Introduction Chemistry: The study of matter and its changes Chemistry investigates and explains the sub-microscopic reasons for the what happens in the macroscopic world! Introduction Sub-microscopic understanding leads to understanding of the world around you: How does bleach remove stains? What causes and air bag to inflate? Why does DNA have a double helical structure? What makes a rose smell sweet and old fish smell awful? Introduction How does radio-carbon dating tell how old a fossil is? What are electrolytes and why do sports drinks like Gatorade contain them? What happens to garbage in a landfill? Is it always better to use biodegradable materials? Introduction Why should YOU study chemistry? Required for your college major Pre-med Pre-pharmacy Pre-dental Biology Geology Environmental Science Engineering Nursing Psychology English BSW/MSW Fine Arts Pre-Law Introduction Chemistry is the foundation of other sciences Physics Biology Geology Astronomy Chemistry impacts our daily lives! Food, clothing and shelter Health care Environment Life itself Measurement Metric System Quantity Unit Unit Symbol Length meter m Mass gram g Volume liter L Time second s Temperature Kelvin or degree celsius K or oC Prefixes every student should know… Prefix Symbol Means.. Example micro- millionth g milli- m thousandth mL centi- c hundredth cg kilo- k thousand km More prefixes… couldn’t hurt to know these ones, too: Prefix Symbol Means.. Example mega- M million ML giga- G thousand million GA Benefits of the Metric System: • Uses Decimal System • International Standard • The units relate to each other by using water as standard! (What does that mean?) “the units relate to each other… 1cm3 = 1 mL therefore , (10cm)3 = 1 L 1000 cm3 = 1 L http://www.metricamerica.com …by using water as a standard”: 1 kg H2O ≈ 1 L H2O ≈ (10 cm)3 H2O ≈ 1000 cm3 H2O 1g H2O ≈ 1 mL H2O http://www.metricamerica.com/images/Export00_288.mov Volume is special because: • Volume can be measured in liters (L), milliliters (mL), etc. s or… OR… • Volume can be measured in cubic meters (m3) centimeters (cm3), …..etc. Remember; 1 cm3 = 1 mL Remember any geometry? • Volume of a cube is …. lxwxh i.e. 4cm x 5cm x 2cm = 40 cm3 •Volume of a cylinder is …. 2 r h i.e. x (5cm)2 x 10cm = 250 cm3 Typically, mL or L are used to describe the volume of a liquid... …and cm3 or m3 are used to describe the volume of a regularly shaped solid. Volume of a Rock… To find the volume of objects with weird shapes, use a technique called “water displacement” in this case,the volume of the solid may be in cm3 or mL Remember: 1 cm3 = 1 mL Determining the Volume of an Irregularly Shaped Solid 22 mL 32 mL Temperature is special because… We will sometimes use degrees celsius… …we sometimes will use kelvin. Example K C F Boiling Point of Water 373 100 O 212 O Body Temperature 310 37 O 98 O Freezing Point of Water 273 0O 32 O Absolute Zero 0 -273 o -459 O Meters, Liters, Grams, Seconds…. These are units you should be familiar with. In chemistry,we will use math to do weird things to these nice units… …and turn them into units that are complex. Complex units like…. g/mL and 2 kg•m/s Math with Units… Examples: 5 • 5 = 25 3m • 4m = 12 m2 12m2 ÷ 12m = 1m 4 kg • 2 m/s2 = 8 kg•m/s2 10 L•atm ÷ 2 mol•K = 5(L•atm)/(mol•K) Example: Density Density is a property of matter. If you measure the mass (g) and the volume (mL) of an object, you can calculate it’s density using the formula: D = m/v Density = mass/volume So, the units of density must be…. g/mL Complex Units come from a formula… • Why is density measured in g/mL? (aka “grams per milliliter”) (not “gee slash em-ell”) Because the formula for density is m mass (in grams) g D = ----- = ------------ -------------- ---v volume (in milliliters) mL Brick is more dense than Styrofoam because there is more mass packed into the same volume (more molecules or atoms in the same space.) DENSITY Styrofoam Brick Substance • Air • Wood (Oak) • Steel •Water Density (g/mL) 0.0013 g/mL 0.80 g/mL 7.80 g/mL 1.00 g/mL Atoms of some elements are more dense than others. Density of Gold: 19.30 g/mL Silver: 10.50 g/mL Aluminum: 2.70 g/mL DENSITY - an important and useful physical property Density mass (g) volume (cm3) Mercury Platinum Aluminum 13.6 g/cm3 21.5 g/cm3 2.7 g/cm3 Variations of the Density Formula: D = m/v m D v v = m/D m=v•D Application: Calculate the density of a 57.9g sample of metal with a volume of 22.45mL. Application: • Calculate the mass of 4,800 mL of molten lead (density = 11.4g/mL)? •What is the mass in kg? Application: • A camelbak backpack hold 1 kg of water. What is the volume of the backpack? Application: • Molten iron (Fe) has a known density of 7.87 g/cm3. What would be the volume of 595 kg of molten iron, in liters? Metric System Quantity Unit Unit Symbol Length meter m Mass gram g Volume liter L Time second s Temperature Kelvin or degree celsius K or oC Prefixes every student should know… Prefix Symbol Means.. Example micro- millionth g milli- m thousandth mL centi- c hundredth cg kilo- k thousand km Typically, mL or L are used to describe the volume of a liquid... …and cm3 or m3 are used to describe the volume of a regularly shaped solid. Temperature is special because… We will sometimes use degrees celsius… …we sometimes will use kelvin. Example K C F Boiling Point of Water 373 100 O 212 O Body Temperature 310 37 O 98 O Freezing Point of Water 273 0O 32 O Absolute Zero 0 -273 o -459 O Example: Density Density is a property of matter. If you measure the mass (g) and the volume (mL) of an object, you can calculate it’s density using the formula: D = m/v Density = mass/volume So, the units of density must be…. g/mL