Name:__________________________________________________ Class:____________________ Unit 3 Chemistry Notes Democritus History and Experiments Conclusions or Discoveries -Comes from the time around __________ -Came up with the word _____________ -Ancient _________________ philosopher -He said that the atom was a small -He performed ____________ __________________________ molecule experiments during his time -It was the ____________ piece of matter Aristotle -_______________________ B.C -Stated that all matter was made up of -___________________ Philosopher __________________________________ -Used __________________ rather than -Views were unchallenged for _________ experiments years John Dalton -English school teacher who developed 1, All matter is made of _______________ the ________________________ in 1803 and indestructible atoms -Studied the masses of _______________ 2. Atoms of the _______________ and ____________________ and their element are identical ratios 3. Atoms of _________________ -Used _______________________ data elements are different to support his theory 4. Atoms of different elements combine in whole _______________________ and form compounds 5. Chemical reactions consist of the ________________________________ __________________________ of atoms. 1. Law of conservation of mass Mass (matter) is neither created or destroyed, just rearranged. Mass of reactants = mass of products J.J. Thompson History and Experiments Conclusions or Discoveries -Researched the atom back -Discovered ___________________ in___________ -Plum pudding model of the atom -He used a -(Chocolate Chip Cookie) __________________________ and observed the cathode ray is attracted to a positive (+) charge Observations When using a magnetic field, the rays bent away from the field Inferences When using electric fields the rays were attracted to the (+) field. When a small paddle wheel was placed in the path of the cathode rays the wheel was set in motion. Ernest Rutherford -Some of the most important discoveries -Discovered the ____________________ related to the atom were completed by -The nucleus is very _________________ Rutherford ______________ -His work was completed in__________ -The atom is mainly _______________ -________________________________ space James Chadwick Did work in __________ -Discovered the _________________, a Theorized there must be a ____________ neutral subatomic particle with relatively particle the same mass as a proton. -The masses of all atoms except ______________________ were known to be greater than the combined masses of their protons and electrons. ________________________– neutrally charged particle (no charge) ________________________ – made up of protons and neutrons Niels Bohr History and Experiments Conclusion or Discoveries -Bohr’s research on the atom was -Electrons _____________________ the completed in _______________________ nucleus -Still highly relevant today Draw Thompson’s Model Draw Bohr’s model Definitions ________________________ The smallest part of an element that upholds the chemical properties of that element _________________________ A substance that can’t be broken down into simpler chemical substances. ◦ What’s smaller: an atom or element? Subatomic Particle Electron Symbol Charge Location Mass Proton Neutron Periodic Table of Elements -Just like the 26 letters of the alphabet combine to form all the words in the English language, the 100 or so elements combine to form everything that exists in the world -About 90 of the elements on the PT are found naturally in nature, the rest have been created in a laboratory -Any material made of one type of atom is classified as an ______________________ -The Periodic Table is organized into rows and columns -Each vertical column is called a ____________________ or____________________ -Elements within the same group have similar properties EX. Au, Ag, Cu -Each horizontal row is called a ____________________ -Properties of the elements gradually change when you move through a period -Elements get smaller when you move from _________________ to ______________. How to Read the Periodic Table -Each element is designated by its _____________________________ -Some symbols do not match actual element name because they were named under their ________________________________, -The first letter of an atomic symbol is ____________________ and the second letter is _______________________ -The atomic number is the special I.D. of the element It can tell you how many _________________________ are in the element -_____________________have an electric charge _____________ -Electrons are _____________________________________________ in an element -_____________________ have an electric charge _____________ Atomic # = _______________________=________________________ -The atomic mass of an element is the number at the _______________of the square -Atomic mass is the sum of the __________________________________ in the atom -_____________________ have an electric charge ______________ Atomic mass = ______________________+_____________________ The _____________________ of an atom contains all the protons and neutrons Element 35 Cl 17 7 Li 3 MASS # ATOMIC # # PROTONS # NEUTRONS # ELECTRONS Isotopes -Atoms of the ________________________element that contain _________________ numbers of _______________________ are called Isotopes. -We identify isotopes by their ___________________________. The mass number is the total number of protons and neutrons it contains. Mass # = _______________________ + ________________________ One way to express isotopes Mass Number OVER Atomic Number The total number of neutrons in an isotope is to subtract its atomic number from the mass number. Mass number -Atomic Number Number of Neutrons Example How many Protons? How many Neutrons? How many Protons? How many Neutrons? Atomic mass is the ___________________________________ of an element and its various isotopes. Measured in ______________________________________ (amu) Example: Imagine 100 students take a test worth 100 points. If all students scored an 80 then the average would be an 80%. But what would happen if one student gets a 100%? It would raise the average slightly. Same thing happens with isotopes Element X has 45 protons and 50 neutrons, while Element Y has 50 protons and 45 neutrons Same, Different, Isotope? Element A has 13 protons and 15 neutrons, while Element B has 13 protons and 14 neutrons Same, Different, Isotope? Electromagnetic Spectrum All types of electromagnetic radiation share common characteristics: ◦ ____________________________ c - Speed of light (in a vacuum) = 3.0 x 108 m/s constant λ – ___________________________ ν - ____________________________ _____________________________________-set of frequencies of the electromagnetic wave emitted by atoms of the element. Each element is unique. Flame gives off colors Quantum Model The ____________________________ describes the probability of finding an electron in a given region of space called an _________________________. n = __________________________________ Major energy levels Larger n, the further away electron is from nucleus and the higher its energy Values of n are whole numbers from 1 infinity l = _____________________________________ Designates the shape of the orbital Values of l are whole numbers from l = 0 to n – 1 N=2 L= 0 n-1 L=0,1 L Value Letter Shape Ml= _____________________________________ Designates the orientation of the orbital in space Values of m are whole numbers: -l 0 +l For example, if l = 1 calculate m Therefore, m = -1, 0, +1 Ms=_____________________________________ Describes the direction of an electron’s spin Electrons spin on their axis either clockwise or counterclockwise Only two possible values: +1/2 or -1/2 Quantum numbers (n, l, ml, and ms) attempt to locate where electrons in an atom “should” be Quantum numbers are analogous to the information give on a ticket stub: Stadium, Section, Row, and Seat n=4 l= ml= ms= n=2 l= ml= ms= n=1 l= ml= ms= Electron Configuration and Orbital Notation We identify elements based on how the _____________ are arranged in __________. At least ____________shells and each shell can hold a certain amount of electrons. Draw the amount of electrons allowed in each shell Electron Configuration For full configuration you must have all prior parts as well! 2 2 5 Fluorine: 1s 2s 2p All adds up to 9! Francium 2 2 6 2 6 2 10 6 2 10 6 2 14 10 6 1 1s 2s 2p 3s 3p 4s 3d 4p 5s 4d 5p 6s 4f 5d 6p 7s All adds up to 87! The block method! Fill in the blocks Quick Review 1. What Element? What Period? Final part of configuration? 2. What Element? What Period? Final part of configuration? _______________________________ is a way to show how many electrons are in an orbital for a given element. They can be shown with arrows. Take what we just learned with electron configuration but take it a step further. Each line can hold up to _________ electrons. ◦ ◦ ◦ ◦ S= ____ P= ____ ____ ____ D= ____ ____ ____ ____ ____ F=____ ____ ____ ____ ____ ____ ____ ________________________________Principal A max. of two electrons can occupy each orbital and these electrons must have opposite spin ________________________________ Principal Electrons will occupy the lowest energy levels possible ________________________________Rule Electrons enter orbital's of the same energy one at a time before pairing up ◦ It is more STABLE to have the max. number of unpaired electrons Mole Conversions 23 1 mole of any substance has 6.02 x 10 atoms Avogadro’s number 1 mole of any substance is equal to its mass on the periodic table in grams. Molar mass How many atoms is 2.5 moles of Copper? How many grams is 2.22 x 1025 atoms of Zinc? Lewis Dot Structure Depending on what group they are in on the periodic table determines how many valence electrons they have. You cannot double up valence electrons until each side of the element has an electron Try creating Lewis Dot structures for the first 10 elements! H He C N Li O Be F B Ne Additional Notes _____________________________________________________________________ _____________________________________________________________________ _____________________________________________________________________ _____________________________________________________________________ _____________________________________________________________________ _____________________________________________________________________ _____________________________________________________________________ _____________________________________________________________________ _____________________________________________________________________ _____________________________________________________________________ _____________________________________________________________________ _____________________________________________________________________ _____________________________________________________________________ _____________________________________________________________________ _____________________________________________________________________ _____________________________________________________________________ _____________________________________________________________________ _____________________________________________________________________ _____________________________________________________________________ _____________________________________________________________________ _____________________________________________________________________ _____________________________________________________________________ _____________________________________________________________________ _____________________________________________________________________ _____________________________________________________________________