Unit 4- Mixture and Compounds Notes Model So Far….. • Key Concept 1: Everything has been a simple “pure” particle….. What are the two categories of “stuff” that exist? REVIEW FROM UNIT 1 c • Key Concept 2: Matter is anything made of atoms. • Matter has observable and measurable qualities. – Key Concept 3: Two basic types of properties of matter: physical properties and chemical properties. – Key Concept 4: All matter can undergo change: physical change or chemical change REVIEW FROM UNIT 1 Properties –Key Concept 5: Physical properties can be observed without changing the substance(use your senses). –Key Concept 6: Chemical properties are determined by trying to change the make-up of a substance (only evident at the particle level). RIVIEW FROM UNIT 1 Change – Key Concept 7: Physical change- the original substance still exists (its particles are still the same); it has simply changed form. – Key Concept 8: Chemical change- takes place on the molecular level and produces a new substance (chemical changes are accompanied by physical changes) (hard to undo). What are some properties of…. Sugar Salt Iron Key Concept 2: Water vs. Ethanol Property Appearance Odor Flammability Density Melting Point Boiling Point Chem/Phys Water Ethanol What happens to the properties if I mix water and ethanol? • Solubility? • Density? • Boiling points? • Physical Change, not chemical • Crude Oil and fractional distillation What happens if I mix sulfur (S) and iron (Fe) together? • Chemical Change Change and Properties • Key Concept 3: Physical change- mixed two particles together, but no reaction. – Some properties are the same as the original substance (MP and BP), and other are a mix of those properties(density). • Key Concept 4: Chemical change- mixed particles react to form a new product. – All the physical and chemical properties have changes. We made mixtures “Elemental” “Mixture” Is the new product a mixture? “Elemental” “Compounded” End of Day Key Concept 5 A type of matter Examples: steel, air, water, vegetable soup A type of matter Examples: steel, air, water, vegetable soup Homogenous Heterogeneous Characteristics of mixture Key Concept 6: Homogenous- “homo” same or alike Heterogeneous- “hetero” different A type of matter Examples: steel, air, water, vegetable soup Homogenous Heterogeneous Heterogeneous Mixture Heterogeneous Mixture Key Concept 7: Heterogeneous mixtures- are composed of large pieces that are easily separated by physical means. • You can see with your eyes (you might need a microscope for some) that the composition is not the same throughout • Components are distinguishable • Examples: fruit salad, vegetable soup, etc. Heterogeneous Mixture A type of matter Examples: steel, air, water, vegetable soup Homogenous Homogenous Mixture Heterogeneous Heterogeneous Mixture Homogenous Mixture Key Concept 8: Homogenous mixtures- looks the same throughout but can be separated by physical means. • If you break a piece of homogeneous matter into smaller pieces, each piece will have the same properties as every other small piece. • If you look at one of the pieces under a microscope, it is impossible to distinguish one part as being a different material from any other part. • Examples: air and glass Homogenous Mixture A type of matter Examples: steel, air, water, vegetable soup Homogenous Heterogeneous Homogenous Mixture Solution Heterogeneous Mixture Solution Everyday definition • Answer to a problem • A type of liquid Chemistry • Key Concept 9: Solution- uniform mixture that can contain solid, liquid, or gases Solution = Homogenous mixture They are synonyms How a solution is made? • Solution consist of a solvent and solute. • Key Concept 10: Solvent- the substance that dissolves the solute to form a solution; most plentiful substance in the solution. • Solute- one or more substance dissolved in a solution. How a solution is made? Important vocabulary Soluble Insoluble Alloy A type of matter Examples: steel, air, water, vegetable soup Homogenous Heterogeneous Homogenous Mixture Solution Solvent + Solute Heterogeneous Mixture A type of matter Examples: steel, air, water, vegetable soup Homogenous Pure Substance Heterogeneous Homogenous Mixture Solution Solvent + Solute Heterogeneous Mixture Pure Substance • Key Concept 11: Pure Substance- Consists of only one component with definite physical and chemical properties. A type of matter Examples: steel, air, water, vegetable soup Homogenous Pure Substance Element Heterogeneous Homogenous Mixture Solution Solvent + Solute Heterogeneous Mixture Element • Key Concept 12: Elements- composed of 1 type of atom A type of matter Examples: steel, air, water, vegetable soup Homogenous Pure Substance Element Compound Heterogeneous Homogenous Mixture Solution Solvent + Solute Heterogeneous Mixture Compound • Key Concept 13: Compound – is composed of two or more different elements chemically bonded together. Demo 3 A type of matter Examples: steel, air, water, vegetable soup Homogenous Pure Substance Element Compound Can be separated only by chemical means. Heterogeneous Homogenous Mixture Solution Solvent + Solute Heterogeneous Mixture Can be separated using physical means. Key Concept 14: Make a 4 column T chart Pure Substances Mixtures Element Compound Homo. Mixture Heter. Mixture Example for T chart • • • • • • • • • • Water Ethanol Water mixed with ethanol Sulfur Iron Iron Sulfide Sugar Sea Water Vegetable Soup Orange Juice BIG IDEA for Unit 4 • Key Concept 1: Everything has been a simple “pure” particle….. But now we need to illustrate matter as either a mixture (homo/hetero) or a pure substance (compound/element). Separating Techniques • The primary concept of chemistry is the classification of matter. • You have learned that matter can be a pure substance or a mixture that is homogenous or heterogeneous. A type of matter Examples: steel, air, water, vegetable soup Homogenous Pure Substance Element Compound Heterogeneous Homogenous Mixture Solution Solvent + Solute Heterogeneous Mixture Separating Techniques Key Concept 15: Why is this important to understand separation techniques? Why is are separation techniques important? • “For some 1.1 billion people, sufficient, safe, acceptable, accessible and affordable water for life is a hope for the future, not a reality for the present.” • 17 % OF HUMANITY WITHOUT ACCESS TO CLEAN WATER !! Why is this important Why is this important PBS News Hour: Haiti Why is this important Why is this important Why is this important Why is this important • 0.7% sodium hypochlorite liquid solution used to treat drinking water at "point of use“. Electrochlorination is the process of producing hypochlorite by running an electric current through salt water. NaCl + H2O + ENERGY → NaOCl + H2 Why is this important Why is this important NaCl + H2O + ENERGY → NaOCl + H2 Why is this important Separating Techniques • Settling – Used to separate substances with different weights • Sifting – Used to sort solids by size. Separating Techniques • Decanting: Used to separate an insoluble solid from a liquid by carefully pouring off the liquid. Based upon differences in density. Separating Techniques • Key Concept 16: Filtration – Used to separate a liquid and an insoluble solid. • Alum – Added to a liquid to promotes coagulation of suspended particles which is then filtered. Separation Techniques • Key Concept 17: Evaporation: Used to separation of a liquid and a soluble solid. Separation Techniques • Crystallization: Slow formation of a solid from a warm solution that is cooled. Separation Techniques • Key Concept 18: Distillation: Used to separation two miscible liquids, that have different boiling points. • If two liquids are miscible they form a homogeneous mixture when added together. Miscible = Mix M&M • It is made possible due to the fact that each liquid has its unique boiling point. Separation Techniques • Key Concept 19: Separating Funnel: used in separate the two immiscible liquids with different densities. "water is immiscible with suntan oil” “alcohol is miscible with water” Separation Techniques • Key Concept 20: Magnetism: used to separate out any substance based on its magnetic properties. Separation Techniques • Paper Chromatography: used to separate soluble substances from one another based upon differences in size as a solvent moves over paper. Defining a process with word you don’t know Miscible Immiscible Solute Soluble Insoluble Why is this important • How is your drinking water cleaned? End of Day Practice Problems 4ASpeed Dating Reading Atoms From Democritus to Dalton These Key Concepts will be summarized from the reading: • • • • • Key Concept 21: Empedocles Key Concept 22: Democritus Key Concept 23: Torricelli & Bernoulli Key Concept 24: Priestley Key Concept 25: Lavoisier Goal of this reading: Understand some key hypothesis that will allow us to get out of the particle model. Dalton • Key Concept 26: Dalton Dalton’s atomic theory • Key Concept 27: Dalton's atomic theory had four main concepts: – All matter is composed of indivisible particles called atoms. – All atoms of a given element are identical; atoms of different elements have different properties. – Chemical reactions involve the combination of atoms, not the destruction of atoms. – When elements react to form compounds, they react in defined, whole-number ratios. Dalton’s atomic theory vs. Atomic Theory Practice Problems B- # 1-3 End of Day Water? Question still to answer? • Density- Practice Problems Unit 1C Particle diagram illustrating density What substance has the greatest density and how do you know? Iron (Fe) Aluminum (Al) Is everything a simple particle? • One of the greatest challenges early chemists faced was trying to find a way to connect the mass of a substance to the number of particles in the sample. • If we knew how atoms combined together, we could deduce the mass of different types of atoms. Battle of understanding simple combinations Coming to Understand Simple Combinations • Read out loud as a group taking turns. • Go in a circle each person reading a paragraph. • Answer each key questions on the paper as you go. • Whiteboards/poster and markers are available at lab table 6. End of Day Guy-Lussac Experimental Evidence Guy-Lussac found that one volume of water vapor was not produced, but two equal volumes. Avogadro’s Hypothesis • Key Concepts 28: Avogadro assumed – Equal volumes of gases have equal numbers of molecules. – These particle can be split into half-particle during chemical reactions (particles of some gaseous elements must contain two atoms.) – That particle of elemental gases could contain more than a single atom. Avogadro’s Hypothesis • Two volumes of hydrogen react with one volume of oxygen to produce two volumes of water when hydrogen and oxygen can be split into half-molecules! Avogadro’s Hypothesis • If we accept Avogadro’s Hypothesis, we can compare the mass of various gases and deduce the relative mass of the molecules. • To do this, we pick a weighable amount of the lightest element (how about 1.0) then use mass ratios to assign atomic masses to the other elements. Molecular vs. Compound • Key Concept 30: A molecular is made of one or more elements (7 + 1). Dalton, Gay-Lussac, and Avogadro NOS? Homework- Due • Write a letter as if you were Avogadro to Dalton and Guy-Lussac. • You will need to explain how your hypothesis can be used to explain Dalton's density problem and excepts Guy-Lussac law of combining volumes. • Couple of paragraphs End of Day Is everything a simple particle? • One of the greatest challenges early chemists faced was trying to find a way to connect the mass of a substance to the number of particles in the sample. Avogadro’s Hypothesis • If we accept Avogadro’s Hypothesis, we can compare the mass of various gases and deduce the relative mass of the molecules. • To do this, we pick a weighable amount of the lightest element (how about 1.0) then use mass ratios to assign atomic masses to the other elements. • 36:30 to 37:50 • https://www.youtube.com/watch?v=ADYiwJ6 exf4 Relative Mass • To assign relative masses to elements it is necessary to know that the samples being compared have the same number of particles – If particles are all the same size, the same size sample would have the same number of particles – If particles are different sizes, the same size sample would have different numbers of particles Particle diagram illustrating density What substance has the greatest density and how do you know? Iron (Fe) Aluminum (Al) ANSWER • The best way is….. – If it is a gas (same number of particle per unit volume) – If it is a liquid or gas (different number of particle per unit volume due to how close the atoms are and the size of the atoms) PIQ- next class period Review Practice Problems A & B A type of matter Examples: steel, air, water, vegetable soup Homogenous Pure Substance Element Compound Heterogeneous Homogenous Mixture Solution Solvent + Solute Heterogeneous Mixture Out of the particle level Our model has to change……. Elements Compounds Mixtures Ionic Compounds vs. Molecular Compounds Ionic vs. Molecular Compound Demos Ionic vs. Molecular Properties Summary State (Room Temp.) Ionic Compounds Molecular Compounds Solubility in water Conductivity Boiling Point Melting Point Strength of Intermolecular Forces End of Day Understanding chemical bonding starts with a very important question? What type of compound is it? What type of compound is it? Ionic Compound vs. Molecular Compound What type of molecule is it? Ionic Compound • There is a transfer of electrons that forms an ionic bond. Molecular Compound • There is a sharing of electron through a covalent bond. Properties Review What is different about these two compounds: NaCl (table salt) vs. C6H12O6 (sugar) Get out Demo Sheet- Properties Review What if we just look at the compounds that conducted electricity Compound Conductivity Tap water (H2O and salts) Yes Sodium Chloride (NaCl) Yes Magnesium Sulfate (MgSO4) Yes Potassium Chloride (KCl) Yes What do these compounds have in common? What is an ionic compound? • How would you define a salt? – A salt is just an ionic compound • So what is an ionic compound? – Key Concept 31: Ionic Compound: consists of a metal and a non-metal bound together in a lattice structure by ionic bonds. Ionic Compounds • Ionic Compound = metal + nonmetal or cation + anion Ionic Compounds • Key Concept 32 – Cation – positively charged ion – Anion – negatively charged ion • Polyatomic Ions – – – – “Poly” = many “atomic” = atoms Ion = charged Polyatmoic ion = many atoms bonded together having an overall charge – See periodic table WE NEED A TOOL TO DETERMINE IF AN ELEMENT WILL BE A CATION OR ANION • This is a “tell”….. • We have a tool and it is called the periodic table. • Why this tool works won’t come until Unit 6 & 7 next semester. • Right now I just need you to correctly use the tool. Ionic Compounds • Ionic compounds consist of a cation (metal) bonded with an anion (non-metal). • Key Concept 33: Polyatomic ions themselves are not ionic compounds, but they form ionic bonds when paired with a metal. Properties of ionic compounds • When compounds conduct electricity they are also called electrolytes. • Where have you heard the term electrolyte before? Key Concept 34 : Properties of ionic compounds A. Conductivity – Ionic compounds conduct electricity because of the presence of ions. B. Solubility – Ionic compounds are soluble in water. Properties of ionic compounds (cont) C. Melting Point – Ionic compounds have a very high melting point because of the bond strength within the compound D. Intermolecular Forces – Ionic compounds have very strong intermolecular forces causing a very high bond strength – This causes all ionic compounds to be found in the solid state at room temperature Ionic Bonding • Key Concept 35: Ionic Bond– forms through a transfer of electrons that causes an attraction between 2 oppositely charged ions. • Review: What is an ion? – Different number of electrons from protons – Not a neutral atom – Contains a charge Ionic Bonding (cont) • Ionic bond is formed through electrostatic attraction between 2 oppositely charged ions • These ions are attracted to one another and form what is called a lattice or crystalline structure Why do these properties exist? • Key Concept 36: This lattice structure and strong interaction between ions is what causes the high bond strength and high melting point and solid state at room temperature • When ionic compounds interact with water, the ions are more attracted to the water molecules so the lattice dissociates • Key Concept 37: The dissociation of the ions is what causes ionic compounds to conduct electricity dissociation animation Key Concept 38: Properties of Molecular Compounds A. Conductivity – Molecular compounds do not conduct electricity B. Solubility – Molecular compounds are generally not soluble in water Properties of Molecular compounds (cont) C. Melting Point/Boiling Point – Molecular compounds have a very low melting point or boiling point because of the bond strength within the compound D. Intermolecular Forces – Molecular compounds have very weak intermolecular forces causing low bond strength – This causes most molecular compounds to be found in the liquid or gas state at room temperature Bonding in Molecular Compounds • Molecular compounds contain covalent bonds • Key Concept 39: Covalent bond– the sharing of electrons in an atom to form a bond. Bonding Chemistry is about stability • Some molecules are more stable when they are found as diatomic – two of the same element covalently bonded BrINClHOF B r o m i n e I o d i n e N i t r o g e n C h l o r i n e H y d r o g e n O x y g e n F l u o r i n e Bonding Time to process and organize Make some type of graphically organizer over the properties of ionic compounds vs. molecular compounds Get Creative End of Day Basic properties of ionic and molecular compounds • • • • • • Composition Conductivity Solubility Melting/Boiling Points Intermolecular Forces Types of Bonds Bonding – can be modeled with people! Ionic Bond vs. Covalent Bond What other information do we need to know? Ionic Compounds • How to name and write the formulas • Use common ions to predict the products of a chemical formulas Molecular Compounds • How to name and write formulas • Draw Lewis Structures (NOT UNTIL NEXT SEMESTER) 90% 10 % Why is naming important? • What does your name mean to you? • Where did your name come from? Would anyone like to share? • In other cultures, names can come from tradition and have different meanings. • We are going to look at a few different cultures and how they determine names Spain • Most people have one or two given names, followed by two surnames. • The first surname (considered the primary surname) is inherited from the father's paternal surname • The second is inherited from the mother's paternal surname. • Women usually keep their names when they marry. • Example - If José Lopez Garcia marries María Reyes Cruz, both will keep their surnames unchanged. If they have a child named Tomás, his full name will be Tomás Lopez Reyes. Africa • Traditional African given names often reflect the circumstances at the time of birth. – time or day when the child was born. – birth order of the newborn, – describe the parents' reaction to the birth – descriptive of the newborn or of desired characteristics • Example: Esi "Sunday“ Mosi "first born" Chinese • A modern Chinese name consists of a surname (xìng 姓) and a given name (míng 名 or míngzì 名字), usually presented in that order. • When transcribed into western writing, the characters of the given name are often written separately. • Sometimes the first character of the given name is shared by all members of a generation in a family Navajo • Navajo name is considered so precious it’s only used during ceremonies, meaning a day-to-day conversation in a Navajo family may go something like “Mother, go get Son.” • The Salish tribe follows a “naming trail” in which the name given to a baby by his parents at birth (usually a virtue or trait the parents hope for the baby) is eventually replaced at adolescence with another name that is given by the tribal leader at a ceremony called the Jump Dances. • This name usually represents a talent or strength for which the child is known. • Navajo naming is done through ceremony and names are symbolic of traits, tribes, animals, or virtues Chemistry • In chemistry, compounds and elements are named using the IUPAC system of naming – International union of pure and applied chemistry • This system ensures that everyone in every language will know what a compound is based on its name • There are a set of rules for naming different types of compounds Naming Rules – Ionic Compounds • There are 3 different “types” of naming rules for ionic compounds based on what metals and nonmetals are involved – Type A: metal (cation) + nonmetal (anion) • NaCl – Type B: metal (cation) + polyatomic ions (anion) • CaCO3 – Type C: transition metal (cation) + nonmetal/ or polyatomic (anion) • CuCl Pass out- Formula to Name Graphical Organizer Glue it on a new clean page Key Concept 40: Formula to Name– Ionic Compounds Type A Metal + Nonmetal 1. Name the metal 2. Name the nonmetal 3. Change the ending of the nonmetal to “ide” Example: NaCl – sodium chloride Naming Rules – Ionic Compounds Type B Metal + Polyatomic ion 1. Name the metal 2. Name the polyatomic ion, DO NOT change the ending Example: CaCO3 – calcium carbonate EXCEPTION ALERT!! • There is 1 polyatomic ion that is a cation, which means it is NOT a metal • NH4+ - ammonium • Example: NH4NO3 – ammonium nitrate Naming Rules – Ionic Compounds Type C Transition Metal + Nonmetal 1. Name the transition metal 2. Figure out the charge of the transition metal and place in Roman numerals in parenthesis 3. Name the nonmetal: • If it is a regular nonmetal – change the ending to “ide” • If it is a polyatomic ion – DO NOT change the ending Example: CuCl – copper (I) chloride Ionic Compounds- Formula to Name Practice • What naming type should I follow (A, B, or C) and then determine the correct name. • NaF • KSO4 • CaCl2 • NH4NO3 Pass out- Name to Formula Graphical Organizer Glue it on a new clean page Key Concept 41: Name to Formula – Ionic Compounds 1. Refer to the periodic table for the proper symbols and oxidation number. 2. Using the oxidation numbers determine what neutral compound will form (draw out if needed). 3. Use subscripts to indicate the number of each atom needed (if more than one polyatomic exist, put the polyatomic in parenthesis). Here is a tell…… how to determine oxidation numbers. Oxidation Numbers • We won’t get to why this trend exists on the periodic table until Unit 6 & 7. • Right now, use the periodic table as a tool and the understanding of WHY will come next semester. Ionic Bonding (cont) • Work with your shoulder partner to determine the most likely charge for the following: – Chlorine – Sulfur – Sodium – Nitrogen – Aluminum – Potassium Ionic Bonding (cont) Ionic Compounds- Name to Formula Practice • Lithium Chloride • Magnesium Sulfide • Calcium Nitride Ionic Compounds- Name to Formula Practice • Copper (II) sulfate • Copper (I) sulfate • Aluminum hydroxide Ionic Compounds- Ions to Names Bonding With A Classmate Go bond until the bell…. Watch the clockClosure is Be the Teacher Change name tags every third bond End of Day What other information do we need to know? Ionic Compounds • How to name them • Use common ions to predict the products of a chemical reaction Molecular Compounds • How to name them • Draw Lewis Structures (NEXT SEMESTER) 90% 10 % Key Concept 42: Formula to Name • The rules for molecular compounds are much easier than ionic (no exceptions) 1. Name First Element (Use prefix on first element if more than one) 2. Use prefix name second element 3. Change suffix to –ide. Example: N2O5 NO2 Naming Rules- Molecular Compounds • Greek Prefixes 1 = mono 2 = di 3 = tri 4 = tetra 5 = penta 6 = hexa 7 = hepta 8 = octa 9 = nona 10 = deca Key Concept 43: Name to Formula 1. Refer to the periodic table for the proper symbols 2. Use prefix in the name to determine subscripts needed. Example: triphosphorus hexafluoride carbon dioxide You have seen molecular represented like this Speed Dating Understanding chemical bonding starts with a very important question? What type of molecule is it? Tomorrow Combined Practice End of Day Properties of Water - demos • How many drops of water can a penny hold? • Will a needle float or sink in water? Properties of Water • Why can this bug “walk” on water? • Why does water form a meniscus with glass? Properties of Water • Why did the top of the penny hold so many drops of water? • Why can the bug walk on water? • Why did the needle float at first in the water? • Key Concept 44: Surface tension – an inward force that tends to minimize the surface area of a liquid; it causes the surface to behave as if it were a thin skin Properties of Water • Water has polar, covalent bonds and interacts with other water molecules by hydrogen bonding • Hydrogen bonding is an intermolecular force and is part of the reason for water having the properties we just saw • Key Concept 45: The intermolecular forces in water is called hydrogen bonding. These intermolecular forces are very strong for a liquid. Covalent bond Hydrogen bond Properties of Water • Why does water form a meniscus? • Key Concept 46: Capillary action – ability of a liquid to move up a surface against the forces of gravity. • With water, this is due to the water molecules hydrogen bonding with the glass molecules Properties of Water • Because of the surface tension and hydrogen bonding, water has a very high specific heat capacity – amount of heat energy required to raise the temperature of an object by a given amount. Properties of Water • These properties of water help answer many different questions about the “odd” behavior of water under different circumstances • Why are snowflakes shaped the way they are? • Why do oil and water not mix? • Why do ionic compounds dissolve in water and conduct electricity? • Why does solid water (ice) float in liquid water? (with other substances, the solid state is more dense than the liquid state). Crash Course • https://www.youtube.com/watch?v=HVT3Y3_ gHGg Four different fact from the video • • • • Key Concept 47: Key Concept 48: Key Concept 49: Key Concept 50: Understanding chemical bonding starts with a very important question? What type of molecule is it? Combined Practice: Rotation Station END OF UNIT 4