Chemical Equations and Chemical Reactions Writing A Chemical Equation The general format for chemical equations is: a+ b c +d What Does It All Mean? a+ b c +d The reactants go on the left side of the equation (a and b in this case). The + sign means “reacts with”. The means “produces or yields”. The products go on the right side of the equation (c and d in this case). Lets work with the statement: “Hydrogen gas reacts with oxygen gas to form liquid water” Word Equation hydrogen + oxygen water Skeleton Equation H2 + O2 H2O To balance equations numbers called coefficients are put before the formulas. This changes the number of molecules. You cannot add or change subscripts. You do not write coefficients of 1 (one). Balanced Equation ___H2 + ___O2 ___H2O 2H2 + O2 2H2O Why Must We Balance Equations? • Remember the Law of Conservation of Mass states that the total mass of reactants is always equal to the total mass of the products. • Dalton’s Atomic Theory states that atoms can not be created or destroyed. Compounds are formed when atoms of different elements combine in fixed proportions. Sometimes you need to know the state of the chemicals that are involved in a chemical reaction. State solid liquid gas aqueous solution Abbreviation State Abbreviation solid (s) liquid gas aqueous solution State Abbreviation solid (s) liquid (l) gas aqueous solution State Abbreviation solid (s) liquid (l) gas (g) aqueous solution State Abbreviation solid (s) liquid (l) gas (g) aqueous solution (aq) Final Balanced Chemical Equation 2H2(g) + O2(g) 2H2O(l) Step 1: • • Write in the symbols for all atoms and ions (skeleton equation) Balance each compound – – Remember diatomic ions: H2, N2, O2, F2, Cl2, Br2, I2 Remember to look for polyatomic ions on both sides of the equation iron + water hydrogen gas + iron (III) oxide Fe + H2O H2 + Fe2O3 Step 2: • Write in the abbreviations for the state of each compound if known or given Solid = (s) Liquid = (l) Gas = (g) Aqueous solution = (aq) ex. Fe (s) ex. H2O (l) ex. He (g) ex. NaCl (aq) • Fe (s) + H2O (l) H2 (g) + Fe2O3 (s) Step 3: Balance Equation • Balance the equation by adding coefficients – Pick single elements that appear on each side first to balance – Remember leave O then H until the end • Go back and re-check that all atoms are equal on both sides – If you have any fraction coefficients clear them by multiplying. – Also, make sure you have the smallest possible coefficients by reducing the ENTIRE EQUATION. 2Fe (s) + 3H2O (l) 3H2 (g) + Fe2O3 (s) Example 1: Word Equation sodium + water sodium hydroxide + hydrogen gas Skeletal Equation Na + H2O NaOH + H2 Balanced Equation ___Na + ___H2O ___NaOH +___H2 2Na + 2H2O 2NaOH + H2 Balanced Chemical Equation 2H2O__ 2Na__ + 2NaOH__ + H2___ 2Na(s) + 2H2O (l) 2NaOH(aq) + H2(g) Verification Reactants 2 Na atoms Products 2 Na atoms 4 H atoms 4 H atoms 2 O atoms 2 O atoms Example 2 Word Equation copper + silver nitrate copper(II) nitrate + silver Skeletal Equation ___ + ______ ______ + ___ Cu + AgNO3 Cu(NO3)2 + Ag Balanced Equation __Cu +__ AgNO3 __Cu(NO3)2 + __Ag Cu + 2AgNO3 Cu(NO3)2 + 2Ag Balanced Chemical Equation Cu__ + 2AgNO3__ Cu(NO3)2__ + 2Ag__ Cu(s) + 2AgNO3(aq) Cu(NO3)2(aq) + 2Ag(s) Cu(s) + 2AgNO3(aq) Cu(NO3)2(aq) + 2Ag(s) Verification Reactants Products Cu(s) + 2AgNO3(aq) Cu(NO3)2(aq) + 2Ag(s) Verification Reactants Products 1 Cu atom Cu(s) + 2AgNO3(aq) Cu(NO3)2(aq) + 2Ag(s) Verification Reactants Products 1 Cu atom 1 Cu atom Cu(s) + 2AgNO3(aq) Cu(NO3)2(aq) + 2Ag(s) Verification Reactants Products 1 Cu atom 1 Cu atom 2 Ag atoms Cu(s) + 2AgNO3(aq) Cu(NO3)2(aq) + 2Ag(s) Verification Reactants Products 1 Cu atom 1 Cu atom 2 Ag atoms 2 Ag atoms Cu(s) + 2AgNO3(aq) Cu(NO3)2(aq) + 2Ag(s) Verification Reactants Products 1 Cu atom 1 Cu atom 2 Ag atoms 2 Ag atoms 2 NO3- ions Cu(s) + 2AgNO3(aq) Cu(NO3)2(aq) + 2Ag(s) Verification Reactants Products 1 Cu atom 1 Cu atom 2 Ag atoms 2 Ag atoms 2 NO3- ions 2 NO3- ions Example 3 Word Equation calcium nitrate + sodium hydroxide calcium hydroxide + sodium nitrate Skeletal Equation Ca(NO3)2 + NaOH Ca(OH)2 + NaNO3 Balanced Equation __Ca(NO3)2 + __NaOH __Ca(OH)2 + __NaNO3 Ca(NO3)2 + 2NaOH Ca(OH)2 + 2NaNO3 Balanced Chemical Equation Ca(NO3)2__ + 2NaOH__ Ca(OH)2__ + 2NaNO3____ Ca(NO3)2(aq) + 2NaOH(aq) Ca(OH)2(s) + 2NaNO3(aq) Ca(NO3)2(aq) + 2NaOH(aq) Ca(OH)2(s) + 2NaNO3(aq) Reactants Products Ca(NO3)2(aq) + 2NaOH(aq) Ca(OH)2(s) + 2NaNO3(aq) Reacta Produc nts ts 1 Ca atom Ca(NO3)2(aq) + 2NaOH(aq) Ca(OH)2(s) + 2NaNO3(aq) Reactan Products ts 1 Ca 1 Ca atom atom Ca(NO3)2(aq) + 2NaOH(aq) Ca(OH)2(s) + 2NaNO3(aq) Reactants Products 1 Ca atom 1 Ca atom 2 NO3 ions Ca(NO3)2(aq) + 2NaOH(aq) Ca(OH)2(s) + 2NaNO3(aq) Reactants Products 1 Ca atom 1 Ca atom 2 NO3- ions 2 NO3- ions Ca(NO3)2(aq) + 2NaOH(aq) Ca(OH)2(s) + 2NaNO3(aq) Reactants Products 1 Ca atom 1 Ca atom 2 NO3 ions 2 NO3 ions 2 Na atoms Ca(NO3)2(aq) + 2NaOH(aq) Ca(OH)2(s) + 2NaNO3(aq) Reactants 1 Ca atom 2 NO3 ions 2 Na atoms Products 1 Ca atom 2 NO3 ions 2 Na atoms Ca(NO3)2(aq) + 2NaOH(aq) Ca(OH)2(s) + 2NaNO3(aq) Reactants Products 1 Ca atom 1 Ca atom 2 NO3- ions 2 NO3- ions 2 Na atoms 2 Na atoms 2 OH- ions Ca(NO3)2(aq) + 2NaOH(aq) Ca(OH)2(s) + 2NaNO3(aq) Reactants 1 Ca atom 2 NO3 ions 2 Na atoms 2 OH ions Products 1 Ca atom 2 NO3 ions 2 Na atoms 2 OH ions Homework: P. 174 # 1 to 4