Carbon in crown, bole, roots of live trees. Standing Dead Tree - Carbon in crown, bole, roots of standing dead trees. Understory - Carbon in understory trees and shrubs. Diameter less than 1 inch. Down Dead - Carbon in dead, downed wood more than 3 inches diameter. Forest Floor - Biomass (dead) less than 3 inches diameter above mineral soil. Soil (1m) - Organic carbon in the surface 1 meter of mineral soil, excluding coarse roots. Figure 2.1 – Carbon-Storing Components of Trees (USDA Forest Service, 2013) One of the main issues to consider in agricultural crop carbon sequestration is the longevity of the product. Carbon captured in soils by crops can be lost due to tilling, wind, fire, drought or pests. This carbon loss can be reduced by eliminating ploughing, switching to no-till farming, growing cover crops in the rotation cycle and using organic manure (Paustian et al., 2004). The amount of carbon stored in the soil due to agriculture also depends on the net carbon left in the soil after decomposition of biomass. If decomposition can be reduced, then amount of carbon stored in the soil can be increased. 8 This can be achieved by recycling crop residue and efficient use of water and nutrients (Paustian et al., 2004). In contrast, the role of forests, which act as a natural carbon sinks, is significant. Long-term storage of carbon using forest can be realized by preserving trunk, stem and branches either by long-lived tree growth or by putting them in productive use as timber. It is estimated that about 12-19% of carbon from fossil fuel combustion is sequestered by the existing forests of the United States (Ryan et al, 2010). 2.2.2 Carbon Pools Associated with Forests Carbon pools associated with forests include the standing forest, forest products in use, and wood products disposed in landfills (IFPC, 2012). There are multiple ways to put parts of trees, including trunk, stem, branches and dead leaves on the forest floor to commercial use without letting them decompose or burn and release carbon into atmosphere. Modern forest products operations are efficient at using each part of a tree. Trees are used to make lumber. Leftover chips and sawdust are made into wood pulp for paper and other products. When wood is turned into pulp for paper, heat and chemicals dissolve the lignin and release the cellulose fibers. Byproducts of this process are used in asphalt, paint, chewing gum, detergents and turpentine. Other refined cellulose products include rayon fabric, and nitrocellulose, which is used to make nail polish, solid rocket fuel and industrial explosives (IFPC, 2012). The share of the carbon contained in the salable portion of harvested timber that is sequestered in wood and paper products (including recycled products) during their usable lives and afterward 9 in landfills is estimated to range from 20 percent to about 45 percent of tree biomass. (Lubowski et al., 2006) 2.2.3 Enhancement of Carbon Sequestration through Management Practices The amount of carbon that will be accumulated in the forest depends on location, climate and plant species. Carbon sequestration can be increased by planting new trees on lands previously used for other purposes (afforestation) or by planting additional or replacement trees on existing forestland (reforestation). Sequestration is estimated to increase from 2.2 to 9.5 metric tons of CO2 per acre over 120 years by afforestation (Birdsey, 1996) and from 1.1 to 7.7 metric tons of CO2 per acre by reforestation (Row, 1996). Sequestration can also be increased by management practices such as timely harvesting, choosing the right tree species, and using wastewater effluent for afforestation. Forests that are managed on a regular basis during the early growth stages can remove significantly more atmospheric carbon by increasing the life span of a tree compared to forests that are not intensively managed. Intensively managed redwood forests, for example, support the greatest concentration of carbon storage (150 tons/acre) among all California forest types (Nowak et al., 2002). Due to the tremendous increase in carbon biomass during growth stages, net carbon storage per year in young trees is far larger than in old, mature trees. To increase carbon sequestration in old trees, the focus needs to be on ways to increase the foliage area in the trees and overall canopy growth. This can be achieved by regular thinning of the trees and harvesting at the proper growth age (Mader, 2007). Management practices also involve selecting trees with appropriate life spans and growth rates. Given the same life span and growth rate, larger trees at maturity will 10 sequester more carbon than smaller trees. Growth rates will affect net sequestration if the tree is harvested before it reaches mature size. For example, two different species may store 3 tons of carbon at maturity and live 100 years, but if one species reaches a mature size after 10 years (fast growth) and the other after 90 years (slow growth), and if these trees are harvested after only 50 years, the fast-growing tree will have sequestered more carbon by the time of harvest. However, if both species live to maturity (100 years), there is no difference in carbon storage. Large trees at maturity with long life spans and moderate growth rates are useful to attain high net carbon storage. 2.2.4 Carbon Accounting Tools The U.S. Department of Agriculture Forest Inventory and Analysis National Program conducts a national-level strategic forest inventory which is a combination of field-based measurements of carbon content and remotely-sensed observations. The data collected provide estimates of forest age, cover types, disturbance that can be used for modeling of components that are difficult to measure. A software toolbox has been developed with basic calculation tools to help quantify forest carbon for planning or reporting (USDA Forest Service, 2013). The tools listed in Table 2.1 are currently available. 11 Table 2.1- List of Available Carbon Accounting Tools Tool Carbon OnLine Estimator (COLE-EZ) U.S. Forest Carbon Budget Model (FORCARB2) U.S. Forest Carbon Calculation Tool (CCT) Forest Vegetation Simulation (FVS) i-Tree Chicago Climate Exchange (CCX) Carbon Accumulation Table Description COLE is a planning tool that enables a planner to estimate forest carbon characteristics of any county of the continental United States for generating carbon credits. COLE data are based on USDA Forest Service Forest Inventory & Analysis and Resource Planning Assessment data, enhanced by other ecological data. It can calculate changes in net carbon stocks in each part of a tree with an option for standing forests or managed systems. These criteria are unique in the tool and important for selection of trees to maximize annual carbon sequestration. FORCARB2, an updated version of the U.S. FORest CARBon Budget Model (FORCARB), produces estimates of carbon stocks and stock changes for forest ecosystems and forest products at 5-year intervals. The Carbon Calculation Tool 4.0 is a computer application that reads publicly available forest inventory data collected by the U.S. Forest Service’s Forest Inventory and Analysis Program (FIA) and generates state-level annualized estimates of carbon stocks on forest land based on FORCARB2 estimators. FVS is an individual-tree, distance-independent growth model for forests that are in existence. The tool is used in early stages of tree growth to predict changes in tree diameter, height, crown ratio, and crown width, as well as mortality over time. Two carbon reports can be requested: the Stand Carbon Report and the Harvested Carbon Report i-Tree is a state-of-the-art, peer-reviewed software suite from the US Forest Service that provides urban and community forestry analysis and benefits assessment. The i-Tree tool helps communities of all sizes to strengthen their urban forest management and advocacy efforts by quantifying the environmental services that trees provide and assessing the structure of the urban forest. The CCX Carbon accumulation tables give an estimate of CO2 /acre/year of tree growth for US regions and species. If the species and region combinations do not match a particular project, the carbon accumulation values for the species in a similar climate can be applied. Citation http://www.ncasi2.org/CO LE http://www.nrs.fs.fed.us/pu bs/35613 http://www.nrs.fs.fed.us/pu bs/2394 nrs.fs.fed.us/carbon/tools www.itreetools.org http://www.cinram.umn.ed u/publications/landowners_ guide1.5-1.pdf 12 For this project, COLE-EZ was used as a planning tool for selecting a tree type and calculating the net carbon storage annually. Other software tools such as FVS and iTree require real time data of existing forests which are not available in this project. COLE-EZ allows estimation of carbon stocks for future planning of afforestation (establishing a forest especially on land not previously forested) as well as reforestation (planting new trees in areas where they have been removed) projects (USDA Forest Service, 2013). 2.3 Irrigating Forest with Reclaimed Wastewater The most common forest crops used in so-called “slow rate” wastewater irrigation systems are mixed hardwoods and pines (Kemp et al., 1978). “Slow rate” (SR) means the application of wastewater by spraying on permeable soil. Use of slow rate systems reduces discharges to surface water and the potential for groundwater contamination. Slow rate forested systems offer several advantages (Kemp et al., 1978): 1. Forested systems can accommodate a longer wastewater application season than agricultural crops, thus utilizing a higher annual volume of wastewater per acre. 2. Forested systems allow higher hydraulic loadings than typical agricultural crops. 3. During cold weather, soil temperatures are often higher in forestlands than in agricultural lands. A summary of representative slow rate systems and types of forest crops used is presented in Table 2.2. 13 Table 2.2- Forested Slow Rate Treatment Systems in the United States (Crites et al., 2000) Location Dalton, GA Clayton, Co., GA Helen, GA St. Marys, GA Mackinaw City, MI State College, PA West Dover, VT Design Flow, MGD 30.0 19.5 0.02 0.3 0.2 3.0 0.55 Tree Types Pines Loblolly pines, hardwood Mixed pine and hardwood Slash pine Aspen, birch, white pine Mixed hardwood, pine Hardwood balsam, hemlock, spruce The use of treated wastewater for forest is less explored than agricultural and landscape irrigation, which is widespread in various regions. For example, shade and street trees and urban green areas are irrigated with treated sewage effluent transported by tanker in some cities such as Cairo, Tehran and others in the Middle East, India and the United States (El-Lakany, 1995). However, large-scale use of wastewater for the irrigation of tree plantations or forests is still relatively limited. It is generally practiced for waste disposal and treatment rather than for enhanced forestry production. Pioneering studies on the application of treated municipal wastewater on forest lands as a means of purification and groundwater recharge were carried out in central Pennsylvania in the United States from 1963 to 1977 (FAO, 1978). Sewage effluent which had undergone secondary treatment was sprayed on three different forest areas: a mixed oak (Quercus spp.), a red pine (Pinus resinosa) and a sparse stand of white spruce (Picea glauca) with different application rates. The results indicated that the controlled irrigation of forests with up to 2.5 cm/ha (0.4 in/acre) of effluent per week over an year can effectively remove nitrogen, phosphorus and other constituents, rendering water of acceptable quality for drinking. 95 percent of the effluent applied was recharged to the 14 groundwater reservoir and nutrients in the effluent were responsible for an increase in tree growth (measured by diameter) of 80 to 186 percent. A model of wastewater purification similar to that tested in Pennsylvania has been adopted in parts of Spain, Australia and India (FAO, 1978). 2.3.1 Water Quality Criteria for Wastewater Forest in California Applying wastewater and sludge to land for remediation is recommended by the Environmental Protection Agency (EPA) and others as a method to recycle nutrients and organic matter and conserve water resources (Sopper and Kardos, 1973; Sopper et al., 1982; Bastian and Ryan, 1986; Luecke and De La Parra, 1994). The level of sewage treatment prior to land application can range from primary treatment using a simple lagoon to tertiary treatment using a sophisticated mechanical wastewater treatment plant. In California several state agencies, including the Department of Health Services (DHS), the State Water Resources Control Board and the Regional Water Quality Control Board, plus county and local authorities have regulatory authority over potential projects using recycled water. A compilation of California laws related to recycled water, including excerpts from the Health and Safety Code, Water Code, and Titles 17 and 22 of the California Code of Regulations, are contained in a document referred to as the “Purple Book,” last updated in June 2001 by California Department of Public Health Services (CDPH, 2001). The recycled water types, along with the corresponding water quality standards and treatment processes required, are summarized in Table 2.3. 15 Table 2.3- Water Recycling Types and its Criteria (CDPH, 2001) Total Coliform Bacteria (MPN/100 mL) Code Section3 60301.230 60301.220 60301.225 60301.900 Recycled Water Type Disinfected Tertiary Disinfected Secondary – 2.2 Disinfected Secondary-23 Un-disinfected Secondary Treatment Process Filtered1 and Disinfected2 Oxidized and Disinfected Oxidized and Disinfected Oxidized Median Maximum allowed in a 30-day period 2.2 2.2 23 240 (never exceed) 23 23 240 - - Notes: 1. “Filtered” means an oxidized wastewater that satisfies (A) or (B) below (A) Has been coagulated and passed through natural soils or filter media with a specified maximum flux rate, depending in the type of filtration system, and the turbidity does not exceed any of the following: (1) A daily average of 2 NTU (2) 5 NTU more than 5 percent of the time within a 24-hour period (3) 10 NTU at any time (B) Has been passed through a microfiltration, ultrafiltration, nanofiltration or reverse osmosis membrane so that the turbidity does not exceed any of the following: (1) 0.2 NTU more than 5 percent of the time within a 24-hour period, (2) 0.5 NTU at any time 2. Disinfected by either: (A) A chlorine process with continuous CT of 450 mg-min/L with a modal contact time of 90 minutes (based on peak dry weather design flow). (B) A combined process that inactivates and/or removes 99.999 percent (5-log removal) of Fspecific bacteriophage MS-2 or polio virus (1) In the last 7 days for which analyses have been completed (2) In no more than 1 sample in any 30-day period (3) In no samples 3. The California Code of Regulations, Title 22, Division 4, Chapter 3 The four types of recycled water that are currently permitted by the CDPH and some of the approved uses are summarized in Table 2.4. 16 Table 2.4: Approved Recycled Water Treatment and Uses (CDPH, 2001) Treatment Level Disinfected Tertiary Recycled Water Disinfected Secondary- 2.2 Recycled Water Disinfected Secondary- 23 Recycled Water Approved Uses Spray Irrigation of Food Crops Landscape Irrigation1 Non-restricted Recreational Impoundment Surface Irrigation of Food Crops Restricted Recreational Impoundment Pasture for Milking Animals Landscape Irrigation2 Landscape Impoundment Surface Irrigation of Orchards and Vineyards3 Fodder, Fiber and Seed Crops Un-disinfected Secondary Recycled Water Notes: 1. Includes unrestricted access golf courses, parks, playgrounds, school yards and other landscaped areas with similar access 2. Includes restricted access golf courses, cemeteries, freeway landscapes, and landscapes with similar public access. 3. No fruit is harvested that has come in contact with irrigating water or the ground. Table 2.3 and Table 2.4 indicate that the option of forest irrigation proposed in this project requires only Un-disinfected Secondary Recycled Water for irrigation as long as care is taken that no irrigation with recycled water occurs for a period of 14 days prior to harvesting or allowing access by the general public. Further, the Purple Book specifies that, “No irrigation with, or impoundment of, un-disinfected secondary recycled water can take place within 150 feet of any domestic water supply well. No spray irrigation of any recycled water other than disinfected tertiary recycled water can take place within 100 feet of a residence or a place where public exposure could be similar to that of a park, playground or schoolyard” (CDPH, 2001). One concern that requires attention during the application of wastewater is increasing the salinity of the soil. Light, frequent irrigation can increase surface soil salinity that can limit crop production. On the other hand, over-irrigation can carry contaminants to the groundwater. Wastewater provides an excellent source of nutrients 17 for vegetation, but care needs to be taken that wastewater leaching in groundwater is free from excessive nitrate-nitrogen. If the nitrate-nitrogen level is higher than the maximum contaminant limit (MCL) of 10 mg/L in groundwater that is used for drinking water, it can be harmful to young infants and young livestock because it can restrict oxygen flow in the blood stream (USEPA,2009; USDA-NRCS, 2011). Therefore, during the use of wastewater for irrigation, a balance needs to be achieved through careful selection of application rates that would prevent both increases in surface soil salinity and contamination of groundwater. Current regulations do not generally define the limits of specific constituents that can be discharged in land application, although limits may be included in discharge permits for individual facilities. Nevertheless, a limit of 10 mg/L of total nitrogen based on the drinking water quality standard is recommended as the maximum allowable percolating water concentration, as mentioned in Draft Groundwater Recharge Reuse Regulations developed by the California Department of Public Health (CDPH, 2013). 2.4 City of Davis Wastewater Treatment Plant and Wetlands The Davis Water Pollution Control Plant (WPCP) was constructed in 1970. Figure 2.2 shows location of the WPCP with respect to the city and the site of the proposed carbon sequestration forest. 18 Wastewater Treatment Plant Discharge Point 001 (Willow Slough Bypass) Wetland Discharge Point 002 (Toe Drain) Proposed Forest Irrigation Site City of Davis I-80 Figure 2.2- Water Pollution Control Plant Facilities and Proposed Forest, City of Davis, CA (Google maps) The following description of WPCP is based on several documents published by the City of Davis (City of Davis, 2005; City of Davis, 2010a; City of Davis, 2013). The current plant processes, shown in Figure 2.3, consist of comminutors, grit removal, primary sedimentation, oxidation ponds, aerated ponds, a Lemma (duckweed) pond, overland flow terraces, disinfection and anaerobic solids treatment (City of Davis, 2005). Figure 2.3- Existing WPCP Facilities Treatment Schematic (City of Davis, 2005) 19 20 During the summer months, primary effluent is pumped to three oxidation ponds operated either in series or in parallel. During the winter months, a portion of the primary effluent is sent directly to aerated ponds, always operated in series, to reduce the BOD loading to the oxidation ponds. Depending on the season, the Lemna pond receives either aerated pond effluent or oxidation pond effluent. The Lemna pond is operated yearround, primarily as a settling and polishing pond. The various pond designations, surface areas, maximum depth, and available storage volumes are summarized in Table 2.5. Table 2.5- Summary of Davis WPCP Secondary Treatment Ponds (City of Davis, 2013) Designation Maximum Depth(a), feet Oxidation Pond 1 5.5 Oxidation pond 2 5.5 Oxidation Pond 3 5.5 West Aerated Pond 7.0 East Aerated pond 7.0 Lemma Pond 7.5 Totals (a) Includes a freeboard of 2 feet Surface Area, acres Storage Volume, MG 33 35 35 5.3 5.3 5.0 119 57 61 61 12 12 12 215 Pond effluent is applied to the overland flow terraces through sprinklers, which provide further biological treatment as the water flows over soil and through vegetation. The overland flow terraces are divided into fifteen watering zones; the number of zones in service at any given time depends on the season and operational and maintenance needs. Effluent from the overland flow system is collected at the effluent pump station, where it is pumped to the chlorine contact basin for disinfection prior to discharge. The present treatment process involves oxidation and disinfection processes that provide disinfected secondary-level treatment. Treated effluent is discharged either to Willow Slough Bypass or to the Conaway Ranch Toe Drain via the Davis Restoration 21 Wetlands, subject to weather conditions and treatment performance. During winter, the discharge is routed to the restoration wetland which has a volume of 430 million gallons (MG). Disinfected secondary effluent is discharged into one of two wetland lagoons and then flows into two tracts (out of seven) prior to discharge either to Willow Slough Bypass or to the Conaway Ranch Toe Drain (City of Davis, 2005). Annual average WPCP influent flows for years 2000-2004 are presented in Table 2.6. Table 2.6- Average Annual WPCP Influent Flow Statistics for 2000-2004 (City of Davis, 2005) Year 2000 2001 2002 2003 2004 Average Annual Average Flow (MGD) 5.64 5.59 5.77 5.86 5.96 5.77 To understand the quality of influent entering into the system at different times of the year, the City recently sampled WPCP influent for the following study periods (City of Davis, 2013): Special Monitoring Period Study No. 1: Daily data collected over a 14-day period starting July 23, 2012 and ending August 6, 2012. These data represent the influent conditions that occur when the student population in the city is at its lowest. Special Monitoring Period Study No. 2: Daily data collected over a second 14-day period starting October 29, 2012 and ending November 11, 2012. These data represent the influent conditions that occur when the student population in the city is at its highest. 22 The average influent constituent concentrations measured during each of the two monitoring periods are summarized in Table 2.7. Table 2.7: WPCP Average Influent Water Quality Characteristics (City of Davis, 2013) Parameters Units Special Monitoring Period Study No. 1(a) Study No. 2 Influent Primary Influent Primary Effluent Effluent Organics BOD-total mg/L 187 148 238 168 BOD-soluble mg/L 63 79 82 84 COD-total mg/L 491 355 605 367 COD-soluble mg/L 136 166 156 157 Suspended Solids TSS mg/L 213 74 280 87 VSS mg/L 174 63 259 82 ISS mg/L 32 11 21 4 Nutrients NH4-N mg/L 31 30 36 34 NO3-N(b) mg/L <0.010 <0.010 <0.010 <0.010 NO2-N(b) mg/L <0.002 <0.003 <0.012 <0.012 TKN-total mg/L 43 40 48 42 TKN-soluble mg/L 31 31 36 36 Phosphorous-total mg/L 5.2 5.4 5.5 5.5 Phosphorous-soluble mg/L 3.1 3.8 4.0 4.2 Orthophosphate mg/L 2.7 3.2 3.4 3.7 Other Parameters Alkalinity (as CaCO3) mg/L 427 440 408 409 Electrical Conductivity uS/cm 1442 1500 1420 1410 Calcium mg/L 31 32 34 33 Magnesium mg/L 42 44 41 41 Total VFAs(d) mg/L 80 74 70 77 (a) Influent data from the first week of sampling (July 23-30) is not included in the averages because it was determined to be unrepresentative of normal WPCP influent. Influent data are shown for July 31-August 6, 2012. Primary effluent data shown are for dates as indicated. (b) “<” indicates average values that include non-detect results, with individual non-detect (ND) data set at the method detection limit (MDL) (c) Individual inert suspended solid (ISS) data points used in the average have been calculated as the difference between paired TSS and VSS data points. (d) Total VFAs has been calculated as the sum of paired results for the following acids, with ND results ignored: acetic, butyric, DL-lactic, formic, isovaleric, propionic, pyruvic, valeric. In 2007, the Regional Water Quality Control Board (RWQCB) issued new National Pollution Discharge Elimination System (NPDES) permit requirements which were much more stringent than previous requirements with respect to biological oxygen 23 demand (BOD), total suspended solids (TSS) and ammonia (City of Davis, 2013). Table 2.8 summarizes the 2007 NPDES permit effluent limits at the Willow Slough Bypass discharge location. The permit also requires a compliance date of October 25, 2017 for upgrading the current treatment system. To meet this requirement, the City needs to construct a new tertiary treatment process. Table 2.8- Summary of 2007 NPDES Permit at Discharge Location- Willow Slough Bypass (SWRCB, 2007) Parameter BOD 5-day @ 200 C1 Total Suspended Solids1 pH Settleable Solids1 Turbidity1 Total Coliform Organisms1 Aluminum Total Recoverable3 Ammonia (1 March – 31 October) Ammonia (1 November – 29 February) Cyanide Iron, Total Recoverable Selenium, Total Recoverable 1. 2. 3. Units Effluent Limitations Maximum Instantaneous Daily Minimum Maximum Average Monthly Average Weekly mg/L Lbs/day2 mg/L Lbs/day2 Standard values mL/L NTU MPN/ 100 mL 10 630 10 630 15 940 15 940 µg/L 71 140 mg/L Lbs/day2 0.43 26.9 1.04 65.1 mg/L Lbs/day2 0.52 32.5 1.04 65.1 µg/L mg/L 3.8 0.8 9.5 2 20 1300 20 1300 6.5 0.1 8.5 0.2 10 240 µg/L 4.4 7.1 Lbs/day2 0.28 0.44 Compliance is to be measured at Monitoring Location EFF-A as described in the attached MRP. Based on an average dry weather flow of 7.5 MGD. Compliance with the effluent limitations for aluminum can be demonstrated using either total or acid-soluble (inductively coupled plasma/atomic emission spectrometry or inductively coupled plasma (mass spectrometry) analysis methods, as supported by USEPA’s Ambient Water Quality Criteria for Aluminum document (EPA 440-86-008), or other standard methods that exclude aluminum silicate particles as approved by the Executive Officer. 24 The restoration wetlands downstream of the WPCP were put in service in 1999 with funding from the U.S. Army Corps of Engineers to restore wetland habitat in the area (City of Davis, 2005). The land area of the wetlands is 400 acres, out of which 77 acres is used for wastewater treatment and the rest is used for stormwater detention. One of the main issues with the current wetland configuration is that the long detention times and lack of vegetated zones lead to algal growth and a rise in pH, making compliance with existing discharge requirements difficult. In addition, test results over the last five years show a steady rise of selenium in the wetland invertebrates and bird eggs, indicating that continued use of the wetlands may be problematic as bioaccumulation of selenium in the food chain can be toxic (City of Davis, 2005). A Wastewater Planning Charrette was conducted on October 22-23, 2009 to develop a cost-effective wastewater management plan for the City of Davis (City of Davis, 2010a). The City has chosen the Charrette Plan as its preferred plan for wastewater improvements. Figure 2.4 shows the proposed treatment plant processes. Figure 2.4- Proposed Process Flow Diagram For The City of Davis Wastewater Treatment Plant. Dashed Lines Indicate Alternative Flow Pathways or Intermittent Flow (City of Davis, 2010a) 25 26 Existing screening/grit removal, primary sedimentation, disinfection/ dechlorination facilities and anaerobic solids digestion are going to remain unchanged (City of Davis, 2013). A secondary treatment process with biological reactors, secondary clarifiers and associated facilities will replace the existing treatment ponds and overland flow facility. For BOD removal, the improvement plan proposes a biological treatment process that relies on either plug-flow activated sludge or oxidation ditch technology. It should also provide biological nitrification and denitrification without an external carbon source as long as the influent provides adequate carbon. Nitrification (oxidation of ammonia to nitrate) can be achieved to a greater degree and more reliably with activated sludge than with alternative processes such as trickling filters (City of Davis, 2010a). Upon completion of the Wastewater Treatment Plant (WWTP) Improvements Project, the existing treatment ponds will be used for long-term emergency and maintenance storage, recycled water storage, stormwater storage, and flow equalization (City of Davis, 2013). These ponds will, therefore, provide operational flexibility and reliability (City of Davis, 2013). For tertiary treatment, wastewater will be processed through chemical addition, disk filtration, disinfection/dechlorination and post-aeration to achieve Title 22 defined disinfected tertiary quality as described in Table 2.3. The city currently relies entirely on groundwater wells for public water supply. A combination of intermediate and deep wells extracts groundwater from underlying aquifers. Studies (City of Davis, 2005 and 2013) have shown that if the city either replaced intermediate aquifer wells with deep aquifer wells and/or developed a surface water supply from the Sacramento River, TDS, EC, and selenium concentrations in the 27 wastewater would decrease. The City has proposed a surface water project to provide 12 million gallons per day (MGD) of surface water from the Sacramento River to Davis water customers which should reduce concentrations of selenium, alkalinity, total dissolved solids, and hardness (City of Davis, 2005 and 2010a). Compliance with selenium requirements is expected to be possible even during periods when groundwater would be used as part of the supply. The decrease in alkalinity will result in a decrease in effluent pH. For this reason, the improved treatment plant will not have any salinity or selenium removal processes. (City of Davis, 2010a) 2.5 Future Reuse Opportunities Meeting the 2007 NPDES permit conditions will require construction of a tertiary treatment system that could meet the Title 22 disinfected tertiary standards. This would allow reuse of the city’s effluent in the future. The following disposal and reuse alternatives were evaluated by the City (City of Davis, 2005): 1. Surface Water Discharge to Willow Slough/Conaway Ranch Toe Drain (existing discharge) or Sacramento River 2. Export raw wastewater to Sacramento Regional County Sanitation District (SRCSD) 3. Year-round land disposal/reuse to seasonal agricultural reuse/storage or yearround percolation basins 28 4. Seasonal Reuse by: Urban reuse from the main WPCP facility, Urban reuse through a satellite treatment facility separate from the WPCP, Reuse at the Yolo Basin Foundation/Department of Fish and Game (DFG) Wetlands, and Demonstration reuse on city-owned lands The disposal/reuse alternatives evaluated by the City are compared in Table 2.9. Table 2.9- Summary of Disposal/Reuse Alternatives Evaluation (City of Davis, 2005) Reuse/Disposal Alternative Existing Discharge Sacramento River Export to SRCSD Land Percolation Storage/Reuse Relative Cost(1) Level of Treatment Assumed Implementation Risk 1.00 1.8 1.6 Tertiary Tertiary Secondary (provided at SRCSD) Secondary Secondary Low High Medium 1.1-1.3 2.0-3.0 High Low (1) Relative cost = cost of alternative divided by cost of existing discharge alternative. As described in City of Davis (2005), the Sacramento River may offer dilution for discharge but is expensive due to the need for a new pipeline 20 miles long from the WPCP to the river. In addition, there may be opposition from downstream stakeholders regarding the quality of water added as a new discharge to Sacramento River. Export to SRCSD is also costly both because of the distance and because SRCSD is in the process of adding tertiary treatment. The year-round land percolation option has number of unknowns associated with it, such as the ability to maintain a sustained long-term 29 percolation rate due to heavy clays. Regulation of percolation operations is likely to be changed as groundwater degradation continues to be evaluated. The storage and reuse options were expected to be costly due to the large area of storage ponds required to hold the water through the winter, and the large amount of land in addition to the existing City of Davis parcel that must be purchased for reliable agricultural reuse (City of Davis, 2005). Agricultural use was considered the best option for reuse given the surrounding land uses, but Conaway Ranch and other land owners who might use the water indicated that it would either not meet their water quality needs (because it cannot be directly applied to consumable crops) or would be more costly than simply drilling a shallow well to produce irrigation water (City of Davis, 2013). Looking to lower costs and implementation risks, the City decided to continue discharging at the existing locations (City of Davis, 2013). The goal of this project is to evaluate an option for wastewater remediation by irrigating a carbon sequestration forest on land the city currently owns. The master plan did not look at this option. The forest option requires only secondary-level treated wastewater for irrigation. This will reduce the volume of wastewater that will require tertiary treatment for surface water discharge per the NPDES permit. This could reduce the overall cost of wastewater treatment. In addition, a carbon pool will be created in the form of forest which will provide carbon sequestration. This alternative will also help City achieve its greenhouse gas (GHG) reduction goals. In the following chapters this option will be assessed further by choosing a crop based on the amount of carbon it can sequester per year and its climate and water quality 30 requirements; performing a water balance based on the irrigation requirements of the tree crop and the need to prevent potential threats to groundwater such as nitrogen or salinity loading; and determining the mass of carbon that can be sequestered annually by this facility. 31 Chapter 3 PROJECT CALCULATIONS In this chapter, the feasibility of a carbon sequestration forest is assessed by evaluating the suitability of the site for the forestry plan, choosing an agroforestry management plan, and performing a water balance between forest water requirements and available secondary treated wastewater effluent, based on hydraulic loading rates which avoid leaching of nitrogen to groundwater and waterlogging. 3.1 Slow Rate (SR) Forest Treatment Slow rate land treatment is the application of wastewater to a vegetated soil surface. The applied wastewater receives significant treatment as it flows through the plant root/soil matrix. Solids removal generally occurs at the soil surface and biological, chemical and additional physical treatment occurs as the wastewater percolates downward. Off-site runoff of any of the applied wastewater is prevented by the system design. Slow rate land treatment can be operated to achieve a number of objectives including: Further treatment of the applied wastewater, Economic return from the use of water and nutrients to produce marketable crops, Exchange of wastewater for potable water for irrigation purposes in arid climates’ and Development and preservation of open space and greenbelts. 32 The selection of slow rate application for this project is based on water reuse regulations and the limit of 10 mg/L nitrogen in the groundwater (CDPH, 2013). The most cost-effective system applies the maximum possible amount of secondary treated wastewater to the smallest possible land area for cultivating trees (i.e. increasing the sequestered carbon biomass) at the highest growth rate possible. The principal limitation to the use of wastewater for forested SR systems is that nitrogen removals are relatively low unless young, developing forests are used or conditions conducive to denitrification are present (USEPA, 1981). The design of land treatment systems, wetlands, and similar processes is based on the Limiting Design Parameter (LDP) concept (Crites et al., 2000). The LDP is the factor or the parameter which controls the design by establishing the required size and loadings for a particular system. If a system is designed for the LDP, it will then function successfully for all other less-limiting parameters of concern. Experience has shown that the LDP for SR systems depends significantly on the agronomic requirements of the crop, the hydraulic capacity of the soil or the ability to remove nitrogen to the specified level when typical municipal wastewaters are applied (USEPA, 1981). Whichever of these parameters requires the largest treatment area for a given flow controls design as the LDP. 3.2 Site Characteristics and Climate As described in the introduction, this project would be implemented on the approximately 770 acres of city-owned area located north of Interstate Highway 80 shown in Figure 3.1 (green areas). The site has the advantage that no land acquisition cost 33 will be involved to implement this project. An additional benefit would be relatively low distribution costs due to its close proximity to wastewater treatment plant. Currently the site is open land with no agricultural activities. Figure 3.1- Site Area Location of Proposed Forest Plan (City of Davis, 2005) Important site characteristics to be examined for the design of a forest system are land use, type of soil, textural class, soil permeability and groundwater depth. A custom soil resources report for the site was generated by the author from a USDA-NRCS website (USDA-NRCS, 2013a). Types of soil in the area of study are shown in Figure 3.2 and listed in Table 3.1. Figure 3.2- Soil Map of Study Area in Davis, California (USDA-NRCS, 2013a) 34 35 Table 3.1- Soil Type Classification of Study Area in Davis, California (USDA-NRCS, 2013a) Area (Acres) Soil Classification (see Table 3.2 for names) Ca, Rg, Mf Ca, Sd Ck, Sd 327.044 245.58 198 Total = 770 Soil Type Silty clay, Silty clay loam Silty clay, Clay Clay Other site characteristics that were considered in assessing the feasibility of a site for slow- rate land applications are listed in Table 3.2. Table 3.2- Site Characteristics of Study Area in Davis, California (USDA-NRCS, 2013a) 0 to 1 Mf – Marvin silty clay loam 0 to 1 Rg – Rincon silty clay loam 0 to 1 Sd – Sacramento clay, drained 0 to 1 0.06 to 0.20 0.06 to 0.20 0.06 to 0.20 Groundwater depth (ft) > than 6.5 ft > than 6.5 ft Textural class Silty clay Silty clay loam Ca – Capay silty clay Slope (%) Soil Permeability (Ksat in in/hr) CkClear lake clay Slow Rate System Requirement* 0 to 2 0 to 20 0.06 to 0.20 0.06 to 0.20 0.06 - 2.0 > than 6.5 ft > than 6.5 ft > than 6.5 ft 2 to 10 Silty clay loam Clay Clay Clay loam to sandy loam *USEPA, 2006 The custom soil resources report also provides land management interpretations designed to guide in evaluating the soil response to forest management practices. The key factor is that most of the soils under the study area have drainage limitations and flooding which will reduce the choice of plants or require careful water management, or both. Sunset Magazine climate zone descriptions provide guidance in choosing the right tree that could be grown under the range of temperature differences in the area. The climate zone for the City of Davis is number 14 (Sunset Magazine, 2013). Zone 14 is 36 comprised of milder-winter, marine-influenced areas and the cold-winter inland valley areas. Over a 20-year period, this area has experienced temperature lows ranging from 26 to 16º F (–3 to –9º C) and 226 frost-free days (United States National Weather Service, 2013). Precipitation averages 16.83 inches per year, mainly between months of November and March (CDEC, 2013). 3.3 Carbon Sequestration Plan In this section, the method for systematically selecting forest trees and determining the best harvesting ages to achieve maximum CO2 sequestration is presented. Trees choices are based on following criteria: Trees which produce marketable wood in the form of lumber or other longterm uses are preferred. To achieve increased carbon sequestration, trees having trunk, stem and branches of superior strength-to-weight ratio are desired because each part of tree can be put into long-term uses such as construction lumber, plywood, furniture, paper and several wood pulping byproducts as described in Section 2.2.2. This implies that lumber trees are preferred over ornamental trees. Trees should be evergreen so that the needles take up more carbon throughout the whole year. Trees with fast growth rate and long maturity are preferred. As explained in Section 2.2.3, tree build up carbon biomass through the growth of trunk, stem and branches until maturity. After maturity is attained, the growth rate 37 declines as components lose biomass by withering or dying. A long maturity period helps to gain positive net annual change in carbon. Trees should survive in the temperatures (-3 to 34 oC) and soil conditions (clay and loamy soil) of the study area. Trees should be salt tolerant and survive in moist or saturated conditions. Many native and California trees can be grown as forest. Native trees which are common in the valley, but are not suited for carbon sequestration are listed in Table 3.3. Table 3.3- List of Native Trees in the Area (Sunset Magazine, 2013) Native Trees* Attributes Not Suitable for Carbon Sequestration Different varieties of Willow Small height, ornamental (no lumber) California Sycamore Ornamental (no lumber) California white oak, White Oak, Valley Oak Grows in Sand – Loamy soil, Slow growth rate Different varieties of Cottonwood Ornamental (no lumber) *Personal communication with tour docent during site visit to City of Davis Wetlands (02/23/2013) In this study, non-native trees such as Douglas fir, Ponderosa pine and redwood, because they satisfy all the criteria listed above to maximize sequestration of carbon. Specific characteristics considered in the selection of these trees are listed in Table 3.4. Table 3.4 – Characteristics of Trees Selected for the Agro-Forestry Plan (Forest Foundation,2013; USDA-NRCS, 2013b) No. Trees Scientific Names Forest Type Water Needs Soil Type Maturity Attained (Years) Maximum Height (ft) 1 Douglas fir Pseudotsuga menziesii Evergreen 2 Ponderosa pine Pinus ponderosa 3 Redwood Sequoia sempervirens Canopy Growth Longevity Climate Uses o Width Rate (Years) C (Products) (ft) (Inches per season) 20-30 24 150 - 33 to Structural 37 Lumber Moist to Dry Soil Clay, Loam or Sand 12-20 80-160 Evergreen Moist to Dry Soil Clay, Loam or Sand 19-250 50-100 25-30 24 to 36 151 Evergreen Moist Clay, Loam or Sand 10-50 70-100 15-30 36 or more 100 -40 to 43 Building Timber -9 to 38 Lumber for decks, fencing , outdoors 38 39 To assess the carbon pool storage in each part of a tree, which in turn helps to select tree type to achieve maximum carbon storage, the COLE-EZ version of the COLE software was used. The information regarding the selection of COLE-EZ over other tools for this project is provided in Chapter 2. COLE originated as a collaborative project between the National Council for Air and Stream Improvement Inc. (NCASI) and the United States Department of Agriculture (USDA) Forest Service, Northern Research Station (USDA Forest Service, 2013). The COLE-EZ 1605b Forest Carbon Reporting Tool is a flexible web-based tool for forest carbon analysis that can be used to generate forest carbon inventory estimates for any area of the continental United States. Carbon estimates (Metric tons carbon per hectare) generated in COLE-EZ are derived from a comprehensive public database of forest plot measurements from over 100,000 forested plots all over the continental United States maintained by the USDA Service Forest Inventory and Analysis (FIA) program. COLE-EZ covers all trees species that are encountered at different locations. The carbon analyses are established by fitting equations to data through combinations of state, county, year and other filters categorized in Table 3.5. The carbon calculations are based on methods described in Smith et al. (2006). 40 Table 3.5- Categorical Variables Available in COLE-EZ for the Filtering Analysis Variables State / County Owner / Owner Group Forest Type/ Forest Group Productivity Class/ Stand size Land Clearing Status Measurement Year Stand Age Class Stand Origin Description County where forest will be located Selection of land ownership classes Type of forest or kind of forest trees Having capacity to grow crops of industrial wood. It classifies diameter class of trees (large diameter is >11.0 inches for hardwoods and > 9.0 inches diameter for softwoods; medium diameter is > 5.0 inches and small diameter is < 5.0 inches). Afforestation is selected if this stand is established on nonforest land, otherwise use the reforestation option Year at which data for trees taken, if applicable. Selection of reporting year Planting or artificial seeding Variables selected for this study Yolo, California Private Douglas fir/ Ponderosa pine/ Redwood Unstocked Afforestation Variable Variable Planted Reports are generated in form of tables to reflect selection of filters giving a breakdown of carbon stored into the component pools as explained in Section 2.2.1. Figure 3.3 shows a sample report generated in COLE-EZ giving information on carbon stocks (tons/acre or metric tons/hectare) in each part of the tree for base year (start year) and reporting year (end year) and the change in carbon stored between base and reporting years. Figure 3.3: Sample Report Generated by COLE-EZ 41 42 Reports of carbon storage in each carbon pool at intervals of 5 years up to the end of the growth cycle were generated for Douglas fir, Ponderosa pine and redwood as summarized in Table 3.6, Table 3.7 and Table 3.8 respectively. Graphs in Figure 3.4, Figure 3.5 and Figure 3.6 show cumulative carbon sequestered in metric tons/tree for each pool over time in 5-year increments. Table 3.6 - Cumulative Carbon Storage in Different Pools (in Metric Tons of carbon per tree) Generated using COLE-EZ for Douglas fir Year Live Tree 5 10 15 20 25 30 35 40 1.8 9.2 20.5 32.9 44.5 54.5 62.6 69 Non-standing Tree Biomass 21.5 19.4 18.4 17.8 13.4 17.3 17.1 17 Soil (1m) Total Carbon 31.9 32.2 32.7 33.3 34.1 35 35.9 36.8 55.1 60.8 71.6 84 92 106.7 115.6 122.8 Carbon sequestration Metric Tons/tree 140 120 100 Live Tree 80 Non-standing Tree Biomass 60 Soil (1m) 40 20 Total C 0 0 10 20 30 40 50 Years Figure 3.4- Graph of Carbon Storage in Different Pools for Douglas fir 43 Table 3.7- Cumulative Carbon Storage in Different Pools Generated (in Metric Tons of carbon per tree) using COLE-EZ for Ponderosa pine Year Live Tree 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 0.3 1.9 4.8 8.4 12.3 16.1 19.8 23 25.8 28.2 30.3 31.9 33.3 34.4 35.3 36.1 36.7 37.2 37.5 37.8 38.1 38.3 Non-standing Tree Biomass 15.7 14.7 13.2 12.6 12.5 12.5 12.6 12.8 13 13.1 13.3 13.4 13.5 13.6 13.6 13.7 13.7 13.7 13.8 13.8 13.8 13.8 Soil (1m) Total Carbon 14.1 14.2 14.4 14.7 15 15.4 15.8 16.2 16.6 17 17.3 17.6 17.8 18 18.2 18.3 18.4 18.5 18.6 18.6 18.6 18.7 30.1 30.8 32.4 35.7 39.8 44 48.2 52 55.4 58.3 60.9 62.9 64.6 66 67.1 68.1 68.8 69.4 69.9 70.2 70.5 70.8 44 Carbon sequestration Metric Tons/tree 80 70 60 Live Tree 50 40 Non-standing Tree Biomass 30 Soil (1m) 20 Total C 10 0 0 50 100 150 Years Figure 3.5- Graph of Carbon Storage in Different Pools for Ponderosa pine Table 3.8- Cumulative Carbon Storage in Different Pools (in Metric Tons of carbon per tree) Generated using COLE-EZ for Redwood Year Live Tree 5 10 15 20 25 30 35 40 45 50 55 60 5.4 25.3 51.8 77.3 98.3 114.4 126.2 134.5 140.2 144.2 146.9 148.7 Non-standing Tree Biomass 10.4 18.2 24.3 29.1 32.9 35.7 37.8 39.42 40.6 41.536 42.33 42.8 Soil (1m) Total Carbon 22.2 22.4 22.8 23.2 23.8 24.4 25.04 25.6 26.2 26.8 27.3 27.8 38 65.9 98.9 129.6 155 174.5 189 199.5 207 212.5 216.5 219.3 45 Carbon sequestration Metric Tons/Acre 250 200 Live Tree 150 Non-standing Tree Biomass 100 Soil (1m) 50 Total C 0 0 20 40 60 80 Years Figure 3.6- Graph of Carbon Storage in Different Pools for Redwood The analysis shows that trees store more carbon per year while they are growing as opposed to when they are mature. Proper harvesting ages for each tree were determined by looking at the maximum average growth rates of carbon storage shown in Table 3.9. The average growth rate is calculated by dividing the cumulative storage by the growing time (e.g. for Douglas fir at 30 years the rate would be 54.5/30 = 1.82 metric tons/acre/year). Harvesting at this time would utilize the full benefits of the growth stages because average growth rate decreases after this time. Similarly, the harvesting ages of Ponderosa pine and redwood should be at 40 years and 25 years respectively as shown in Table 3.9 and Figure 3.7. 46 Table 3.9- Determination of Harvesting Age of each Selected Trees Years Douglas fir Ponderosa pine Redwood Cumulative Carbon Storage in Live Tree (MT/acre) Average Carbon Sequestration Growth Rate (MT/acre) Cumulative Carbon Storage in Live Tree (MT/acre) Average Carbon Sequestration Growth Rate (MT/acre) Cumulative Carbon Storage in Live Tree (MT/acre) Average Carbon Sequestration Growth Rate (MT/acre) 5 1.8 0.36 0.33 0.07 5.4 1.08 10 9.2 0.92 1.92 0.19 25.3 2.53 15 20.5 1.37 4.75 0.32 51.8 3.45 20 32.9 1.65 8.37 0.42 77.3 3.87 25 44.5 1.78 12.3 0.49 98.3 3.93 30 54.5 1.82 16.1 0.54 114.4 3.81 35 62.6 1.79 19.8 0.57 126.2 3.61 40 69.0 1.73 23 0.58 134.5 3.36 45 25.8 0.57 140.2 3.12 50 28.2 0.56 144.2 2.88 55 30.3 0.55 146.9 2.67 60 31.9 0.53 148.7 2.48 65 33.3 0.51 70 34.4 0.49 75 35.3 0.47 80 36.1 0.45 85 36.7 0.43 90 37.2 0.41 95 37.5 0.39 100 37.8 0.38 105 38.1 0.36 110 38.3 0.35 47 Average Annual Growth Rate (tons/acre) 4.50 4.00 3.50 3.00 2.50 Douglas 2.00 Ponderosa 1.50 redwood 1.00 0.50 0.00 0 20 40 60 80 100 120 Years Figure 3.7- Graph showing Average Annual Growth Rate for Selected Trees 3.4 Water Balance and Storage Requirement The following sections describe slow rate wastewater treatment design factors that would affect the hydraulic loading rate used to irrigate the forest under study, and calculations of the acreage that could be irrigated with and without wastewater storage. 3.4.1 Slow Rate System Design Factors As discussed in Section 3.1, this project is a slow rate (SR) land treatment system. There are two basic types of SR systems (USEPA, 2006). Type I, Maximum Hydraulic Loading, involves applying the maximum amount of water to the least possible land area, a “treatment” system. In Type 2, Optimum Irrigation Potential, water is applied to match the crop or vegetation requirements. In essence this is an irrigation or “water reuse” system with treatment capacity being of secondary importance. In this study, Type 2 is chosen so that trees receive water optimally to maximize carbon uptake. The water 48 balance equation which provides the hydraulic loading rate based on leaching requirements is (Reed et al., 1988): Lag = (ETc − Pr )(1 + LR) ( 100 E ) (3.1) where Lag = hydraulic loading due to tree requirements, in/month Pr = design precipitation, in/month ETc = crop evapotranspiration, in/month LR = leaching requirement, fraction E = efficiency of the irrigation system Overall irrigation efficiency (E) is the fraction of applied water that becomes available to the plants. Typically, 70 to 85% efficiency is commonly achieved using sprinkler irrigation (USEPA, 2006). Crop evapotranspiration (ETc) is the sum of plant transpiration and evaporation from plant and soil surfaces. The design ETc rate is an important component in the water balance for both crop production and water quality concerns. A high water loss due to ETc will tend to increase the concentration of constituents in the percolate. Crop evapotranspiration (ETc) is commonly estimated based on measured Pan evapotranspiration (ETo) and a crop coefficient (Kc) representing the specific crop and growth stage. ETc = ETo·Kc where ETo = Pan evapotranspiration, in/month Kc = Crop coefficient (3.2) 49 Historical data for monthly pan evapotranspiration (ETo) and monthly precipitation (Pr) in inches/month were obtained from the Parameter-Elevation Regressions on Independent Slopes Model (PRISM) (Orang et al., 2013). These were used in the Simulation of ET of Applied Water (Cal-SIMETAW) application program, which was developed as a cooperative effort between the University of California (UC) and the Department of Water Resources (DWR) (Orang et al., 2013). The data are shown in Table 3.10 and Table 3.11 respectively. Historical data for monthly average pan evaporation (Epan) were obtained from the California Climate Date Archive as shown in Table 3.12 (Western Regional Climate Center, 2008). The crop coefficient, Kc for conifers is 1.0 for all seasons (FAO, 1988). Table 3.10- Average Monthly Pan Evapotranspiration, ETo in Inches for City of Davis Period of Record Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Annual 1921-2010 1.49 2.34 4.54 7.13 10.19 12.17 12.77 11.28 9.08 6.35 2.89 1.45 81.68 Source- Data from the Cal-SIMETAW model using daily PRISM grid (4 X 4 Km) over Davis, UC Davis Biometrology Program (Orang et al., 2013) Table 3.11- Average Monthly Precipitation, Pr in Inches for City of Davis Period of Record Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Annual 1921-2010 3.92 3.87 2.77 1.17 0.56 0.2 0 0.05 0.26 0.9 2.36 3.54 19.6 Source- Data from the Cal-SIMETAW model using daily PRISM grid (4 X 4 Km) over Davis, UC Davis Biometrology Program ( Orang et al., 2013) Table 3.12- Average Pan Evaporation, Epan in Inches for City of Davis Period of Record Jan Feb Mar Apr May 1917-2002 1.49 2.34 4.51 7.09 10.16 Jun 12.2 Jul 12.8 Aug Sep Oct 11.29 9.07 6.37 Nov 2.89 Dec 1.45 Annual 81.66 Source- Data from the California Climate Data Archive (United States Western Regional Climate Center, 2008) 50 51 The leaching requirement (LR) is the volume of deep percolation expressed as a fraction of the applied water (USEPA, 2006). The leaching requirement is incorporated in the study because if leaching is inadequate, harmful amounts of salt can accumulate in the soil within a few cropping seasons. If the salt concentration exceeds the crop’s salt tolerance threshold level, leaching is required to restore full productivity. Depending on the degree of salinity control required, leaching may occur continuously or intermittently at intervals of a few months to a few years. Where leaching is insufficient, crop losses may become severe over time. Soil reclamation will be required before crops can be grown economically again. The economical way to control soil salinity is to ensure that the amount of salt added as irrigation water must equal the amount drained to maintain salt balance. Hoffman (1985) created a graph (Figure 3.8) relating Crop Salt Tolerance Threshold Value (ECe), salinity of the applied water (Ca), and leaching requirement (LR). Figure 3.8 is based on the results from several models run to calculate leaching requirements (Tanji, 1990). 52 Figure 3.8- Leaching Requirement as a Function of Applied Salinity and ECe of Crop Salinity Threshold (Tanji, 1990) To find the leaching requirement, threshold salinity values (ECe) for the trees under consideration were combined with the wastewater salinity. The ECe values used are listed in Table 3.13. Table 3.13- Threshold Salinity of Douglas fir, Ponderosa pine and Redwood (Tanji, 2000) Trees Douglas fir Ponderosa pine Redwood Threshold Salinity (ECe) 2 dS/m 6 dS/m 2 dS/m Slight tolerance Moderately high tolerance Slight tolerance 53 To be conservative, the salinity of applied water (Ca) was assumed to be 1500 µS/cm, i.e. 1.5 dS/m, as indicated in Table 2.7. Using threshold salinities given in Table 3.13 and 1.5 dS/m of salinity in the applied water, the leaching requirements shown in Table 3.14 were estimated using Figure 3.8. Table 3.14- Leaching requirement of Douglas fir, Ponderosa pine and Redwood Trees Leaching Requirement (LR) Douglas fir 0.145 Ponderosa pine 0.04 Redwood 0.145 The limiting design parameter, hydraulic loading rate, is based on either (1) crop water requirements, which include the leaching requirement and irrigation efficiency, or (2) nitrogen limitations, as discussed next. The removal of nitrogen in land treatment systems is complex and dynamic due to the many forms of nitrogen in wastewater (organic-N, NH3, NH4, NO2, and NO3) and the relative ease of changing from one oxidation state to another. The nitrogen present in typical municipal wastewater is usually present as organic nitrogen (about 40 percent) and ammonia/ammonium ions (about 60 percent). Typically, only a portion of the ammonia nitrogen in municipal wastewater is nitrified and the major nitrogen fraction in most effluents is in the ammonium form (USEPA, 2006). Activated sludge and other high-rate biological processes can be designed to convert the entire ammonia content to nitrate (nitrification). As discussed earlier, the City of Davis is planning to adopt high-rate biological treatment for secondary treatment to achieve nitrification. 54 Because all forms of nitrogen can be oxidized to nitrate and excessive nitrogen is a health risk in groundwater, it is important in the design of slow rate land treatment systems to identify the total concentration of nitrogen in the wastewater. Experience with SR treatment processes demonstrates that the less oxidized the nitrogen is when entering the land treatment system the more effective will be the retention and overall nitrogen removal (USEPA, 2006). The soil-plant system provides a number of interrelated responses to wastewater nitrogen as shown in Figure 3.9 (USEPA, 2006). The organic nitrogen fraction, usually associated with particulate matter, is entrapped or filtered out of the applied liquid stream. The ammonia fraction can be lost by volatilization, taken up by the crop or adsorbed by the clay minerals in the soil. Nitrate can be taken up by the vegetation, or converted to nitrogen gas via denitrification in macro- or micro-anaerobic zones and lost to the atmosphere. Nitrate can also be leached through the soil profile to the underlying groundwater. 55 Figure 3.9- Nitrogen Cycle in the soil (USEPA, 2006) The U.S. primary drinking water standard for nitrate is set at 10 mg/L as nitrogen (USEPA, 2009). When potable aquifers, sole source aquifers, or wellhead protection areas are involved, the current guidance requires that drinking water standards be met at the land treatment project boundary (USEPA, 2006). As a result, nitrogen often becomes the limiting design parameter for slow rate systems. There are safety factors inherent in the following approach that ensures a conservative design. The procedure assumes that all of the applied nitrogen will be converted to nitrate (i.e., complete nitrification) within the same time period assumed for water application (no time lag or mineralization of ammonia) and that there is no mixing or dispersion with the in-situ groundwater which 56 would lower the concentration before the groundwater crosses the project boundary (USEPA, 2006). Because nitrogen stored within the biomass of trees is not uniformly distributed among the tree components, the amount of nitrogen that can actually be removed from the site with a forest crop system will be substantially less than the estimated nitrogen storage unless 100 percent of the aboveground biomass is harvested (whole-tree harvesting). If only the merchantable stems are removed from the system, the net amount of nitrogen removed by the system will be less than 30 percent of the amount stored in the biomass (USEPA, 1981). The estimated annual nitrogen uptake (U) of forest ecosystems in selected regions of the United States is presented in Table 3.15 (Crites et al., 2000). Whole-tree harvesting is recommended to maximize nitrogen removal provided it takes place in the summer when the needles are on the trees. The role of the understory vegetation is particularly important in the early stages of tree establishment. Forests take up and store nutrients and return a portion of those nutrients back to the soil in the form of leaf fall and other debris such as dead trees. Upon decomposition, the nutrients are released and re-absorbed by the trees. During the initial stages of growth (1 to 2 years), tree seedlings are establishing a root system, and biomass production and nutrient uptake are relatively slow. To prevent leaching of nitrogen to groundwater during this period, nitrogen loading must be limited or understory vegetation must be established that will take up and store applied nitrogen that is in excess of the tree crop needs(USEPA, 2006). 57 The calculation to determine nitrogen limitations involves estimating an allowable hydraulic loading rate based on an annual nitrogen balance (Ln), and then comparing that to the previously calculated hydraulic loading rate based on crop needs and leaching rate (Lag) to determine which value controls. The USEPA Process Design Manual (USEPA, 1981) describes allowable annual hydraulic loading rate based on nitrogen limits using the following equation, Ln = 𝐶𝑝 (𝑃𝑟−𝐸𝑇𝑐)+(𝑈)(4.413) 𝐶𝑛 (1−𝑓)−𝐶𝑝 (3.3) where Ln = Allowable annual hydraulic loading rate based on nitrogen limits, in/month Cp = Nitrogen concentration in percolating water, mg/L Pr = Precipitation rate, in/month ETc = Crop Evapotranspiration rate, in/month U = Nitrogen uptake by crop, lbs/acre-year Cn = Nitrogen concentration in reclaimed wastewater, mg/L f = Fraction of applied nitrogen removed by denitrification and volatilization. 4.413 - unit conversion factor. The limiting percolate nitrogen concentration, Cp is set at 10 mg/L which is the nitrogen limit allowed in groundwater (CDPH, 2013). Monthly precipitation (Pr) and monthly evapotranspiration rate ( ETc) are given in Tables 3.10 and 3.11 respectively. 58 Table 3.15- Nitrogen Uptake for Selected Forest Ecosystems with Whole Tree Harvesting (USEPA, 2006) Eastern forests: Mixed hardwoods Red pine Old filed with white spruce plantation Pioneer succession Aspen sprouts Tree Age, Years Average Annual Nitrogen Uptake, lb/(acre-year) 40-60 25 200 100 15 5.15 - 200 200 100 Southern forests: Mixed hardwoods 40-60 250 Loblolly pine with no understory 20 200 Loblolly pine with understory 20 250 Lake states forests: Mixed hardwoods 50 100 Hybrid poplara 5 140 Western forests: Hybrid poplara 4-5 270 Douglas fir plantation 15-25 200 a Short-term rotation with harvesting at 4 to 5 years; represents first-growth cycle from planted seedlings These rates are considered maximum estimates of net nitrogen uptake including both the understory and overstory vegetation during the period of active tree growth. Average annual nitrogen uptake (U) is assumed 200 lb/ (acre-year) for all the trees based on value given for Douglas fir plantation in Table 3.15. Monthly average nitrogen uptake is assumed to be proportional to growth as indicated by evapotranspiration and is calculated by Equation 3.4. 𝑈𝑚𝑜𝑛𝑡ℎ = ( 𝐸𝑇𝑚𝑜𝑛𝑡ℎ 𝐸𝑇𝑦𝑒𝑎𝑟 ) 𝑈𝑦𝑒𝑎𝑟 (3.4) As described previously, the City received a new NPDES permit for the WPCP that requires compliance with a number of effluent requirements by October 25, 2017 (City of Davis, 2013). In response, the City has developed effluent performance criteria, 59 which are constituents and associated concentrations that shall be achieved when the treatment plant is upgraded. These criteria are listed in Table 3.16. Table 3.16- Process Effluent Performance Criteria for Future Effluent Requirements for the WPCP (City of Davis, 2013) Constituent Units NH4-N mg/L NO3-N plus NO2-N mg/L BOD mg/L TSS mg/L Design/Performance Criteria Summer Monthly Average: 1.3 Winter Monthly Average: 1.7 Monthly Average:10 Monthly Average: 10 Weekly Average: 15 Monthly Average: 10 Weekly Average: 15 Process Secondary Treatment Secondary Treatment and Tertiary Filtration Monthly average effluent concentrations of total nitrogen (Cn) which is sum of NH4-N, NO3-N, and NO2-N from the upgraded secondary treatment process are 11.3 (10 + 1.3) mg/l in summer and 11.7 (10 + 1.7) mg/l in winter as indicated in Table 3.16. The organic nitrogen concentration is assumed to be negligible because it has been converted to ammonium and then to nitrate (USEPA, 2006). A nitrogen loss factor (f) has been developed to account for nitrogen lost to denitrification, volatilization, and soil storage. When the wastewater contains a high carbon-to-nitrogen (C:N) ratio, significant denitrification can occur (USEPA, 2006). Because of the large influence of organic carbon on available nitrogen, the nitrogen loss factor (f) varies as a function of C:N as shown in Table 3.17. Actual losses are dependent on other factors including climate, forms of the nitrogen applied and application method. 60 Table 3.17- Nitrogen Loss Factor for Varying C:N Ratios (Reed et al., 1988) C:N ratio Example f >8 Food processing wastewater 0.5-0.8 1.2-8 Primary treated effluent 0.25-0.5 0.9-1.2 Secondary treated effluent 0.15-0.25 <0.9 Advanced treatment effluent 0.1 Given the amount of nitrification through the secondary process proposed by the City, there will be little BOD left in the effluent and as shown in Table 3.17 the C:N ratio is expected average about 1.05 (midpoint of 0.9- 1.2) and the corresponding nitrogen loss factor (f) assumed in this study is 0.2 (midpoint of 0.15-0.25). As denitrification varies with temperature, the nitrogen loss factor varies by about a factor of 2 for a 10 ºC temperature change (Heinen, 2005). Accordingly, in this study f is assumed to be 0.2 for spring and fall, 0.1 for winter reflecting a 10 ºC temperature drop and 0.3 for summer representing a 10 ºC increase from average. 3.4.2 Hydraulic Loading Based on Slow Rate Wastewater Treatment Using derived values for all the variables in the SR system design equations, monthly values of Lag (Equation 3.1) were calculated and compared with Ln (Equation 3.3). The lower of the two values was used to determine the design monthly hydraulic loading rates (Ld). Because the soil at the study area is mostly silty clay, a check was performed to assure that the design hydraulic loading (Ld) does not exceed the percolation rate (Pcalc) given by Equation 3.5 nor the maximum percolation rate of 10 in/month which is the field percolation rate measured near the study area (City of Davis, 2005). 61 Pcalc = Ld – ETc + Pr (3.5) Where Pcalc= Percolation rate, in/month Ld = Design hydraulic loading rate, in/month ETc = Crop Evapotranspiration rate, in/month Pr = Precipitation rate, in/month Using the design hydraulic loading rate, the nitrogen concentration in percolating water (Cpcalc) was calculated with Equation 3.6. The percentage of the tree nitrogen requirement met by the wastewater influent after accounting for denitrification losses (%Napplied) was calculated with Equation 3.7. Cpcalc = 𝐿𝑑 𝐶𝑛 (1−𝑓)−(𝑈𝑚𝑜𝑛𝑡ℎ )(4.413) 𝑃𝑐𝑎𝑙𝑐 %Napplied = 𝐿𝑑 𝐶𝑛 (1−𝑓) (𝑈𝑚𝑜𝑛𝑡ℎ )(4.413) (3.6) (3.7) Tables 3.18 shows the monthly parameters for irrigating Douglas fir and redwood and Table 3.19 shows the monthly parameters for irrigating Ponderosa pine, calculated using this procedure. Table 3.18- Estimation of Monthly Hydraulic Loading Rate for Irrigating Douglas fir and Redwood 1 2 3 4 Hydraulic Loading Rate Average Crop Evapo- Based on Month Precipitation Transpiration Tree Water Requirements LR=0.145 5 6 7 8 9 10 11 Fraction of Hydraulic Applied Calculated Potential Nitrogen Loading Design Nitrogen Calculated Nitrogen Nitrogen Concentration Rate Hydraulic Removed by Percolation Concentration Uptake in Applied Based on Loading Denitrification Rate in Percolating by Tree Water Nitrogen Rate and Water Limit Volatilization Pr, (in) ETc, (in) Lag, (in) Umonth, (lbs/acre) Cn, (mg/L) f Ln, (in) Ld, (in) Pcalc, (in) Jan 3.20 1.04 0.00 4.7 11.7 0.1 80.09 0.00 2.17 0.1 92.84 0.00 0.2 no limit 0.76 Cpcalc, (mg/L) 12 Percentage of Tree Nitrogen Requirement Met by Influent (minus Nitrogen Lost to Denitrification) %Napplied 0 1.58 <0 <0 0.20 <0 14 3.91 1.01 <0 45 Feb 3.24 1.67 0.00 7.6 11.7 Mar 2.05 2.62 0.76 11.9 11.7 Apr 1.11 4.02 3.91 18.3 11.7 0.2 no limit May 0.40 5.37 6.70 24.4 11.3 0.2 no limit 6.70 1.73 <0 56 Jun 0.11 6.43 8.50 29.2 11.3 0.3 no limit 8.50 2.19 <0 52 2.36 <0 53 2.07 <0 53 1.56 <0 59 46 0 Jul Aug Sep 0.01 0.02 0.13 6.80 5.99 4.64 9.15 8.04 6.07 30.9 27.2 21.1 11.3 11.3 11.3 Oct 0.79 2.88 2.81 13.1 11.7 Nov 1.83 1.58 0.00 7.2 11.7 Dec 2.86 0.99 0.00 4.5 11.7 0.3 0.3 0.2 no limit no limit no limit 9.15 8.04 6.07 0.2 no limit 2.81 0.72 <0 0.2 no limit 0.00 0.25 <0 72.68 0.00 1.86 <0 0 0.1 0 15.76 44.02 45.95 200.0 45.95 Column 8 - Equation 3.3. equals to infinity if Cn(1-f)<Cp Column 9 - The smaller of columns 4 and 8. Column 11 - Calculated Nitrogen concentration in percolating water after applying design hydraulic loading rate is negative indicating that more nitrogen is removed by denitrification and volatilization (included in the f factor) than the amount that is applied. 62 Table 3.19- Estimation of Monthly Hydraulic Loading Rate for Irrigating Ponderosa pine 1 2 3 4 Hydraulic Loading Rate Average Crop Evapo- Based on Month Precipitation Transpiration Tree Water Requirements LR= 0.04 5 6 7 8 9 10 11 Fraction of Hydraulic Applied Calculated Potential Nitrogen Loading Design Nitrogen Calculated Nitrogen Nitrogen Concentration Rate Hydraulic Removed by Percolation Concentration Uptake in Applied Based on Loading Denitrification Rate in Percolating by Tree Water Nitrogen Rate And Water Limit Volatilization Jan 3.20 1.04 0.00 Feb 3.24 1.67 0.00 7.6 11.7 0.1 92.84 Mar 2.05 2.62 0.69 11.9 11.7 0.2 no limit 0.69 0.13 <0 12 Apr 1.11 4.02 3.55 18.3 11.7 0.2 no limit 3.55 0.65 <0 41 1.11 <0 51 1.41 <0 47 1.52 <0 48 48 May Jun Jul ETc, (in) Lag, (in) 0.40 0.11 0.01 5.37 6.43 6.80 6.09 7.72 8.31 24.4 29.2 30.9 11.3 11.3 11.3 Aug 0.02 5.99 7.30 27.2 11.3 Sep 0.13 4.64 5.51 21.1 11.3 Oct 0.79 2.88 2.56 13.1 11.7 Nov 1.83 1.58 0.00 7.2 11.7 Dec 2.86 0.99 0.00 4.5 11.7 Cpcalc, (mg/L) Percentage of Tree Nitrogen Requirement Met by Influent (minus Nitrogen Lost to Denitrification) Umonth, (lbs/acre) 4.7 Pr, (in) Cn, (mg/L) 11.7 12 f Ln, (in) Ld, (in) Pcalc, (in) 0.1 80.09 0.00 2.17 1.58 <0 <0 0 0.00 0.2 0.3 0.3 no limit no limit no limit 6.09 7.72 8.31 %Napplied 0 0.3 no limit 7.30 1.33 <0 0.2 no limit 5.51 1.01 <0 54 0.2 no limit 2.56 0.47 <0 41 0.2 no limit 0.00 0.25 <0 0 0.1 72.68 0.00 1.86 <0 0 15.76 44.02 41.74 200.0 41.74 Column 8 - Equation 3.3. equals to infinity if Cn(1-f)<Cp Column 9 - The smaller of columns 4 and 8. Column 11 - Calculated Nitrogen concentration in percolating water after applying design hydraulic loading rate is negative indicating that more nitrogen is removed by denitrification and volatilization (included in the f factor) than the amount that is applied. 63 64 Regardless of which tree is considered, it can be seen in Tables 3.18 and 3.19 that calculated percolation rates (Pcalc) are far less than the measured percolation rate of 10 in/month. Negative values of calculated nitrogen concentration in percolating water (Cpcalc) indicate that more nitrogen is removed by denitrification and volatilization (included in the f factor) than the amount that is applied. 3.4.3 Hydraulic Loading based on Maximizing Tree Growth As it can be seen in Section 3.4.2, using the standard SR design approach does not fully satisfy the nitrogen requirement for tree growth as shown in column 12 (%Napplied) of Tables 3.18 and 3.19. This shows that the design hydraulic loading rates do not provide enough nitrogen to accommodate the full growth potential of the trees. To maximize tree growth, the hydraulic loading rate should be increased to the point that the nitrogen requirement of the tree is met, subject to prevention of groundwater contamination. In this strategy, water is applied in excess of the water requirement of the crop. The hydraulic loading rate is set to meet nitrogen requirement of the tree after denitrification ( Lnreq) obtained by Equation 3.8 instead of the Ln that was used in previous tables. (𝑈𝑚𝑜𝑛𝑡ℎ )(4.413) Lnreq = 𝐶𝑛 (1−𝑓) (3.8) To assure adequate drainage, the hydraulic loading rate is limited by percolation rate calculated by Equation 3.9. Lp = ETc – Pr – Pmax where the maximum percolation rate, Pmax = 10 in/month (3.9) 65 The smaller of the two hydraulic loading rates (Lnreq and Lp) values was used to determine the design monthly hydraulic loading rate ( Ld). Nitrogen loading (minus denitrification), Uloading is determined by Equation 3.10. Uloading = 𝐿𝑑 𝐶𝑛 (1−𝑓) 4.413 (3.10) Using the design hydraulic loading rate, the nitrogen concentration in percolating water (Cpcalc) was calculated with Equation 3.6 except using Uloading in place of Umonth and checked against the 10 mg/L limit(Cp) . Table 3.20 shows adjusted monthly hydraulic loading rates based on meeting the nitrogen requirements of Douglas fir and redwood. Table 3.21 shows adjusted monthly hydraulic loading rates based on meeting the nitrogen requirements of Ponderosa pine. As can be seen, the calculated nitrogen concentration in the percolate water was always zero because the nitrogen loading was based trees’ requirements. Table 3.20- Adjustment of Design Hydraulic Loading Rate to Meet the Nitrogen Requirement of Douglas fir and Redwood to Achieve Maximum Tree Growth 1 2 3 4 Hydraulic loading rate Average Crop EvapoMonth based on Precipitation Transpiration crop LR=0.145 5 6 7 8 Fraction Of Hydraulic Applied Potential Nitrogen Loading To Nitrogen Nitrogen Concentration Meet Removed by Uptake by in Applied Nitrogen Denitrification the Tree Water Requirement And of Tree Volatilization 9 10 11 Hydraulic Design Percentage of Loading Hydraulic Nitrogen Limited by Loading Requirement Percolation Rate Met Rate 12 Nitrogen Loading (Minus Denitrification) 13 14 Calculated Calculated Nitrogen Percolation Concentration Rate in Percolating Water Pr, (in) ETc, (in) Lag, (in) Umonth, (lbs/acre) Cn, (mg/L) f Lnreq, (in) Lp, (in) Ld, (in) %Napplied Uloading, (lb/acre) Pcalc, (in) Cpcalc, (mg/L) Jan 3.20 1.04 0.00 4.7 11.7 0.1 1.97 7.83 1.97 100 4.70 4.14 0.00 Feb 3.24 1.67 0.00 7.6 11.7 0.1 3.18 8.42 3.18 100 7.58 4.75 0.00 Mar 2.05 2.62 0.76 11.9 11.7 0.2 5.61 10.57 5.61 100 11.89 5.04 0.00 Apr 1.11 4.02 3.91 18.3 11.7 0.2 8.61 12.90 8.61 100 18.25 5.70 0.00 May 0.40 5.37 6.70 24.4 11.3 0.2 11.92 14.97 11.92 100 24.42 6.95 0.00 Jun 0.11 6.43 8.50 29.2 11.3 0.3 16.29 16.31 16.29 100 29.20 9.98 0.00 Jul 0.01 6.80 9.15 30.9 11.3 0.3 17.24 16.79 16.79 97 30.10 10.00 0.00 Aug 0.02 5.99 8.04 27.2 11.3 0.3 15.18 15.97 15.18 100 27.20 9.21 0.00 Sep 0.13 4.64 6.07 21.1 11.3 0.2 10.28 14.51 10.28 100 21.07 5.78 0.00 Oct 0.79 2.88 2.81 13.1 11.7 0.2 6.17 12.09 6.17 100 13.08 4.08 0.00 Nov 1.83 1.58 0.00 7.2 11.7 0.2 3.39 9.75 3.39 100 7.19 3.64 0.00 Dec 2.86 0.99 0.00 4.5 11.7 0.1 1.89 8.14 1.89 100 4.51 3.75 0.00 15.76 44.02 45.95 200.0 101.72 101.27 199.20 66 Table 3.21- Adjustment of Design Hydraulic Loading Rate to Meet the Nitrogen Requirement of Ponderosa pine to Achieve Maximum Tree Growth 1 Month 2 3 4 5 6 7 8 9 10 11 12 13 14 Fraction Of Hydraulic Hydraulic Applied Hydraulic Calculated Potential Nitrogen Loading To Design Percentage of loading Nitrogen Loading Nitrogen Calculated Nitrogen Average Crop EvapoNitrogen Concentration Meet Hydraulic Nitrogen rate based Removed by Limited by Loading (Minus Percolation Concentration Precipitation Transpiration Uptake by in Applied Nitrogen Loading Requirement on crop Denitrification Percolation Denitrification) Rate in Percolating the Tree Water Requirement Rate Met LR=0.04 And Rate Water of Tree Volatilization Pr, (in) ETc, (in) Lag, (in) Umonth, (lbs/acre) Cn, (mg/L) f Lnreq, (in) Lp, (in) Ld, (in) %Napplied Uloading, (lb/acre) Pcalc, (in) Cpcalc, (mg/L) Jan 3.20 1.04 0.00 4.7 11.7 0.1 1.97 7.83 1.97 100 4.70 4.14 0.00 Feb 3.24 1.67 0.00 7.6 11.7 0.1 3.18 8.42 3.18 100 7.58 4.75 0.00 Mar 2.05 2.62 0.69 11.9 11.7 0.2 5.61 10.57 5.61 100 11.89 5.04 0.00 Apr 1.11 4.02 3.55 18.3 11.7 0.2 8.61 12.90 8.61 100 18.25 5.70 0.00 May 0.40 5.37 6.09 24.4 11.3 0.2 11.92 14.97 11.92 100 24.42 6.95 0.00 Jun 0.11 6.43 7.72 29.2 11.3 0.3 16.29 16.31 16.29 100 29.20 9.98 0.00 Jul 0.01 6.80 8.31 30.9 11.3 0.3 17.24 16.79 16.79 97 30.10 10.00 0.00 Aug 0.02 5.99 7.30 27.2 11.3 0.3 15.18 15.97 15.18 100 27.20 9.21 0.00 Sep 0.13 4.64 5.51 21.1 11.3 0.2 10.28 14.51 10.28 100 21.07 5.78 0.00 Oct 0.79 2.88 2.56 13.1 11.7 0.2 6.17 12.09 6.17 100 13.08 4.08 0.00 Nov 1.83 1.58 0.00 7.2 11.7 0.2 3.39 9.75 3.39 100 7.19 3.64 0.00 Dec 2.86 0.99 0.00 4.5 11.7 0.1 1.89 8.14 1.89 100 4.51 3.75 0.00 15.76 44.02 41.74 200.0 101.72 101.27 199.20 67 68 The percentage of annual nitrogen demand (%Nsatisfied) is 99.6% for all the trees, derived by Equation 3.11comparing with estimated average annual nitrogen uptake shown in Table 3.16 that is satisfied by the application of wastewater. %Nsatisfied = ∑ 𝑈𝑙𝑜𝑎𝑑𝑖𝑛𝑔 𝑈𝑦𝑒𝑎𝑟 x 100 (3.11) 3.4.4 Water Balance Determination After determining the wastewater demand for tree irrigation, the next steps were to match the loading to the amount of water available from the secondary treatment system. Two strategies for irrigating trees were investigated: 1. Irrigating trees without the availability of any stored wastewater, meaning the area to be irrigated is limited by the maximum monthly wastewater flow. 2. Irrigating trees with winter storage so that the annual volume of wastewater can be used to maximize the area that can be irrigated. Population growth assumptions used in recent water supply planning studies were used to develop future wastewater flow projections (City of Davis, 2013). Specifically, it was assumed that WPCP influent flow and loads will increase at a rate of 0.5 percent per year through 2019, and then at a rate of 1.0 percent per year for 2020 and beyond. It was also assumed that the monthly pattern of wastewater influent flow for the period of 2009 through 2011 will be essentially the same as under current conditions. This assumption is reasonable given the extremely slow rates of growth in the city in recent years. A WPCP capacity based on 6.0 MGD average dry weather flow (ADWF) is expected to be 69 adequate through 2041 (i.e., providing three years for WPCP modification plus 25 years of operation). The projection conforms to the recommendation of the Charrette Report to construct a 6.0 MGD ADWF treatment process (City of Davis, 2013). An adjustment factor to convert average dry weather flow to annual average flow was developed based on historical influent flow data. The annual average flows (AAF) are presented in Table 3.22. Average dry weather flow (ADWF) is defined as the average of the three consecutive lowest monthly flows. Table 3.22- WPCP Improvements Project Design Flows (City of Davis, 2013) Flow Parameter Average Flows ADWF Average Annual Flow (AAF) Flow Value, MGD 6.0 6.6 The average annual flow (AAF) of 6.6 MGD was distributed by month based on the seasonal flow variation for the years 2000-2004 shown in Table 3.23. Two dominant factors affect seasonal flow variations: student population and rainfall. As indicated, the City of Davis is unusual in that a significant portion of the service area population is made up of students who attend the University of California at Davis (UC Davis). From mid-June through mid-September and in November and December, a significant portion of UC Davis students are on break and are absent from the community all or part of the time. WPCP influent flows are impacted and reduced by this periodic decrease in population. Influent flows to the WPCP are also influenced by the amount of infiltration and inflow (I&I) present in the influent due to rainfall. I&I are generally elevated during the wet season, which is defined as the period from November 1 through April 30 based on typical rainfall patterns in the city. The four seasonal flow conditions of interest are: 70 Wet Season: Significant Student Population (January 1 to April 30), Dry Season: Significant Student Population (May 1 to June 15 and September 21 to October 30), Dry Season: Minimal Student Population (June 16 to September 20), and Wet Season: Minimal Student Population (November 1 to December 31). Table 3.23- WPCP Seasonal Average Influent Flow Statistics for 2000-2004 (City of Davis, 2005) Seasonal Flow Condition, MGD Jan-1 to Apr-30 2000 2001 2002 2003 2004 Average 5.90 5.84 6.12 6.20 6.38 6.09 May-1 to Jun-15 and Sep-21 to Oct-30 5.83 5.72 5.84 6.08 6.07 5.91 Jun-16 to Sep-20 5.23 5.23 5.41 5.44 5.62 5.39 Nov-1 to Dec-31 (1) 5.51 5.50 5.56 5.53 5.54 5.53 Average 5.77 (1) Flows during the Thanksgiving and Winter Holiday break for UC Davis students are typically the lowest daily flows recorded in a given year period. The 6.6 MGD (AAF) is a 14% increase from historically average annual flow of 5.77 MGD based on 2000-2004 data. To predict the monthly flow pattern, the design flow (AAF) of 6.6 MGD was prorated throughout year according to the seasonal pattern in Table 3.23 distributed over a monthly time scale. The results are shown in Table 3.24 and Figure 3.10. 71 Table 3.24- Flow Prediction of Average Monthly Inflows through 2030 at WPCP Jan Feb Mar Apr May Jun Jul Aug Sept Oct Nov Dec Average Annual Flow Influent Flow Conditions Historically (Average of 2000 to 2004) 6.09 6.09 6.09 6.09 5.91 5.65 5.39 5.39 5.39 5.91 5.53 5.53 Flow Prediction of Average Monthly Inflows Through 2030 6.9 6.9 6.9 6.9 6.7 6.4 6.1 6.1 6.1 6.7 6.3 6.3 5.77 6.6 Figure 3.10- Seasonal Prediction of Average Monthly WPCP Inflows through 2030 72 3.4.5 Water Balance without Wastewater Storage This section presents the calculation of acreage that could be irrigated using effluent available from secondary treatment without any storage. The design hydraulic loading rate (Ld) that resulted from meeting the nitrogen requirements of the trees and projected average monthly flows through 2030 were used to determine the area that could be irrigated using the whole flow (Aw) each month according to Equation 3.12. Aw = 𝑉𝑑 ×𝑑𝑎𝑦𝑠 ×12 𝑖𝑛𝑐ℎ𝑒𝑠×3.069 𝐿𝑑 (3.12) Where Aw = Area needed to accommodate whole flow, Acres Vd = Design wastewater treated volume, MGD 3.069 is the conversion factor from million gallons to acre-feet. As shown in Table 3.27, only 415 acres could be irrigated in July regardless of the tree type chosen. Assuming 415 acres is irrigated throughout the year, the daily flow to irrigation (Qi) and the daily flow that must be discharged to Willow Slough (Qd) is calculated from Equation 3.13 and Equation 3.14. The results are shown in Table 3.25. Qi = 415 𝐴𝑐𝑟𝑒𝑠 × 𝐿𝑑 𝑑𝑎𝑦𝑠 ×12 𝑖𝑛𝑐ℎ𝑒𝑠×3.069 Qd = Vd –Qi (3.13) (3.14) Table 3.25- Determination of Acreage that could be Irrigated for Growing Different Trees without Storage Douglas fir, Ponderosa pine and Redwood Month Design Hydraulic Loading rate Design wastewater Area needed to accommodate Daily flow to irrigation* treated volume whole flow Daily flow to discharge Ld, (in) Vd, (MGD) Aw, (Acres) Qi, (MGD) Qd, (MGD) Jan 1.97 6.90 3997 0.72 6.18 Feb 3.18 6.90 2240 1.28 5.62 Mar 5.61 6.90 1405 2.04 4.86 Apr 8.61 6.90 886 3.23 3.67 May 11.92 6.70 642 4.33 2.37 Jun 16.29 6.40 434 6.11 0.29 Jul 16.79 6.10 415 6.10 0.00 Aug 15.18 6.10 459 5.51 0.59 Sep 10.28 6.10 655 3.86 2.24 Oct 6.17 6.70 1240 2.24 4.46 Nov 3.39 6.30 2053 1.27 5.03 Dec 1.89 6.30 3809 0.69 5.61 Total 101.27 78.30 1140 1240 48% 52% Annual Flow, (MG) % of annual volume * Values are based on irrigating 415 acres. 73 74 Under this strategy about 48% of the annual effluent volume would be utilized for irrigation and 52% of treated wastewater effluent would be discharged into Willow Slough, mainly in winter, regardless of tree type. 3.4.6 Water Balance with Wastewater Storage This approach allows for excess water to be stored in the 215 million gallons available in the existing wastewater treatment plant oxidation ponds, aeration ponds and the Lemna pond. The ponds cover a total of 119 acres and have a minimum depth of 5.5 feet. Storage of excess water in the winter will allow more acreage to be irrigated. Determining the irrigation area required an iterative approach. Initially the irrigated area was assumed to be the whole 770 acres of city land. The daily wastewater flow required to irrigate trees in 770 acres of land (Qi) using the design hydraulic loading rate (Ld) to meet the nitrogen requirements of the trees (Section 3.4.3) was calculated using Equation 3.15. Qi = 𝐴 × 𝐿𝑑 𝑑𝑎𝑦𝑠 ×12 𝑖𝑛𝑐ℎ𝑒𝑠×3.069 (3.15) Where Qi = Daily flow to irrigation, MGD A = Irrigated area, Acres 3.069 is the conversion factor from million gallons to acre-feet. Wastewater in excess of that needed by the crop (Qd) on a monthly basis was calculated using Equation 3.14. This volume was stored monthly as excess wastewater volume (Vst). The cumulative volume stored at the start of the month (VS) is equal to the 75 cumulative volume stored at the end of the previous month (Ve). Some of the stored wastewater would be lost to evaporation. To calculate this volume, the water surface in the storage ponds was needed. In actuality, each pond with its different dimensions (area) would fill up one after the other, i.e., not simultaneously but in series, and depths would vary. Since only a rough estimate of water loss through direct evaporation of pond was desired, the following approximate method was adopted. The pond area (As), the so-called “storage area”, required to hold the cumulative volume was calculated by Equation 3.16. As= Vi x 3.069 Dm (3.16) Where As = Storage area to accumulate cumulative volume, acres Vi = Cumulative volume stored, MG = 0.5 x (Cumulative volume stored at the start of month + Cumulative volume stored at the end of month without evaporation) = 0.5 x (Vs + (Vs + Vst)) Dm = Minimum depth of pond (storage), feet = 5.5 feet (from Table 2.5) The water surface area in the storage pond was estimated each month using Equation 3.16 with the average volume stored, neglecting evaporation. The maximum value allowed was 119 acres in accordance with existing facilities. Next the net pond evaporation, Ep in MG was calculated using Equation 3.17. ((Kp x Epan )−P𝑟 ) x As Ep = 12 inches x 3.069 (3.17) 76 where, Kp = Pan coefficient = 0.7 which is applicable to Class A pan (Kohler et al., 1955) Epan = Monthly average pan evaporation, inches (from Table 3.12) Pr = Monthly average precipitation, inches (from Table 3.11) Cumulative volume stored at the end of the month considering average evaporation (Ve) is calculated by Equation 3.18 Ve = Vs + Vst - Ep (3.18) Wastewater in excess of what can be stored due to the storage capacity being limited to 215 million gallon would be discharged or overflow (Vo) to Willow Slough. These volumes were calculated using Equation 3.21. Vo of current month = (Vs + Vst – Ep) in previous month – 215 (3.21) where 215 MG is maximum storage available through existing ponds mentioned in Table 2.5. Based on the initial water balance (area = 770 acres), it was seen that the pond would start accumulating excess water in September for all trees. Accordingly, the cumulative volume was set at zero at the beginning of this month and the water balance calculations were carried out for the following year. In a properly balanced system, the storage calculated at the end of August for all the trees should be zero. The ExcelTM Solver function was applied to adjust the area being irrigated (A) until this requirement was met. The calculations indicate that 569 acres of Douglas fir, Ponderosa pine and redwood could be irrigated with the monthly storage volumes shown in Table 3.26. Table 3.26- Determination of Area Irrigated for Douglas fir, Ponderosa pine and Redwood Using Wastewater Storage and Maximizing Nitrogen Applications to the Tree Crop 1 2 3 4 5 6 7 8 9 10 11 Storage Excess Excess Cumulative Area for Design Design Daily Wastewater Wastewater Volume end-ofIrrigated Wastewater Hydraulic Cumulative Net Pond Month Flow to (Not Sent Volume Stored at the month Area Treated Loading Volume Evaporation Irrigation to (Storage Start of The Volume Volume Rate* Stored Irrigation) In/Out) Month without Evaporation A, Vd, Ld, Qi, Qd, Vst, Vs, Vi, As, Ep, (Acres) (MGD) (in) (MGD) (MGD) (MG) (MG) (MG) Acres (in) Jan 569.0 6.9 1.97 0.98 5.92 183.46 215 307 119 -6.98 12 13 Cumulative Volume WasteStored at water end-of- discharged month with (overflow) Evaporation Ve, (MG) 215 Vo, (MG) 172.08 Feb 569.0 6.9 3.18 1.75 5.15 144.15 215 287 119 -5.19 215 190.44 Mar 569.0 6.9 5.61 2.79 4.11 127.31 215 279 119 3.57 215 149.34 Apr 569.0 6.9 8.61 4.43 2.47 74.07 215 252 119 12.44 215 123.74 May 569.0 6.7 11.92 5.94 0.76 23.59 215 227 119 21.69 215 61.63 Jun 569.0 6.4 16.29 8.39 -1.99 -59.60 215 185 103 23.64 132 1.90 Jul 569.0 6.1 16.79 8.37 -2.27 -70.26 132 97 54 13.11 48 0.00 Aug 569.0 6.1 15.18 7.56 -1.46 -45.32 48 26 14 3.07 0 0.00 Sep 569.0 6.1 10.28 5.29 0.81 24.16 0 12 7 1.14 23 0.00 Oct 569.0 6.7 6.17 3.07 3.63 112.42 23 79 44 4.40 131 0.00 Nov 569.0 6.3 3.39 1.75 4.55 136.64 131 199 111 0.58 215 0.00 Dec 569.0 6.3 1.89 0.94 5.36 166.13 215 298 119 -5.95 215 52.10 78.3 101.27 816.74 Annual Excess Wastewater -Annual Evaporation losses-Annual Overflow 65.52 751.22 = 0.00 MG Calculated Irrigated Area, A = 569.0 Acres *Design hydraulic loading rate based on maximizing tree growth calculated in Section 3.4.3 77 The total volume of wastewater treated would be 2381 million gallons per year. From Tables 3.28, it can be seen that for the Douglas fir, Ponderosa pine and redwood water balance, 751 million gallons of wastewater, i.e. 31% of total volume would be discharged to Willow Slough. 3.5 Agro-Forestry Management Plan Secondary treated wastewater, especially if it meets the nitrogen effluent quality planned by the City can be used to irrigate a carbon sequestration forest via a slow rate application system. Trees such as Douglas fir, Ponderosa pine and redwood are appropriate to cultivate for carbon storage. As shown in Tables 3.9, the harvesting ages of Douglas fir, Ponderosa pine and redwood should be 30, 40 and 25 years respectively. After harvest Douglas fir and Ponderosa pine must be replanted. Redwood can reproduce by coppice (from stump) or natural seeding (Birzer, 2010). Thinning at an intermediate age is recommended for Ponderosa pine and redwood trees to stimulate growth of the trees and maintain maximum biomass production. The purpose of thinning operation is to increase growing space so that trees do not have to compete for light, moisture, and nutrients (Roth, 1989). To achieve maximum nitrogen removal, whole tree harvesting must take place in the summer. Wood from branches and trunk should be used for lumber. Leaves and root systems should be sold for landscaping, although these uses do not create long-term sequestration. No part of tree or debris should be burned. Trees should be spaced 8-10 feet (Reukema, 1979) and the strip method for harvesting should be used in which 78 alternative rows of tree are harvested. According to Row (1996), the advantages of adopting this method are: 1. Equipment can be more easily operated in a strip. 2. Closer tree spacing may be used to achieve the desired nutrient uptake rates during initial rotation. 3. Uneven-aged trees will provide a consistent amount of carbon storage each year. 4. The gaps created between rows will allow the trees to have more sunlight and space which encourage growth. To achieve optimum distribution and water-use efficiency, micro-irrigation or sprinkler irrigation system could be used, but the decision would be based on economics. (Bastian and Ryan, 1986) 79 Chapter 4 DISCUSSION This Chapter discusses potential benefits of CO2 mitigation forest that was assessed with the help of above chapters, uncertainties and unsettled questions that were raised during this project and not covered due to scope of this project study. It is further suggested to research and evaluate the unsettled issues indicated by the study in detail before adopting CO2 sequestered forest as final reuse alternative. 4.1 Potential Benefits Using on the average annual growth rates presented in Table 3.9 for harvest times of 30, 40 and 25 years for Douglas fir, Ponderosa pine and redwood, respectively carbon uptakes for each kind of tree were calculated. The results are shown in Table 4.1. Redwood supports the highest carbon storage of 98.3 MT/Acre (3.93 x 25) with the shortest harvesting cycle of 25 years. The 2236 MT/year captured would store in approximately 279,500 board feet of marketable timber. Table 4.1-Annual Mass of Carbon Captured in Biomass Average Annual Rate Tree Type Harvest of Carbon Age Capture (MT/acre) Douglas fir Ponderosa pine Redwood Area Irrigated Without Storage (Acre) Annual Carbon Capture Without Winter Irrigation Storage (MT/yr.) Area Irrigated With Storage (Acre) Annual Carbon Capture With Winter Irrigation Storage (MT/yr.) 30 1.82 415 755 570 1036 40 0.58 415 241 570 330 25 3.93 415 1631 570 2236 80 For perspective, the total metric tons of carbon captured by this project (with storage) were compared with the estimated carbon emissions summarized in Table 4.2. Table 4.2- 2007-2010 CO2 Emissions of Davis, California (Sears, 2012) Year Emissions (Metric Tons CO2) Total Community Community Electricity Stationary Use Combustion Transportation Solid Water and Additional Waste Wastewater (Non- Energy Use Required) Sources 2007 361,451 75,674 64,678 195,748 9,202 2,683 13,466 2008 360,550 75,570 64,872 196,772 8,510 2,840 11,987 2009 352,517 69,077 65,563 197,621 7,817 2,057 10,381 2010 335,187 52,234 65,142 197,527 8,094 1,367 10,821 In Table 4.3, the carbon captured by this forest proposal is expressed as a percentage of the city’s 2010 carbon emissions in various sectors. Table 4.3- Percentage Community Carbon Emissions Potentially Offset by this Project 2010 Community Emissions of City of Davis Emissions (Metric Tons CO2) % of Carbon Sequestered through this Project Community Electricity Use Community Stationary Combustion Transportation Solid Waste Water & Wastewater Energy Use Additional (Non-Required) Sources 52,234 65,142 197,527 8,094 1,367 10,821 Total 335,185 4 3 1 28 164 21 0.7 As shown, the proposed forest has the potential to more than offset the city’s current CO2 emissions due to water and wastewater energy use, but as a fraction of the community’s total CO2 emissions, the offset by the forest is small. It should be noted that cultivating lumber within the city saves the carbon that is currently used to cut and 81 transport lumber from forests far away. This savings is not accounted for in these calculations. Neither are the CO2 emissions associated with forest management. In Table 4.4, the irrigated carbon sequestration forest is compared with other disposal/reuse options which the City examined the 2005 Master Plan discussed in Section 2.5. Table 4.4- Comparison of Forest Alternative with Reuse Alternatives Considered by City of Davis Level of Treatment Needed Year-Round Land Disposal/Reuse Seasonal agricultural reuse/storage Seasonal Reuse Demonstration reuse on cityowned lands Carbon Sequestration Forest Comparative Criteria Secondary 990 acres would be irrigated with 100 acres of storage. Significant purchase of land (more the 200 acres) required. Storage in existing ponds and wetlands. Marketable crop produced. 350 out of 770 acres would be irrigated with 3 to 5 acres of storage for demonstrating the usage to agricultural users in vicinity. 415 out of 770 acres could be irrigated without any storage. 570 out of 770 acres could be irrigated with storage in existing ponds. Marketable wood products produced. Tertiary Un-disinfected Secondary Based on the comparative characteristics listed in Table 4.4, the carbonsequestration alternative is more desirable for several reasons. 1. The forest alternative requires un-disinfected secondary effluent as discussed in Section 2.3.1. This is the lowest level of treatment of the three alternatives in Table 4.4, and is less stringent than the treatment required under the City’s 82 NPDES permit. This aspect would be a large advantage to the City because providing secondary treatment is less expensive than providing tertiary treatment. 2. No additional land is required to dispose of the city’s whole wastewater flow because a forest can accept more water than an agricultural crop. 3. No additional storage beyond the existing ponds would be required. 4. In addition of offsetting some of the city’s carbon emissions, the forest alternative could generate marketable timber. Wood-pulp and mulch from the remaining parts of the trees might also be marketable commodities. Another possible source of revenue would be the sale of carbon credits (Lubowski et al., 2006). 4.2 Uncertainties This study is a planning-level analysis and as such contains many uncertainties. One set of uncertainties involves input parameters. The population projection for determining the project design capacity was taken to be 1 percent per year as specified in the Charrette plan (City of Davis, 2013). The irrigated acreage estimated in the water balance will change if the population growth model is incorrect. Similarly, the wastewater generation pattern which depends on rainfall and students residing in the city could be incorrect since it is based on relatively few data. Changes in this parameter would affect the influent flow characteristics which are the basis of the water balance calculations. Another uncertainty is the performance of the proposed treatment plant upgrades. Changes in effluent characteristics, particularly the nitrogen content and salinity, would affect the calculation of allowable hydraulic loading rate, a key parameter for the water balance. 83 Site characteristics are also uncertain. Recent data on percolation and vertical transmissibility rates for the land proposed for this project are not available. Without these parameters, it would be difficult to determine if the trees are receiving the required irrigation depth and how much seepage is occurring beyond the irrigation depth under the proposed irrigation schedule. A percolation rate of 10 in/month (City of Davis, 2005) was applied to the water balance calculation. However, it is recommended to conduct percolation rate testing at the proposed site. Agronomic issues are a third set of uncertainties. One issue is the nitrogen concentration limitation to prevent groundwater contamination. The carbon estimation tool (COLE-EZ) and the nitrogen balance calculations used in this study do not model nitrogen transformations in detail. How much nitrogen can be absorbed by each tree (nitrogen requirement) and how much is removed in the soil (the “f” factor) were assumed and required to be verified. In the water balance, the hydraulic loading rate of each tree was increased above the water requirements to satisfy the trees’ nitrogen requirements and maximize tree. A check was performed to ensure that excess water would percolate beyond the irrigation depth of soil, but it is uncertain whether the trees can tolerate the over-watering. If not, then the hydraulic loading rate would have to be reduced and the area needed for irrigation increased. Another uncertainty is the growth and carbon sequestration potential of the proposed trees which are not native to the valley. The accuracy of potential carbon sequestration estimated by COLE-EZ needs to be verified for the redwood trees recommended in this project. Further research or a pilot study of irrigation techniques and scheduling, and planting, thinning and harvesting 84 operations are needed to determine how to obtain maximum carbon sequestration through optimum growth of non-native lumber trees. 4.3 Unsettled Questions Two issues not addressed in this study need to be settled before implementing this proposal. First, costs have not been estimated for the installation, operation and maintenance. Even though technically feasible, the City may not consider this to be a cost-effective way to reduce its net carbon emissions. Second, the design assumes that wastewater discharges to Willow Slough can be discontinued at certain periods of the year when the whole wastewater flow would be diverted to irrigation. Further investigation is recommended to determine whether this could pose a problem regarding the maintenance of minimum flow standards established by the Regional Water Quality Control Board. 85 Chapter 5 CONCLUSION The option of growing a carbon sequestration forest for the City of Davis was assessed in this project. Douglas fir, Ponderosa pine and redwood were determined to be potential tree crops based on an evaluation of the climate, site characteristics and potential ability of each tree for maximum long-term carbon sequestration. The proposed forest irrigation would require only un-disinfected secondary recycled water under California laws and regulations. Potential threats to groundwater such as nitrogen or salinity could limit the land application of treated wastewater. For that reason, water balances were performed using slow rate land treatment design procedures which take into account the nitrogen balance and salinity (leaching requirement). The design was controlled by the nitrogen requirements of the trees. Based on a 6.6 MGD average annual design capacity of system, annual wastewater application rates, areas that could be brought under irrigation with or without storage, and annual carbon sequestration masses were calculated. These are shown in Table 5.1. Table 5.1- Hydraulic Loading and Irrigated Area Results Trees Douglas fir Ponderosa pine Redwood Annual Hydraulic Loading Rate Area Irrigated without Storage Carbon Sequestration by Irrigating Land Owned by City of Davis without Storage Area Irrigated with Storage Carbon Sequestration by Irrigating Land Owned by City of Davis with Storage Lh (inches/year) Acres MT/Year Acres MT/Year 101 415 755 570 1036 101 415 241 570 330 101 415 1631 570 2236 86 Redwood trees are the recommended species to be cultivated because they capture greatest mass of carbon/acre/year. 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