Advanced Placement Chemistry Syllabus Texts: Chemistry The Central Science 11th ed. Theodore Brown, H. Eugene LeMay, Jr, Bruce E. Bursten, Catherine Murphy. Pearson Prentice Hall.2009 Solutions to Red Exercises Chemistry The Central Science. Roxy Wilson. Pearson Prentice Hall. 2009 Units of Study: (Chapters and problems refer to Brown, LeMay Bursten and Murphy 11th ed) Summer Assignment Chapter 1: Matter and Measurement Topics: Significant Figures, Measurement, Dimensional Analysis, Density, Organization of Matter Homework Assignment: pgs 30-33 #12, 18, 20, 30, 36, 40, 44 Chapter 2: Atoms, Molecules and Ions Topics: Atomic Theory, Law of Definite Proportions, Law of Multiple Proportions, Ions, Nomenclature Homework Assignment: pgs 70–74 # 10, 20, 26, 32, 38, 50, 58, 60, 66, 68, 70, 72, Trimester 1 Chapter 3: Stoichiometry: Calculations With Chemical Formulas and Equations Topics: Calculating Average Atomic Mass, Molar Mass, Percent Composition, Empirical Formulas, Combustion Analysis, Stoichiometry, Limiting Reagent, Percent Yield Lab: Hydrates Gravimetric Determination of Phosphorous in Plant Food Demos: Instant Rust, 500 + 500 = 1018, Black Magic Homework Assignment: pgs. 109-115 # 6, 8, 14, 24, 36, 50, 52, 54, 62, 70, 72, 74, 78, 88, Chapter 4: Aqueous Solutions and Solution Stoichiometry Topics: Polarity of Water, Solubility, Strong and Weak Electrolytes, Nonelectrolytes, Molarity, Making Dilutions, Precipitation Reactions, Solution Stoichiometry, Acid-Base Reactions, Titrations, Redox Reactions Lab: An Activity Series Identifying an Unknown Hydrogen Carbonate Activity: Learn The Solubility Song Homework Assignment: pgs. 156-160 #2, 16, 20, 22, 26, 38, 50, 52, 70, 76, 84, 88 Chapter 25: The Chemistry of Life: Organic and Biological Chemistry Topics: Hydrocarbons, Alkanes, Alkenes, Alkynes, Aromatics, Isomers, Functional Groups, Simple Organic Reactions Homework Assignment: pgs. 1098-1102 #12, 18, 26, 40, 86 Reaction Review Topics: Synthesis, Decomposition (nonredox), Single Replacement, Combustion, Redox by Common Agents, Double Displacement, Complexation, AcidBase Reactions, Lewis Acid-Base Reactions, Decomposition (redox), Solubility Rules Homework Assignment: Weekly equation sets from old AP exams Chapter 10: Gases Topics: Pressure, Boyles’ Law, Charles’ Law, Avogadro’s Law, Combined Gas Law, Gas Stoichiometry, Ideal Gas Law, Dalton’s Law, Kinetic Molecular Theory, Real Gases vs. Ideal Gases Labs: Molar Volume of a Gas Molar Mass of a Volatile Liquid Demos: Pop Your Top, Smelly Balloons, Shrinking Balloons, The White Ring, Potato Gun, Vacuum Gun, Crushed Can, Egg in a Bottle, Vacuum Pump Expansions Homework Assignment: pgs 426-433 #1, 6, 9, 24, 26, 40, 50, 52, 54, 62, 68, 76, 82, 84, 106 Chapter 15: Chemical Equilibrium Topics: Gas Equilibrium, Solution Equilibrium, Applications of K, Calculation of Equilibrium Concentrations, LeChatelier’s Principle Lab: Modeling Dynamic Equilibrium with Coins Determination of Keq for FeSCN2+ Demos: Equilibrium Demo with Pennies, Oxides of Nitrogen Equilibrium Tubes, Chemical Equilibria of Silver Ions Homework Assignment: pgs. 658-662 #2, 3, 7, 8, 10, 16, 30, 32, 38, 40, 44, 52, 61 Chapter 16: Acids-Base Equilibria Topics: Bronsted-Lowry Model, pH Scale, Weak Acids, Ka, Weak Bases, Kb, acidity of Salt Solutions, Lewis Acids and Bases Labs: Determination of the Equivalent Mass and pKa of an Unknown Acid LeChatelier’s Principle Demos: A Voice Activated Reaction, MOM to the Rescue, The Tortoise and the Hare, Rainbow Tube, Velcro Acids and Bases, Hydrolysis of Salts, Indicator Sponge Video: World of Chemistry – The Proton in Chemistry Homework Assignment: pgs. 709-715 #2, 4, 8, 18, 22, 28, 40, 46, 48, 52, 58, 62, 76, 78, 86, 94, 102 Trimester 2 Chapter 17: Additional Aspects of Aqueous Equilibria Topics: Buffers, Acid-Base Titrations, Choice of Indicator, Solubility Equilibrium Labs: Preparation and properties of buffer solutions Indicators, pH and Titrations Determining the Solubility Product Constant of Calcium Hydroxide Demos: Now You See It Now You Don’t Homework Assignment: pgs. 758-762 #3, 4, 5, 6, 9, 22, 28, 32, 36, 38, 42, 44, 50, 54, 56, 58, 64, 68 Chapter 14: Chemical Kinetics Topics: Reaction Rate, Order of Reaction, Rate Laws, Activation Energy, Reaction Mechanisms, Catalysts Lab: Flipping Pennies and Burning Candles Kinetics of a Reaction Kinetics of the Fading of Phenolphthalein in Alkaline Solution Demos: Dragon Breath, Elephant Toothpaste, Plop, Plop Fizz Fizz, Funneling Ahead, Paper Clip Catalyst Videos: Weird Weird Science – Grain Elevator Explosion, Oscillating Clock Reaction; Heath Kinetics - #32 – 35 Activity: Game - Depletion Homework Assignment: pgs. 615-622 #2, 3, 5, 7, 9, 22, 26, 30, 32, 36, 40, 52, 56, 64, 66, 68, 74 Chapter 5: Thermochemistry Topics: First Law of Thermodynamics, Enthalpy, Calorimetry, Hess’s Law, Standard Heats of Formation Lab: Specific Heat of a Metal Determining the Enthalpy of a Chemical Reaction Demos: Boiling water in a paper cup, freezing flask to wood block, burning magnesium Homework Assignments: pgs. 202-206 #7, 8, 10, 26, 42, 44, 48, 52, 54, 56, 62, 64, 70, 74 Chapter 19: Chemical thermodynamics Topics: State Functions, Spontaneous Reactions, Entropy, Gibbs Free Energy, Relationship between Free Energy and Equilibrium Videos: Heath #4-8 Homework Assignment: pgs. 833-839 #2, 3, 6, 14, 42, 50, 52, 54, 64, 66, 76, 78, 80 Chapter 20: Electrochemistry Topics: Salt Bridge Cell, Standard Voltages, Strengths of Oxidizing and Reducing Agents, Relationship Between E, ΔG, and K, Nernst Equation, Electrolytic Cells, Commercial Cells Labs: Electrochemical Cells Determination of Iron Content by Redox Titration Demos: The Can Ripper, The O.J. Clock, Hot Dog Salt Bridge Videos: Heath #25-27, 44, 46; Pickle Light, World of Chemistry – The Busy Electron Homework Assignment: pgs. 883-889 #3, 5, 6, 22, 34, 36, 42, 46, 52, 54, 60, 64, 88 Electrochemical Logic Puzzle Chapter 6: Electronic Strutcure or Atoms Topics: Electromagnetic Spectrum, Bohr Model, Quantum Numbers, Electron Configurations Lab: Atomic Spectroscopy Planet Xeno Lab Demo’s: The Atom Dazer, Energy Stored in a Crystal Homework Assignment: pgs. 247-250 #12, 14, 22, 36, 42, 64, 66, 68 Quantum Theory Challenge Chapter 7: Periodic Properties of the Elements Topics: Effective Nuclear Charge, Sizes of Atoms and Ions, Ionization energy, Electron Affinity Homework Assignment: 290-292 #24, 28, 42, 50, 52, 60, 66 Trimester 3 Chapter 8: Basic Concepts of Chemical Bonding Topics: Ionic Bonding, Lattice Energy, Covalent Bonding, Bond Energy, Lewis Structures, Formal Charge, VSEPR Theory, Molecular Geometry, Polarity Lab: Molecular Shapes and Structures Demo’s The Suspended Paper Clip, The Great Marble Race Homework Assignment: pgs. 333-336 #4, 12, 24, 40, 46, 52, 54, 62, 66 Chapter 9: Molecular Geometry and Bonding Theories Topics: Valence Bond Theory, Hybridization, Sigma and Pi Bonds Homework Assignment: pgs. 383-387 #2, 8, 36, 48, 52, 56, 58 Chapter 11: Intermolecular Forces, Liquids, and Solids Topics: Intermolecular Forces, Phase Diagrams Labs: Evaporation and Intermolecular Attractions Liquid Chromatography Homework Assignment: pgs. 471-476 # 2, 5, 6, 16, 26, 32, 34, 48, 54, 56, 72, 74 Chapter 21: Nuclear Chemistry Topics: Band of Stability, Alpha, Beta, and Gamma Particles, Fission, Fusion, Mass Defect and Binding Energy, Half Life, Nuclear Reaction Activity: Game – Nucleogenesis Homework Assignment: pgs. 925-929 #8, 18, 28, 34, 44, 77 Lab: 14 Test Tube Lab Chapter 13: Properties of Solutions Topics: Concentration Units, Colligative Properties: Boiling Point Elevation, Freezing Point Depression, Osmosis, Vapor Pressure; Colligative Properties in Electrolytic solutions Labs: Using Freezing Point Depression to Find Molecular Weight Demo: Is It Full?, Instant Slush Homework Assignment: pgs. 563-568 #2, 7, 10, 16, 20, 24, 26, 30, 32, 44, 58, 62, 70, 76 Colligative Logic Puzzle Review and Practice for AP Exam Project preparation for Family Science Fun Night Grading: Term grading is calculated as a ratio of total points scored out of total possible points. Tests will generally be worth 100 points, labs and quizzes 20-30 points and problem sets 10-20 points. Tests: Tests are compiled from old released AP questions and are given covering two chapters at a time. In between, take-home quizzes are given. Extra test points on the multiple choice section are awarded for showing corrections to wrong answers. Half of the missed points can be regained. Laboratory: We have 5 periods per week of 62 minutes in duration. There is no double lab period but our longer classes make up for this. Class is also scheduled to back up to our “seminar” period and students may stay during that time to complete labs if necessary. Labs are predominantly of the “wet lab” variety. Students write up most labs in a bound lab notebook which is collected and graded one week after the lab is performed. Students work in pairs to complete the laboratory experiment but complete the lab write up independently. Homework: Depending on the assignment and the personality of the class, homework assignments may be assigned as problem sets to be completed over a period of time or they may be assigned nightly. Reaction sets are assigned each week.