Story A Magical Mystery Tour through Mr. Schrödinger’s Neighborhood Game Directions Game Preparation Game Pieces Play the game Objectives Credits Copyright Notice A Homemade PowerPoint Game By Courtney Boehlke UGA College of Education You’ve been Invited to an Electron Party…. Mr. Schrodinger is a famous physicist who developed the Schrodinger wave equation that is used to determine the location of any electron in an atom. Eψ = Ĥ ψ There are 4 parts (quantum numbers) that make up any electron’s address. Mr. Schrodinger has invited you to a party at his favorite element’s home. In order to get there you must follow his map of his neighborhood to find the party. In Mr. Schrodinger’s neighborhood addresses are given quantum numbers and electron configurations. Along the way you will meet many new and interesting elements as well as learn how about their electron’s addresses. Home Page Game Directions The goal of the game is to correctly answer all of the questions along the way and collect clues to the final address of Mr. Schrodinger’s party. You will also need to find hidden among the other elements the four parts of Mr. Schrodinger’s wave equation Eψ = Ĥ ψ. To play the game you have to go through the neighborhood by correctly answering the questions. Each time the player reaches an element’s home (click on the element’s home, not the red dot!), the player will have to answer a question. If you get the answer correct, the slide will tell you which way to proceed, some questions will allow you a chance to answer a bonus question where you have the chance to find the parts of the wave equation or the final destination. If you get a question wrong you have to go back to the previous question and try it again. You should take notes as you gather your information, note where you found each part of the wave equation. You will be given a periodic table to help. To win the game you must figure out the mystery element’s identity and collect all four parts of the wave equation. Start the game at the Universität of Wien (University of Vienna)- yellow house- Einsteinium. Note: you should only visit each house once. Use the red dots on the map as a guide to which house you should go to next when you get your directions. You should try to get to the party as quickly as possible so as not to miss the party. Return Game Preparation •Gameboard: Print out slide #5 for each student or team of students. You may also want to print out the game tokens from slide #7 or you may use any other tokens you wish. The parts to the wave equation are here too. You may want to place them on the game board to keep up with where you found them. •Answer Key: The answer key can be found on slide #8. Print it out for yourself. •Periodic Table: Print out the Periodic Table on slide #6 for students to use during the game. Home Page N W Which Way? E S P Game tokens E ψ Ĥ Home Page ψ N W Which Way? E S 10 Question 1 According to Bohr, electrons cannot reside at ______ in the figure below. Point A Point B Point C Point D Question 2 An electron for which n = 4 has more ___ than an electron for which n = 2. Spin Particle nature Wave nature Energy Question 3 A spherical electron cloud surrounding an atomic nucleus would best represent ______. A px orbital An s orbital A combination of px and py orbitals A combination of an s and a px orbital Question 4 The statement that no two electrons in the same atom can have the same four quantum numbers is ___. The Pauli exclusion principal Hund’s rule Bohr’s law The Aufbau principal Question 5 What is the element represented by the shell model to the right? (hint: it is a hard, brittle element, found in large amounts on the ocean floor. This element has many oxidation states and can be pink, black, green or dark purple. Too much of this element can cause a psychiatric condition with hallucinations.) Zn As Mn Cs Question 6 Principal Quantum Number (n): n = 1, 2, 3, …, ∞ Specifies the ____ of an electron and the ____ of the orbital Shape, number Shape, orientation Energy, shape Energy, size Question 7 The atomic sublevel with the next highest energy after 4p is _____. 4d 4f 5p 5s Question 8 If the s and p sublevels of the highest main energy level of an atom are filled, how many electrons are in this main energy level? 2 8 16 32 Question 9 The ion's electron configuration is the same as the nearest noble gas — the ion is said to be _______with the nearest noble gas. stable isoelectronic magnetic electronic Question 10 If electrons in an atom have the lowest possible energies, the atom is in the ____. Ground state Inert state Excited state Radiation-emitting state Question 11 The spin quantum number of an electron can be thought of as describing ______. The direction of electron spin Whether the electron’s charge is positive or negative The electron’s exact location in orbit The number of revolutions the electron makes about the nucleus per second Question 12 According to the Bohr model of the atom, the single electron of a hydrogen atom circles the nucleus ______. In specific, allowed orbits In one fixed orbit at all times At any of an infinite number of distances, depending on its energy Counterclockwise Question 13 How many electrons can occupy the s orbitals at each energy level? Two, if they have opposite spins Two, if they have the same spin one No more than eight Question 14 The change of an atom from an excited state to the ground state always requires________? Absorption of energy Emission of electromagnetic radiation Release of visible light An increase in electron energy Question 15 All of the following describe the Heisenberg uncertainty principal EXCEPT ____. It states that it is impossible to determine simultaneously both the position and velocity of an electron It is one of the fundamental principals of our present understanding of light and matter. It helped lay the foundation for the modern quantum theory It helps to locate an electron in an atom Question 16 The following is the correct electron configuration for which element? 1s22s22p63s23p63d64s2 Fluorine Iron Calcium Sulfur Question 17 Angular Momentum (Secondary, Azimunthal) Quantum Number (l): The secondary quantum number divides the shells into smaller groups of orbitals called sub-shells. The value of l also has a slight effect on the energy of the sub-shell; the energy of the sub-shell ______________. Changes so little that the effect doesn’t matter Fluctuates as electrons fill each shell decreases with l (s > p > d > f) increases with l (s < p < d < f) Question 18 Magnetic Quantum Number (ml): divides the sub-shell into individual orbitals which hold the electrons; there are ____orbitals in each sub-shell. Thus the s sub-shell has only one orbital, the p sub-shell has three orbitals, etc. 2(l )+1/2 2(l )+1 1/2(l )+1 2(m)+1 Question 19 A dumb-bell shaped electron cloud surrounding an atomic nucleus would best represent what? An s orbital A d orbital An f orbital A p orbital Welcome to the Party!! Schrödinger Max Planck Neils Bohr Albert Einstein de Broglie Planck photo: Courtesy of the Clendening History of Medicine Library Congratulations! You’ve reached Bonus Question #1 What is the electron configuration (using the Nobel gas configuration) of Vanadium? [Ar] 3d3 4s2 [Ar] 3s2p6d3 4s2 [Ar] 4d3 4s2 [Kr] 3d3 4s2 Congratulations! You’ve reached Bonus Question #2 The letter designations for the first four sublevels with the maximum number of electrons that can be accommodated in each sublevel are ______ s:2, p:4, d:6, and f:8 s:1, p:3, d:5, and f:7 s:2, p:6, d:10, and f:14 s:1, p:2, d:3, and f:4 Congratulations! You’ve reached Bonus Question #3 You’ve reached the home of Nitrogen. One of the most important elements on Earth. Nitrogen is a component of amino acids which make up proteins as well as being a component in DNA and RNA. Nitrogen is also the N in the explosive TNT ! Nitrogen bonds well with others. How many electrons will Nitrogen accept to form an octet? 5 3 8 2 Congratulations! You’ve reached Bonus Question #4 Electrons that are in the same orbital spin opposite each other. When this happens the electrons are paired. These substances are not attracted to magnets. When a substance is not attracted to a magnet it is defined as being______. diamagnetic antimagnetic paramagnetic dismagnetic Congratulations! You’ve reached Bonus Question #5 You’ve reached the home of Molybdenum. It is a transition metal that makes steel super resilient and heat resistant. It is also mixed with lead ores and its name means “like lead”. What is the electron configuration of Molybdenum? 1s2 2s22p6 3s23p63d10 4s24p64d4 5s2 1s2 2s22p6 3s23p63d10 4s24p64d6 1s2 2s22p6 3s23p63d10 4s24p64d5 5s1 1s2 2s22p6 3s23p63d10 4s24p6 5s25d4 Congratulations! You’ve reached Bonus Question #6 The Group IA and IIA metals also tend to _____of their valence electrons to form _____. Lose all, cations Fill all, neutral atoms Fill all, anions Lose all, anions Congratulations! You’ve reached Bonus Question #7 You have entered the home of Oxygen. A gas none of us could live without. Oxygen makes bonds with many other elements, including itself. What is the electron configuration of Oxygen (Nobel Gas)? [H]2s22p4 [He]2s22p4 [He]2s22p6 [He]2s22d4 Congratulations! You’ve reached Bonus Question #8 Radon forms a naturally occurring radionuclide when it gives off alpha particles. When this occurs it forms isotopes of Radon. What is the definition of an isotope? same atomic number but different numbers of neutrons same atomic weight but different numbers of neutrons same atomic number but different numbers of protons same atomic number but different numbers of electrons Congratulations! You’ve reached Bonus Question #9 French scientist Louis de Broglie theorized that ______ Electrons could have dual wave-particle nature Light waves did not have a dual wave-particle effect The natures of light and quantized electron orbits were not similar Bohr’s model of the hydrogen atom was completely correct Congratulations! You’ve reached Bonus Question #10 A quantum of electromagnetic energy is called a(n) _________. Electron Excited atom Photon Orbital Oh, I didn’t know that!! (1) You reached the home of Vanadium. It is a transition metal and is named after the Scandinavian Goddess for Beauty and Love. As you can see in the picture below, it makes many different colored solutions. Oxidation states of vanadium, from left +2 (lilac), +3 (green), +4 (blue) and +5 (yellow). Oh, I didn’t know that!! (2) Radon is a Nobel gas, meaning that it is largely resistant to chemical reactions. This is due to the fact that all elements in this group, Group VIII, have eight electrons in their outer shell (except for helium who’s outer shell is an s shell and is complete with only 2 electrons) Unlike other members of it’s family, Radon is radio active. It gives off harmful radioactive alpha particles. Also, unlike its other family members, it is not normally found in the atmosphere, but occurs in granite. Congratulations! You’ve found part of the address! n=3 Congratulations! You’ve found part of the address! l=0 Congratulations! You’ve found part of the address! mL = 0 Congratulations! You’ve found part of the address! ms = 1/2 Congratulations! You’ve found part of the formula! EE Congratulations! You’ve found part of the formula! ψ Congratulations! You’ve found part of the formula! ψ Congratulations! You’ve found part of the formula! Ĥ Correct! Go North, one block! Correct! Go South, one block! Correct! Go South, two blocks! Correct! Go East, one block! Correct! Go West, one block ! Correct! Go West, two blocks! Correct! Go back to the Universität (where you started) then west, two blocks! Congratulations! You have found the final address. The party is being held across the street at: 3,0,0,1/2 the electron configuration for this element is [Ne]3s1 Sorry! You went to the wrong address, try the same question again. Credits All teachers and students at non-profit schools can use, revise, or adapt this game at will at no cost on the condition that all prior designers are cited. • Originally designed by Courtney Boehlke, University of Georgia, 5/25/2010 Mr. Schrodinger’s Neighborhood. Home Page Educational Objectives • Grade Level – High School • Subject Area Objectives – Chemistry • SC3.f Relate light emission and the movement of electrons to element identification. • SC4. Students will use the organization of the Periodic Table to predict properties of elements. Home Page Copyright • • • Copyright 2010 Courtney Boehlke Permission to copy this game at no cost is granted to all teachers and students of non-profit schools. Permission is also granted to all teachers and students of non-profit schools to make revisions to this game for their own purposes, on the condition that this copyright page and the credits page remain part of the game. Teachers and students who adapt the game should add their names and affiliations to the credits page without deleting any names already there. Home Page