2.1 Properties of Matter • Define and prove the Law of Conservation of Matter • Describe a substance according to its physical and chemical properties. • Distinguish between extensive and intensive properties. • Describe the six states of matter. • Identify physical changes to matter. • Identify the chemical properties of a substance. • Describe chemical changes and differentiate them from physical changes. • Use various visual clues to identify whether a chemical reaction is taking place. 2.2 Classification of Matter • Define a mixture and understand why mixtures are different than pure substances. • Classify mixtures as homogeneous or heterogeneous • Classify liquids as a solution, suspension, colloid, or alloy • Describe several ways to separate mixtures. • Distinguish between elements and compounds. Classifying Matter • Scientists classify matter according to make-up. Matter Elements Compounds Mixtures Elements and Compounds An element is the simplest form of matter and has a unique set of properties. A compound contains two or more elements chemically combined in fixed proportions. Compounds can be broken down, elements cannot. Elements • Simplest pure substance – fixed composition. • Pure substance is made of only one material. Same throughout. Referred to as homogeneous matter. • Are made of alike atoms, which are the basic building blocks of matter. • Represented by chemical symbols - H, O, Al, Cu, Au. • 118 elements organized in the periodic table in squares called an element key. Compounds • Two or more elements chemically combined. • Represented by chemical formulas. • Examples: H2O, CO2, NaCl, C12H22O11 • Molecules are the smallest natural unit of a compound or diatomic element. A molecule is made up of two or more atoms chemically combined. Pure Substances: Elements are Composed of identical atoms Chlorine gas Sodium metal 2 or More Elements Combine to Produce a Compound Chlorine gas + = Sodium metal + Sodium Chloride = Mixtures • Two or more substances mixed together but not chemically combined. • Has unlike parts and a composition that varies from sample to sample. • Properties: – Sub. in a mixture keep their separate identities. – Sub. can be present in any amount. – Sub. can be separated out by physical means. Mixtures Mixtures Homogeneous Heterogeneous Mixtures: Variable combination of two or more substances: Homogeneous uniform throughout Heterogeneous not uniform throughout Phase Used to describe any part of a sample with uniform composition and properties Heterogeneous: 2 or more phases Homogeneous: 1 phase Solutions • A homogeneous mixture. • One substance dissolves in another. Solutions remain constantly & uniformly mixed. •Solute and Solvent •Particles are smaller than 1 nm in size •Particles do not settle •Particles pass through filter paper Examples: lemonade, soda, ocean water, antifreeze, metal alloys Alloy A homogeneous mixture combining two or more metals to maximize the benefits of each. Ex. Gold Jewelry: 14 kt Gold (Gold for shine, Silver for strength) Colloids • A homogeneous mixture. • Mixed together but not dissolved. • Appears cloudy. Scatters light. •Particles are 2 – 100 nm in size •Particles do not settle •Particles pass through filter paper •Usually not transparent (cloudy) • Examples: milk, cool whip, toothpaste, lotions, fog, smoke, Jello. Suspension Heterogeneous Mixture Particles settle to the bottom unless constantly stirred Particles are greater than 100 nm Not transparent, must be mixed Ex: Paint, Chocolate Milk, Composition of Matter Matter Pure Substance Element Compound Mixture Homogeneous Solution Colliod Heterogeneous Suspension 2.3 Changing Matter • Describe how chemical potential energy relates to heat and work. • Describe the law of conservation of energy and how heat flows between system and surroundings during both endothermic and exothermic processes. • Use the specific heat equation to perform calculations that relate mass, specific heat, change in temperature, and the amount of heat absorbed or released. Thermochemistry Chemical Potential Energy • the energy stored in the chemical bonds of a substance • the kinds of atoms and their arrangement in the substance determine the amount of energy stored in the substance. If 2 objects remain in contact, heat will flow from a warmer object to the cooler object until the temperatures are equal. AKA: HEAT (A) Object A starts with a higher temperature than object B. No heat flows when the objects are isolated from each other. (B) When brought into contact, heat flows from A to B until the temperatures of the two objects are the same. Heat • Symbol = q • energy that transfers from one object to another because of temperature difference • Heat always flows from a warmer object to a cooler object. An Ice Cold Spoon energy transfer A Hot Spoon Thermochemistry • The study of energy changes that occur during chemical reactions and changes of state. Law of Conservation of Energy • In any chemical or physical process, energy is neither created or destroyed • If energy of the system decreases the energy of the surroundings must increase by the same amount so that the total energy of the universe remains unchanged. The Universe • • • • Can be divided into 2 “parts” System- the part you are investigating Surroundings- the rest of the universe In a thermo-chemical experiments the region in immediate vicinity of the system are the surroundings. Units of Heat calorie joule • the amount of energy contained within food • SI Unit of energy • Quantity of heat required to to raise the temp of 1g of water 1° C • Heat changes in chemical reactions are typically measured in joules. Calorie=Kilocalorie=1000calories Joule and calorie Conversion Factors • 1J = 0.2390cal • 1 cal = 4.184 J HEAT HEAT HEAT HEAT Different type of materials may have the same temp, same mass, but different conductivity. •They are affected by the potential energy stored in chemical bonds or the IMFs holding molecules together •It is possible to be at same temp (same KE) but have very different thermal energies. •The different abilities to hold onto or release energy is referred to as the substance’s heat capacity Heat Capacity The measure of how well a material absorbs or releases heat energy •Physical property unique to a particular material •The heat capacity depends on both its mass and its chemical composition. •The greater the mass; the greater the heat capacity. •It can be thought of as a reservoir to hold heat, how much it holds before it overflows is its capacity •Water takes 1 calorie of energy to raise temp 1 °C •Steel takes only 0.1 calorie of energy to raise temp 1 °C Specific Heat The amount of heat required to raise the temperature of one gram of substance by one degree Celsius. q = mCT Calculations Involving Specific Heat q c m T p c = Specific Heat q = Heat lost or gained T = Temperature change m = Mass Table of Specific Heats Calorimetry • The precise measurement of heat flow into or out of a system for chemical and physical purposes • The heat released by the system is equal to the heat absorbed by its surroundings. • Conversely, the heat absorbed by a system is equal to the heat released by it’s surroundings. Calorimeter There are three methods used to transfer heat energy. • • • Conduction – transfer of heat through direct contact Convection – transfer of heat through a medium like air or water Radiant – transfer of heat by electromagnetic radiation