Cycling of Matter in Ecosystems aka – Nutrient Cycles How are energy flow and cycling of matter different? • Energy flows in one direction through an ecosystem. Sun Producers Consumers • Energy doesn’t return to sun, it’s “lost” (unuseable) • Law of Conservation of Matter: Matter cannot be created or destroyed, only re-arranged. • This is why ecosystems must recycle matter • Nature does this well through nutrient cycles. The Essential Elements • Nature tends to use the following raw materials in great quantity: • Nitrogen, Carbon, Hydrogen, Oxygen, Phosphorus and Sulfur • Using their chemical symbols we get the acronym N-CHOPS • Since natural systems use these so much and dispose of them so often, they are cycled quite efficiently • The only way matter can be cycled out of food webs is to involve detritus feeders and decomposers Decomposers at work decomposing rabbit ants and gecko Basic Cycle Overview • Cycles are basically a series of Reservoirs or Sinks connected by pathways or fluxes. • We will trace each nutrient cycle through 5 key points: 1) Identify all Reservoirs, including main res. 2) Identify “pathways” or fluxes between reservoirs 3) Describe interactions with biotic community 4) Understand key terms that apply to each cycle 5) Human impact along the way Use your “Key Points” Sheet Use diagrams – as many as possible Start with one we all know…H2O 1) Make a group of 4 2) Define key terms 3) Create a diagram of the water cycle that shows all 5 key points 4) Use “Key Points” worksheet as a reference 5) Do you remember the Water Cycle Song? Water Cycle = Hydrologic Cycle • Reservoirs: ocean, atmosphere, surface water, groundwater, glaciers, biomass • Evaporation = (liquid to gas) ocean and surface water to atmosphere • Water vapor cools and condenses into liquid (clouds) in atmosphere (another reservoir) • Water falls back to surface by precipitation • Run-off = flow across surface through streams, rivers, lakes back to ocean (check diagram) • Infiltration = precipitated water at surface filters into soil and rocks • Plants can absorb it from soil through roots after infiltration • Water evaporates from plants by transpiration Water (Hydrologic) Cycle Most Consumers get water from run-off locations, not through the food web Water that infiltrates and does not get used by plants will percolate through soil and flow underground eventually back to run-off or ocean (aquifer) Natural purification steps: 1) Evaporation = only pure H2O is moving on 2) Percolation = soil, sand and rock act as a filter for groundwater 3) Run-off (ation) = pollutants settle out on lakes and wetlands Human Interactions • Over-withdrawal = depletion of fresh water supply (problem in western US) • Creating an imbalance between run-off and infiltration – increased run-off, flooding and erosion 1) clearing vegetation 2) creating impervious surfaces • Modifying = draining wetlands, modifying riparian zones (river banks) • Modifications short circuit the natural purification of run-off • Pollution of air, groundwater, surface water, soils And now a little game…. 1) On your own… 2) Take a total of 16 trips 3) Use sheets to keep track of where you go and how 4) Answer questions on separate sheet of paper when finished – staple all papers together 5) Report out findings Nitrogen Game Analysis Answer the following questions quietly on your own… 1) Which station did you visit most often? 2) What station was visited the most by the entire class? How does this compare with your answer to #1 3) What does this tell you about nitrogen in nature and how it moves? 4) What kinds of human impacts were you involved in? 5) Explain the difference between how plants and animals obtain their nitrogen requirements. 6) Identify two ways atmospheric nitrogen is made “biologically useable” Nitrogen • Main reservoir is atmospheric N2 = useless gas • Gets to producers by being fixed into useable forms of nitrogen = Ammonia (NH3), Nitrate (NO3) • Nitrogen Fixation is done by bacteria and lightning NH3 • Legume family of plants have root nodules that house these beneficial bacteria (beans, alfalfa, peas, etc…) • Nitrification = soil bacteria converts ammonia to nitrate (NO3-) • Uptake of NH3 or NO3 by autotrophs = assimilation • Travels through food chain • Released to soil again through plant & animal waste and decay • Animal wastes, dead plants, etc.. Broken down by decomposers and returned to atmos as N2 (unusable) = denitrification Human Impact on Nitrogen Cycle • Humans interfere by burning certain fossil fuels that release nitrogen compounds to form acid rain • Also, over-fertilization pollutes waterways – remember the nutrient pollution lab • Over-farming removes nitrogen from soil as crops are removed • Use crop rotation to reduce nitrogen loss • Make sure your diagram is accurate and complete for this cycle Carbon Cycle • Main reservoir is CO2 in atmosphere and dissolved in oceans • Other reservoirs: Ocean sediments, biomass, fossil fuels such as coal, petroleum, natural gas (methane) • In the atmos. CO2 acts as nature’s thermostat (greenhouse effect) • Basic 3 step Cycle: 1) Taken in by plant leaves to do photosynthesis 2) Travels through consumers/food chain 3) Released back into atmos. as CO2 by animal respiration, decay processes or burning vegetation Ocean part of cycle is very similar except some CO2 is incorporated into coral and shells of clams, oysters, etc… Human Impact • Clearing vegetation (Deforestation) increases levels of CO2 in the atmosphere • Combustion (burning) of fossil fuels increases levels of CO2 in the atmosphere (fuel + O2 CO2 + H20 + Energy) • Fossil Fuels = organic compounds made by the decay of organisms deep underground in the presence of high heat or pressure (coal, petroleum, natural gas, etc…) • This could increase Greenhouse Effect Global Climate Change • Push for alternative energy to avoid climate change or to lessen our dependence on resources that are non-renewable or difficult to obtain • What alternatives are good? Not so good? Traditional Fossil Fuel Usage Traditional Fossil Fuel Usage: Petroleum = gasoline, diesel, propane, other fuels Coal = burned to generate electricity Natural Gas = heat homes, water tanks, appliances Alternatives: Crop Ethanol, Landfill Gas, Biodiesel still emit CO2 Wind Power, Nuclear, Geothermal, Hydrogen Fuel cells, Solar do not emit CO2 Alternative energy sources replace traditional fossil fuels Use more Methane / Natural Gas – makes sense • Methane produces less CO2 and is easier to obtain than petroleum • Methane (CH4) is a much stronger greenhouse gas than CO2 • Hydro-fracking for methane…safety? • Use landfill gas as alternate energy source? Hydro-fracking to release CH4 Phosphorus • • • • • • • • • P circulates through earth’s crust, organisms and water Not in atmos, no gas phase Very slow Typically found as phosphate (PO4) in terrestrial rock and ocean floor sediments = Main Res. Enters biotic through uptake by producers’ roots Often a limiting factor for plant growth unless added in fertilizers Passed on through food chains Returns to soil through decomposition, poop and pee (guano – seabird poop deposits) Can move slowly from ocean to land through uplifting of rock Phosphorus • Human activities: mined for fertilizers and detergents • Removed by deforestation • Added by run-off of animal waste, fertilizers and sewage discharge • When too much phosphate finds its way into runoff, it causes eutrophication in waterways • Eutrophication = excess phosphate causing algae to grow out of control, reducing available oxygen to other aquatic organisms Sulfur • Similar to P, main reservoir = rocks and minerals in soil • Producers obtain it through roots and pass it on to the rest of the food web • Decomposers return it to soil from waste and detritus • Bacteria also return sulfur the atmosphere as… H2S (hydrogen sulfide) gas from wetlands DMS (Dimethyl Sulfide) from oceans • Or SO2 (sulfur dioxide) gas from volcanoes • SO2 reacts with O2 and H2O in clouds form sulfuric acid = acid rain • Acid rain returns sulfur to soil and rock reservoir Sulfur • • • • Human Impact involves burning soft coal and oil Refining petroleum Using smelting for copper lead and zinc refining These 3 activities increase sulfur dioxide (SO2) and sulfur trioxide (S03) levels in the atmosphere which decreases acid rain pH Acid Rain Effects on Trees Acid Rain Effects on Trees Acid Rain Effects on Buildings Acid Rain! – the band If you missed class time on this… 1) Make sure your notes are complete (Nutrient Cycles at a Glance sheet) 2) Read chapter 3 section 5 (pp.65-72), pay special attention to diagrams 3) Ask Mr. Kearns for help on what you do not understand Freak Point Opportunity (up to 6 Freaks) Make up a song! - to the tune of a holiday song - must incorporate key vocab and the general story behind one of the cycles (not water) - must be sung in front of the class - must be accurate - due by Tuesday (11/8) - # of freak points earned is determined by the teacher