Types of chemical reactions • Imagine that you are baking some cookies at home. • You follow a recipe • In the same way chemists know that elements and compounds undergo particular type of chemical reactions • How do you classify elements? • Chemical famillies • Members react in a similar way How do we classify compounds? Ionic or molecular - Have definite patterns of chemical properties. • Chemists use these patterns to classify groups of chemical changes • 4 categories • • • • Synthesis Decomposition Single displacement Double displacement • Why is it useful to have any knowledge of of the types of reactions? • We can better understand experimental observations. • We can predict products of unknown reactions Look at the reactants represented below, which reaction involves elements as reactants? Which reaction involves compounds as reactants? Synthesis reaction A synthesis reaction involves the combination smaller molecules Decomposition reaction A decomposition reaction involves the breaking apart of larger molecules Recognizing the types of reactants is key to identifying the reaction type LETS US LOOK AT TWO OF THE REACTION TYPES:SYNTHESIS AND DECOMPOSITION Synthesis Reactions • Involve the combination of smaller atoms and /or molecules into larger molecules. • They are also called combination reactions • General formula • A + B AB • If you see two elements as reactants, you know the reaction has to be a sysnthesis reaction • Most of these elements are represented as single atoms, but some occur naturally as diatomic molecules. For example, hydrogen and oxygen gases react to produce water hydrogen + oxygen H2 + O2 Element Diatomic molecule Hydrogen H2 Oxygen O2 Nitrogen N2 Fluorine F2 Chlorine Cl2 Bromine Br2 iodine I2 2H2 + O2 water H2O 2H2O • Synthesis reactions can also involve combinations of small molecules. • For example, when ammonia and hydrogen chloride vapours combine, they form a white smoke as solid particles of ammonium chloride are formed. Hydrogen chloride + ammonia ammonium chloride HCl + NH3 NH4Cl Similarly, combination of water and carbon dioxide molecules Synthesis reaction CO2 + H2O H2CO3(aq) TYPICAL EXAMPLE , RAINWATER Decomposition Reactions • It involve the splitting of • Example, electrolysis of a large molecule into water uses electricity to elements or smaller split water molecules molecules. into their elements water hydrogen + oxygen • General formula H2O H 2 + O2 AB A+ B 2H2O 2H2 + O2 • Sometimes it involves large amounts of energy. • Nitrogen triiodide decomposes rapidly to form the elements nitrogen and iodine nitrogen triiodide • NI3 • 2NI3 nitrogen + iodine N2 + I2 N2 + 3I2 • Can also involve the production of two small molecules from a large molecule • When ammonium nitrate is heated to above 250oC, it decomposes explosively to form nitrous oxide and water molecules • NH4NO3 N2O + H2O • NH4NO3 N2O + 2H2O Single Displacement Reactions Mg + AgNo3 Ag + Mg(NO3)2 • Are chemical changes that involve an element Mg + 2AgNO3 2Ag + Mg(NO3)2 and a compound as reactants. • One element displaces or replaces another element from the compound. • Example, when magnesium ribbon is placed in a solution of silver nitrate Example, when the element bromine is added to a solution of calcium iodide • the bromine displaces (or takes the place of) the iodide ion •bromine + calcium iodide • Br2 + CaI2 iodine + calcium bromide I2 + CaBr2