December 16, 2013 (O) Dalton is important because… Lavoisier is important because… Proust is important because… Boyle is important because… Draw a model of Rutherford’s setup What is the mass in grams of 500. atoms of iron? 7. How many atoms in 0.200 grams of carbon? 8. Write electron configuration, draw orbital diagram, and underline valence electrons for cobalt. 1. 2. 3. 4. 5. 6. December 16, 2013 (O) 1. Review for final HOMEWORK: 1. Continue studying for final 2. Have a calculator for final 3. Periodic Table provided 2. Electron Configuration Hydrogen Comp Simulation 2. Electron Configuration Valence Electrons 2. Electron Configuration What are valence electrons? 2. Electron Configuration What are valence electrons? electrons in its outermost orbital are called the valence electrons 2. Electron Configuration How do we know which are the valence electrons? Has the highest n value, the principle quantum number 2. Electron Configuration Write FULL electron configuration for Silicon, Si 2. Electron Configuration Write FULL electron configuration for Silicon, Si Si = 1s22s22p63s23p2 2. Electron Configuration Write FULL electron configuration for Silicon, Si Si = 1s22s22p63s23p2 2. Electron Configuration Write FULL electron configuration for Germanium, Ge 2. Electron Configuration Write FULL electron configuration for Germanium, Ge Ge = 1s22s22p63s23p24s23d104p2 4 valence electrons 2. Electron Configuration 1. Write electron configurations for the following 2. Underline the valence electrons Barium Carbon Aluminum Tin Nitrogen Oxygen Phosphorus Tellurium Fluorine Neon Chlorine Krypton 2. Electron Configuration 1. Write electron configurations for the following 2. Underline the valence electrons Barium Carbon Nitrogen Oxygen Fluorine Neon [Xe]6s2 [He]2s22p2 [He]2s22p3 [He]2s22p4 [He]2s22p5 [He]2s22p6 Aluminum Tin Phosphorus Tellurium Chlorine Krypton 2. Electron Configuration How many valence electrons do you predict the last row will have? Barium Carbon Aluminum Tin Indium Silicon Nitrogen Oxygen Phosphorus Tellurium Arsenic Selenium Do you notice a pattern? Fluorine Neon Chlorine Krypton Bromine Argon 2. Electron Configuration How many valence electrons do you predict the last row will have? Barium Carbon Aluminum Tin Indium Silicon Nitrogen Oxygen Phosphorus Tellurium Arsenic Selenium Do you notice a pattern? Fluorine Neon Chlorine Krypton Bromine Argon 2. Electron Configuration EXAMPLE: Sodium 1s22s22p63s1 = [Ne]3s1 Lithium 1s22s1 = [He]2s1 This pattern is seen in columns 1-2 and 13-18 of the PT What other patterns might exist within the PT? Maybe there is a reason why the PT has that weird shape! 2. Electron Configuration How do you identify the valence electrons? 2. Electron Configuration Classwork: Thomson Name of Model Rutherford Bohr Nuclear Model Solar System Schrodinger Drawing Significance Electrons travel in quantized orbits Workbook page 18, # 1-12 Write the term Then the letter AND phrase in your answers. You may summarize by just writing keywords You DO NOT have to write the entire phrase 1. What can the Quantum Model of the atom show us? 2. What is an orbit and what is an orbital? 3. Complete Table 4. Textbook page 99, #3,4,5,6,7,9 5. Turn in Thomson Name of Model Rutherford Bohr Nuclear Model Solar System Drawing Significance Electrons travel in quantized orbits Schrodinger 3. Trendy Table The Periodic Table and its Trends OBJECTIVE: Understand how the Periodic Table is organized. 3. Trendy Table Periodic Table What is it? 3. Trendy Table Periodic Table What is it? • a tool • organizes information • NOT something to memorize • instead, learn how to use the organized information •See page or back of textbook 3. Trendy Table Main Question • How to best organize all the different elements? 3. Trendy Table 3. Trendy Table 3. Trendy Table 3. Trendy Table 3. Trendy Table Main Question • How to best organize all the different elements? • Handout 3. Trendy Table Main Question • How to best organize all the different elements? • So a quick history… 3. Trendy Table Brief History of the Table • Just like class activity, different versions • 1860 - John Newlands & Octaves 3. Trendy Table Brief History of the Table • Just like class activity, different versions • 1860 - John Newlands & Octaves 3. Trendy Table Brief History of the Table • Just like class activity, different versions • 1860 - John Newlands & Octaves • 1869 – Dimitri Mendeleev 3. Trendy Table • 1869 – Dimitri Mendeleev 3. Trendy Table • 1869 – Dimitri Mendeleev 3. Trendy Table • 1869 – Dimitri Mendeleev • • Arranged elements into rows by atomic mass. Arranged columns by chemical property • Ingenious design = left blanks, did not assume we discovered all elements. Able to ACCURATELY predict properties of undiscovered elements. 3. Trendy Table Brief History of the Table • • • • Just like class activity, different versions 1860 - John Newlands & Octaves 1869 – Dimitri Mendeleev 1913 – J. Moseley & Protons & Atomic # 3. Trendy Table • • • • Brief History of the Table Just like class activity, different versions 1860 - John Newlands & Octaves 1869 – Dimitri Mendeleev 1913 – J. Moseley & Protons & Atomic # Classwork: Textbook pg 122, #2,5,6,7,8 3. Trendy Table Brief History of the Table Classwork: Textbook pg 122, #2,5,6,7,8 Define the following 1. 2. 3. 4. 5. 6. 7. Period Group Periodic Law Atomic Radius Bond Radius Ionization Energy Electronegativity 3. Trendy Table Brief History of the Table Classwork: Textbook pg 122, #2,5,6,7,8 Define the following 1. Period 2. Group 3. Periodic Law 3. Trendy Table Barium Carbon Nitrogen Fluorine Neon Brief History ofOxygen the Table • Just like class activity, different versions • 1860 John Newlands & Octaves Aluminum Tin Phosphorus Tellurium Chlorine Krypton • 1869 – Dimitri Mendeleev • 1913 – J. Moseley & Protons & Atomic # Classwork: Textbook pg 122, #2,5,6,7,8 3. Trendy Table Barium Nitrogen Fluorine Neon Brief History ofOxygen the Table 2 2 22p3 22p4 22p5 [Xe]6s [He]2s [He]2s [He]2s [He]2s [He]2s22p6 • Just like22p class activity, different versions • 1860 - John Newlands & Octaves Aluminum Phosphorus Tellurium Chlorine Krypton • 1869 –TinDimitri Mendeleev • 1913 – J. Moseley & Protons & Atomic # Indium Carbon Silicon Arsenic Selenium Bromine Argon Classwork: Textbook pg 122, #2,5,6,7,8 3. Trendy Table Barium Carbon Nitrogen Fluorine Neon Brief History ofOxygen the Table 2 2 22p3 22p4 22p5 [Xe]6s [He]2s [He]2s [He]2s [He]2s [He]2s22p6 • Just like22p class activity, different versions • 1860 - John Newlands & Octaves Aluminum Phosphorus Tellurium Chlorine Krypton • 1869 –TinDimitri Mendeleev • 1913 – J. Moseley & Protons & Atomic # Classwork: Textbook pg 122, #2,5,6,7,8 3. Trendy Table 1. 2. 3. 4. 5. 6. 7. Brief History of the Table Workbook pg 23, #2-5 Answer in complete sentences. Define the following Period Group Periodic Law Atomic Radius Bond Radius Ionization Energy Electronegativity 3. Trendy Table Thomson Rutherford Bohr Brief History of the Table Name of Model Nuclear Model Schrodinger Solar System • Just like class activity, different versions Drawing • 1860 - John Newlands & Octaves • Significance 1869 – Dimitri Mendeleev Electrons move in quantized • 1913 – J. Moseley & Protons & Atomic # orbits Classwork: Workbook pg 23, #2-5 Answer in complete sentences. 3. Trendy Table Periodic Trends How would you define “pattern”? How would you define “trend”? 3. Trendy Table Periodic Trends Objective: To recognize patterns in the PT 3. Trendy Table Periodic Trends Objective: To recognize patterns in the PT 3 Patterns 1. Atomic Radius 2. Ionization Energy 3. Electronegativity 3. Trendy Table Periodic Trends First, some important terms 1. Period: 2. Group: 3. Periodic Law: 3. Trendy Table Periodic Trends First, some important terms 1. Period: 2. Group: 3. Periodic Law: 3. Trendy Table Periodic Trends First, some important terms 1. Period: Horizontal row of elements 3. Trendy Table Periodic Trends First, some important terms 1. Period: elements in a period occupy SAME ENERGY LEVEL 3. Trendy Table Periodic Trends First, some important terms Group: vertical column of elements 3. Trendy Table Periodic Trends First, some important terms Periodic Law: predictable patterns when elements arranged by atomic number 3. Trendy Table Periodic Trends First, some important terms Periodic Law: predictable patterns reoccur when elements arranged by atomic number Patterns of what? 3. Trendy Table Periodic Trends Objective: To recognize patterns in the PT 3 Patterns 1. Atomic Radius 2. Ionization Energy 3. Electronegativity 3. Trendy Table Periodic Trends 3 Patterns 1. Atomic Radius 2. Ionization Energy 3. Electronegativity Atomic Radius Ionization Energy Electronegativity Period INCREASES INCREASES INCREASES Row INCREASES INCREASES INCREASES 3. Trendy Table Periodic Trends 1st Pattern or Trend Atomic Radii – Size of Atom 3. Trendy Table 1st Pattern or Trend Atomic Radii – Size of Atom 3. Trendy Table Periodic Trends 1st Pattern or Trend Atomic Radii – Size of Atom As you go down a group, the number of electrons _______ As you go across a period, from left to right, the number of electrons ______ 3. Trendy Table Periodic Trends Atomic Radii – Size of Atom 1. Period: Horizontal row of elements 3. Trendy Table Periodic Trends Atomic Radii – Size of Atom So, as you go down a period, atomic radii ______. As you go across a period…wait WHY? 3. Trendy Table Periodic Trends Atomic Radii – Size of Atom WHY? Because of Electron Shielding and Nuclear Charge 3. Trendy Table Periodic Trends Atomic Radii – Size of Atom WHY? Because of Electron Shielding is when… Valence electrons are shielded by the core electrons 3. Trendy Table Periodic Trends Atomic Radii – Size of Atom 3. Trendy Table Periodic Trends Atomic Radii – Size of Atom 1. Period: Horizontal row of elements 3. Trendy Table Periodic Trends Atomic Radii – Size of Atom 3. Trendy Table Periodic Trends Atomic Radii – Size of Atom WHY? Because of Electron Shielding is when… Valence electrons are shielded by the core electrons 3. Trendy Table Periodic Trends Atomic Radii – Size of Atom WHY? Because of Electron Shielding is when… Valence electrons are shielded by the core electrons FILLED inner orbitals shield electrons in the outer orbitals 3. Trendy Table Periodic Trends Atomic Radii – Size of Atom WHY? Because of Valence Electrons and filled Valence Orbitals Atomic radius determined by valence electrons 3. Trendy Table Periodic Trends Atomic Radii – Size of Atom Electron Shielding 3. Trendy Table Periodic Trends 3 Patterns 1. Atomic Radius 2. Ionization Energy 3. Electronegativity Atomic Radius Ionization Energy Electronegativity Period INCREASES INCREASES INCREASES Row INCREASES INCREASES INCREASES 3. Trendy Table Periodic Trends 3 Patterns 1. Atomic Radius 2. Ionization Energy 3. Electronegativity Atomic Radius Ionization Energy Electronegativity Period INCREASES INCREASES INCREASES Row INCREASES INCREASES INCREASES 3. Trendy Table Periodic Trends 3 Patterns 1. Atomic Radius 2. Ionization Energy 3. Electronegativity Atomic Radius Ionization Energy Electronegativity Period INCREASES INCREASES INCREASES Row INCREASES INCREASES INCREASES 3. Trendy Table Periodic Trends Atomic Radii – Size of Atom 3. Trendy Table Arrange by radius from smallest to largest 1. Calcium, Magnesium, Hydrogen 2. Gold, Arsenic Radon 3. Carbon, Cesium, Copper, Helium, Iron, Potassium 3. Trendy Table Periodic Trends 3 Patterns 1. Atomic Radius 2. Ionization Energy 3. Electronegativity Atomic Radius Ionization Energy Electronegativity Period INCREASES INCREASES INCREASES Row INCREASES INCREASES INCREASES 3. Trendy Table Periodic Trends 2nd Trend: First Ionization Energy 3. Trendy Table Periodic Trends 2nd Trend: First Ionization Energy What is this? 3. Trendy Table Periodic Trends 2nd Trend: First Ionization Energy What is this? Energy needed to remove an electron from an atom 3. Trendy Table Periodic Trends 2nd Trend: First Ionization Energy What is this? Energy needed to remove an electron from an atom A FILLED orbital is a happy and stable orbital 3. Trendy Table Periodic Trends 2nd Trend: First Ionization Energy What is this? Energy needed to remove an electron from an atom A filled orbital is a happy and stable orbital All elements want to be NOBLE 3. Trendy Table 2nd Trend: First Ionization Energy 3. Trendy Table 2nd Trend: First Ionization Energy 3. Trendy Table 2nd Trend: First Ionization Energy 3. Trendy Table Periodic Trends 3 Patterns 1. Atomic Radius 2. Ionization Energy 3. Electronegativity Atomic Radius Ionization Energy Electronegativity Period INCREASES INCREASES INCREASES Row INCREASES INCREASES INCREASES 3. Trendy Table 2nd Trend: First Ionization Energy Arrange from lowest to greatest 1. Cesium, Helium, Gold 2. Calcium, Copper, Potassium 3. Arsenic, Carbon, Cesium, Iron, Magnesium 3. Trendy Table Periodic Trends 3rd Trend: Electronegativity What is this? 3. Trendy Table Periodic Trends 3rd Trend: Electronegativity What is this? Electronegativity is the ability to attract electrons when making compounds 3. Trendy Table 3rd Trend: Electronegativity 3. Trendy Table 3rd Trend: Electronegativity 3. Trendy Table 3rd Trend: Electronegativity 3. Trendy Table Periodic Trends 3 Patterns 1. Atomic Radius 2. Ionization Energy 3. Electronegativity Atomic Radius Ionization Energy Electronegativity Period INCREASES INCREASES INCREASES Row INCREASES INCREASES INCREASES 3. Trendy Table 3rd Trend: Electronegativity Arr Arrange from lowest to greatest electronegativity 1. Cesium, Helium, Radon 2. Arsenic, Copper, Gold 3. Calcium, Carbon, Iron, Magnesium, Potassium 3. Trendy Table All 3 Trends 3. Trendy Table All 3 Trends 3. Trendy Table All 3 Trends Review for Final From latest section Know: Bohr Groups Period Periodic Law Valence electrons Orbital diagrams Types of orbitals, and how many e in each? Electron configurations Patterns for 3 trends Hund, Aufbau, Pauli Review for Final Green Workbook Chapter 4, page 21 #2, 3, 6-7, 12, 13 Chapter 3, page 16 #1-8, 10-11, 14, 16-20 Chapter 2, page 11 # 6-8 Chapter 1, page 6 #1, 3-5, 8, 10-12, 16, 19-20 2. Electron Configuration Because of electron shielding, electrons in the inner orbitals are closer to the nucleus and more tightly bound to it. So they are rarely involved in chemical reactions. This means that the chemistry of an atom depends mostly on the electrons in its outermost orbital,