Atoms & Chemical Bonding Created in 2008 by Tim F. Rowbotham, Modified in 2011 Element Cards • Follow the directions in the following slides to complete this journal Atoms & Chemical Bonding Created in 2008 by Tim F. Rowbotham, Modified in 2011 NOTES Valence Electrons • Electrons in the outermost energy level are known as valence electrons. • Valence electrons are important because they are the only ones involved in chemical bonding. Valence Electrons • Valence electrons can be gained, lost, or shared by atoms during chemical bonding. • This desire for a certain amount of valence electrons is what causes chemical reactions. Valence Electrons • How many valence electrons in this atom? • REMEMBER VALENCE ELECTRONS ARE ONLY THOSE IN THE OUTER ENERGY LEVEL How many valence electrons in this atom? 0% 0% 0% 0% 1. 2. 3. 4. 1 2 4 6 How many valence electrons in this atom? 0% 0% 0% 0% 1. 2. 3. 4. 9 7 3 2 How many valence electrons in this atom? 0% 0% 0% 0% 1. 2. 3. 4. 1 2 4 88 How many valence electrons in this atom? 0% 0% 0% 0% 1. 2. 3. 4. 1 2 4 88 Return your remote Complete p. 6-7 of your packet Created in 2008 by Tim F. Rowbotham, Modified in 2011 Entrance Questions Ready your remote Created in 2008 by Tim F. Rowbotham, Modified in 2011 How many valence electrons in this atom? 0% 0% 0% 0% 1. 2. 3. 4. 1 2 4 6 How many valence electrons in this atom? 0% 0% 0% 0% 1. 2. 3. 4. 1 2 4 12 How many valence electrons in this atom? 0% 0% 0% 0% 1. 2. 3. 4. 1 2 4 20 How many valence electrons in this atom? 0% 0% 0% 0% 1. 2. 3. 4. 1 2 4 38 CHEMICAL BONDING NOTES Turn to page 1 of your CHEMICAL BONDING PACKET Rows on the Periodic Table • Rows across the periodic table are known as periods. • Elements in the same row have the same number of energy levels. • This outer energy level is often referred to as the valence energy level or the valence shell. Families on the Periodic Table • Elements in the same column of the periodic table are known as groups or families. • Elements in the same family have the same number of valence electrons. Families & Properties • Since elements in the same family have the same number of valence electrons, they behave very similarly in a chemical reaction. • Therefore, atoms in the same family have very similar properties!!! Using the Periodic Table • How to Determine the Number of Valence Electrons Learning Checks • Ready your Remotes Columns on the periodic table are called 0% 0% 0% 0% 1. 2. 3. 4. Periods Groups Compounds Bonding Reagents What is true of elements in the same column of the periodic table? 0% 0% 0% 0% 1. 2. 3. 4. Same first letter Similar properties Same number of protons as neutrons Discovered in the same year Rows on the periodic table are called 0% 0% 0% 0% 1. 2. 3. 4. Groups Compounds Periods Bonding reagents What is the valence energy level of strontium (A# = 38) ? 0% 0% 0% 0% 1. 2. 3. 4. 2nd 3rd 4th 5th What is the valence energy level of Mercury (A# = 80) ? 0% 0% 0% 0% 1. 2. 3. 4. 3rd 4th 5th 6th How many valence electrons does bromine have(A# = 35) ? 0% 0% 0% 0% 1. 2. 3. 4. 8 7 6 4 How many valence electrons does phosphorus have(A# = 15) ? 0% 0% 0% 0% 1. 2. 3. 4. 8 7 6 5 What is the valence energy level of calcium (A# = 20) ? 0% 0% 0% 0% 1. 2. 3. 4. 1st 2nd 3rd 4th How many valence electrons does calcium have(A# = 20) ? 0% 0% 0% 0% 1. 2. 3. 4. 1 2 3 4 Electron Dot Diagrams • Since only the valence electrons are involved in chemical bonding, chemists have a quicker, easier way to represent atoms when showing bonding called an electron dot diagram. Electron Dot Diagrams • An electron dot diagram is simply the chemical symbol of an element with 1 dot for every valence electron it has. • This is also referred to as a Lewis dot structure. Sample Dot Diagrams Learning Checks • Ready your Remotes Rows on the periodic table are called 0% 0% 0% 0% 1. 2. 3. 4. Groups Compounds Periods Bonding reagents What is true of elements in the same column of the periodic table? 0% 0% 0% 0% 1. 2. 3. 4. Same first letter Similar properties Same number of protons as neutrons Discovered in the same year Using the Periodic Table • Return Your Remote • Pick up & Complete Electron Dot diagrams WS • Complete PACKET p.8 “Properties of a Missing Element” Using the Periodic Table • Valence Electrons, Lewis Dot Diagrams & Bohr Models Entrance Questions • Ready your Remotes • Get out a periodic table Columns on the periodic table are called 4% 96% 0% 0% 1. 2. 3. 4. Periods Groups Compounds Bonding Reagents How many valence electrons does aluminum have(A# = 13) ? 3% 90% 7% 0% 1. 2. 3. 4. 2 3 4 5 What is the valence shell of aluminum (A# = 13) ? 0% 0% 0% 0% 1. 2. 3. 4. 1st 2nd 3rd 4th How many valence electrons does phosphorus have(A# = 15) ? 3% 3% 93% 0% 1. 2. 3. 4. 1 3 5 7 Columns on the periodic table are called 3% 90% 7% 0% 1. 2. 3. 4. Periods Families Compounds Bonding Reagents What is true of elements in the same column of the periodic table? 0% 97% 3% 0% 1. 2. 3. 4. Same first letter Similar properties Same number of protons as neutrons Discovered in the same year How many valence electrons does chlorine have(A# = 17) ? 0% 100% 0% 0% 1. 2. 3. 4. 8 7 6 17 Chlorine-37 would have how many neutrons? (A#17) 7% 17% 76% 0% 1. 2. 3. 4. 7 17 20 37 How many valence electrons does phosphorus have (A# = 15) ? 0% 0% 0% 0% 1. 2. 3. 4. 1 3 5 7 Exit Questions • • • • Return your Remotes Read Text pages 130-138 (Chapter 5.2) Complete Periodic Table Brochure Complete pages 8–10 of Chem Bonding Pack Entrance Questions • Ready your Remotes • Get out a periodic table Oxygen-17 would have how many neutrons? (A#8) 0% 0% 0% 0% 1. 2. 3. 4. 7 17 9 8 What is true of elements in the same column of the periodic table? 0% 0% 0% 0% 1. 2. 3. 4. Same first letter Similar properties Same number of protons as neutrons Discovered in the same year How many valence electrons does magnesium have (A# = 12) ? 0% 0% 0% 0% 1. 2. 3. 4. 1 2 5 12 How many energy levels does magnesium have (A# = 12) ? 0% 0% 0% 0% 1. 2. 3. 4. 1 2 3 12 Entrance Questions • • • • • Return your Remotes Turn in Periodic Table Brochure Read Text pages 139-145 (Chapter 5.3) 5.3 Representative Groups Reading Organizer Answer Assessment Questions 1-11 • Complete pages 9–16 of Chem Bonding Pack • ADD- Valence Electrons, Valence Shells, and Electron Dot Diagrams to the flip chart. Entrance Questions • Ready your Remotes Which of the following elements has 6 valence electrons? 0% 0% 0% 0% 1. 2. 3. 4. Oxygen (A# 8) Neon (A# 10) Lithium (A# 3) Carbon (A# 6) CHEMICAL BONDING NOTES Turn to page 2 of your CHEMICAL BONDING PACKET Stable Atoms • Chemically stable atoms have 8 valence electrons (Octet Rule) • (Atoms with only 1 energy level can be stable with only 2 valence electrons) Which of the following elements is naturally chemically stable? 0% 0% 0% 0% 1. 2. 3. 4. Oxygen Neon Lithium Carbon Which of the following families have elements that are chemically stable? 0% 0% 0% 0% 1. 2. 3. 4. Alkali metals Alkaline earth metals Halogens Noble Gases Chemical Bonding • Atoms chemically bond or react to become stable atoms. • They can do this by gaining, losing, or sharing valence electrons. Nerdy electrons? • Use the nerds on the Energy Level Diagrams to represent electrons in the energy levels of the neutral atoms in the slides that follow: Nerdy electrons? Fluorine (A#9) Nerdy electrons? Fluorine – using the nerds to represent electrons, show the proper location of fluorine’s 9 electrons in its energy levels Nerdy electrons? Fluorine (A#9) Nerdy electrons? Fluorine: What change would make it chemically stable? Nerdy electrons? Fluorine: Adding 1 more valence electron would give it a stable 8 !!! -- Nerdy electrons? Fluorine: What effect does this have on the fluorine atom? -- Nerdy electrons? Fluorine: NOW HAS A CHARGE OF -1 It is now chemically stable!!! -- Nerdy electrons? Sulfur (A#16) Nerdy electrons? Sulfur – using the nerds to represent electrons, show the proper location of sulfur’s 16 electrons in its energy levels Nerdy electrons? Sulfur (A#16) Nerdy electrons? Sulfur: What change would make it chemically stable? Nerdy electrons? Sulfur: Adding 2 more valence electrons would give it a chemically stable 8 !!! -- -- Nerdy electrons? Sulfur: What effect does this have on the fluorine atom? -- -- Nerdy electrons? Sulfur: IT NOW HAS A CHARGE OF -2 It is now chemically stable!!! -- -- Nerdy electrons? Sodium (A#11) Nerdy electrons? Sodium – using the nerds to represent electrons, show the proper location of sodium’s 11 electrons in its energy levels Nerdy electrons? Sodium (A#11) Nerdy electrons? Sodium: What change would make it chemically stable? Nerdy electrons? Sodium: -- Adding 7 more valence electrons would give it a chemically stable 8 !!! -- -- -- -- -- -- Nerdy electrons? Sodium: -- But… is there an easier way? -- -- -- -- -- -- Nerdy electrons? Sodium: Take a look again. Is there a different way to get 8 valence electrons? Nerdy electrons? Sodium: Losing 1 electron would leave 0 in the 3rd energy level, making the 2nd energy level the valence shell… which would now have a chemically stable 8!!! Nerdy electrons? Sodium: NOW HAS A CHARGE OF +1!!! It is chemically stable. Nerdy electrons? • Other examples: Nerdy electrons? Magnesium (Construct if you have pink nerds) Oxygen (Construct if you have purple nerds) Nerdy electrons? • So… where do atoms pick up extra electrons? Nerdy electrons? - - Nerdy electrons? • From other atoms that want to lose them!!! Ions • When an atom gains or loses electrons to become stable, it is called an ion. • An ion is a charged atom. Positive Ions • Atoms that lose electrons become positively charged. • These positive ions are called cations. Negative Ions • Atoms that gain electrons become negatively charged. • Negative ions are called anions. Ionic Bonding • Atoms looking to be stable may transfer electrons to other atoms. • Each atom becomes charged, and positive ions are then attracted to negative ions. Ionic Compounds • The attraction of positive ions to negative ions is called an ionic bond. • Atoms that bond this way are called ionic compounds. Ionic Compounds • Here’s how it happens: • Ionic Bond Video Clip 1 • Ionic Bond Video Clip 2 • Ionic Bond Video Clip 3 Ionic Bonding Learning Checks • Ready your Remotes Atoms that gain or lose electrons in order to become more chemically stable are called 0% 1. Isotopes 0% 2. Ions 0% 3. Radioactive 0% 4. Neutral What would a chlorine atom do to become chemically stable? (A# = 17) 0% 0% 0% 0% 1. 2. 3. 4. Gain 1 electron Lose 1 electron Gain 2 electrons Lose 7 electrons What would an iodine atom do to become chemically stable? (A# = 53) 0% 0% 0% 0% 1. 2. 3. 4. Gain 1 electron Lose 1 electron Gain 2 electrons Lose 7 electrons Learning Checks • Return your Remote • Complete PACKET pages 17-18 Ionic Bonds Learning Checks • Ready your Remotes How many valence electrons does rubidium have(A# = 37) ? 0% 0% 0% 0% 1. 2. 3. 4. 1 2 7 37 Stable atoms have how many valence electrons? 5% 85% 5% 5% 1. 2. 3. 4. 1 4 8 20 What would a rubidium atom do to become chemically stable? (A# = 37) 0% 0% 0% 0% 1. 2. 3. 4. Gain 1 electron Lose 1 electron Gain 2 electrons Lose 3 electrons Learning Checks • Return your Remotes Learning Checks • Ready your Remotes Stable atoms have how many valence electrons? 0% 0% 0% 0% 1. 2. 3. 4. 1 4 8 20 How many valence electrons does potassium have(A# = 19) ? 0% 0% 0% 0% 1. 2. 3. 4. 1 2 7 19 What would a potassium atom do to become chemically stable? (A# = 19) 0% 0% 0% 0% 1. 2. 3. 4. Gain 1 electron Lose 1 electron Gain 2 electrons Lose 3 electrons Atoms that gain or lose electrons in order to become more chemically stable are called 0% 1. Isotopes 0% 2. Ions 0% 3. Radioactive 0% 4. Neutral JOURNAL#2 • Draw electron dot diagrams of Fluorine, Chlorine, Bromine, & Iodine Learning Checks • Ready your Remotes How many valence electrons does sulfur have(A# = 16) ? 0% 15% 85% 0% 1. 2. 3. 4. 8 7 6 4 Stable atoms have how many valence electrons? 0% 0% 0% 0% 1. 2. 3. 4. 1 4 8 20 What would a sulfur atom do to become chemically stable? (A# = 16) 0% 0% 0% 0% 1. 2. 3. 4. Gain 2 electrons Lose 2 electrons Gain 3 electrons Lose 3 electrons Oxidation Numbers • Turn to page 3 of your packet Oxidation Number • The oxidation number is essentially the bonding power of an atom. • The oxidation number of an atom is the charge that it will tend to acquire when bonding. Oxidation Number • A positive oxidation number means that an atom will lose electrons when forming an ionic bond. • A negative oxidation number means that it will gain electrons. Sample Oxidation Numbers • Chlorine: • Sodium: • Calcium: • Sulfur: • Aluminum: -1 +1 +2 -2 +3 Video Clips • Intro to Bonding (Ionic) 4:30 • Valence electrons 2:46 Learning Checks • Ready your Remote How many valence electrons does phosphorus have(A# = 15) ? 0% 0% 0% 0% 1. 2. 3. 4. 7 6 5 4 What would a phosphorus atom do to become chemically stable? (A# = 15) 0% 0% 0% 0% 1. 2. 3. 4. Gain 2 electrons Lose 2 electrons Gain 3 electrons Lose 3 electrons What is the oxidation number of phosphorus? (A# = 15) 0% 0% 0% 0% 1. 2. 3. 4. +1 -1 -2 -3 What is the oxidation number of nitrogen? (A# = 7) 0% 0% 0% 0% 1. 2. 3. 4. +1 -1 -2 -3 What is the oxidation number of chlorine? (A# = 17) 0% 0% 0% 0% 1. 2. 3. 4. +1 -1 -2 -3 What is the oxidation number of magnesium? (A# = 12) 0% 0% 0% 0% 1. 2. 3. 4. +1 +2 -2 -1 Learning Checks • Return your Remote • Complete the “Periodic Table Perspectives” sheet Video Clips • Element Rap 3:00 • The Noble Gas Song 3:28 • The Noble Gas Rap 2:50 Entrance Questions • Ready your remote How many valence electrons does an arsenic atom have? (A# = 33) 0% 0% 0% 0% 1. 2. 3. 4. 1 3 5 7 What is the oxidation number of arsenic? (A# = 33) 0% 0% 0% 0% 1. 2. 3. 4. +1 +2 -3 -2 How many energy levels does an arsenic atom have? (A# = 33) 0% 0% 0% 0% 1. 2. 3. 4. 5 2 3 4 Changing An Atom • RETURN YOUR REMOTE • Turn to page 19 of your packet & complete it • Pick up a copy of the “Families of the Periodic Table” worksheet Video Clips • Families of the Periodic Table 14:42 • Groups of Elements on the Periodic Table 7:26 Video Clips • Alkali Metals in Water 2:22 • Sodium & Potassium in Water 0:53 • The Halogens 3:40 Learning Checks • Ready your Remote • Get ready to consult your periodic table!! What is the oxidation number of strontium? (A# = 38) 0% 0% 0% 0% 1. 2. 3. 4. +1 +2 -1 -2 What is the oxidation number of oxygen? 0% 0% 0% 0% 1. 2. 3. 4. +1 +2 -1 -2 What would a calcium atom do to become chemically stable? (A# = 20) 0% 0% 0% 0% 1. 2. 3. 4. Gain 1 electron Lose 1 electron Lose 2 electrons Gain 2 electrons In a chemical reaction, what would an oxygen atom do? 0% 0% 0% 0% 1. 2. 3. 4. Gain 1 electron Lose 1 electron Gain 2 electrons Lose 2 electrons Learning Checks • Return your remote • Turn to page 20 of your PACKET • Make sure you finish page 20 – 21 “Bonding Basics – Ionic Bonds” Covalent Bonding • When atoms share electrons to become stable, it is called a covalent bond. • Covalently bonded atoms are called molecules. Sample Molecule • Hydrogen Fluoride Before After HF Sample Molecule • Ammonia Before After NH3 Sample Molecule • Oxygen (diatomic molecule) Before After O2 Video Clips • The Bonding Song 4:19 Polyatomic Ions • Polyatomic ions are covalently bonded atoms that still hold a positive or negative charge. • Sometimes called radicals, these molecules act as one and can form ionic compounds. Common Polyatomic Ions • Ammonium • Acetate • Hydroxide • Nitrate • Carbonate +1 NH4 C2H3O2-1 OH-1 NO3-1 CO3-2 Law of Conservation of Matter • The Law of Conservation of Matter states that matter is neither created nor destroyed in a chemical reaction. • Matter can just change from one form to another. Law of Conservation of Matter • The mass of the reactants is equal to the mass of the products of a chemical reaction. • The number of atoms before a chemical reaction is the same as the number after a chemical reaction. Law of Conservation of Matter • REACTANTS PRODUCTS Law of Conservation of Matter • REACTANTS PRODUCTS 4H 4H 2O 2O BALANCED CHEMICAL EQUATION: 4 H2 + 2 O2 2 H 2O Law of Conservation of Matter • REACTANTS PRODUCTS Law of Conservation of Matter • REACTANTS PRODUCTS TOTAL ATOMS TOTAL ATOMS 2H 2H 2 Cl 2 Cl BALANCED CHEMICAL EQUATION: H2 + Cl2 2 HCl TOTAL MASS: 2 (1.0g) + 2 (35.5 g) = 2 (36.5 g) 73. 0 g = 73.0 g The Law of Conservation of Matter BALANCED CHEMICAL EQUATION: Na2SO4+ Ca Cl2 CaSO4+ 2 NaCl The Law of Conservation of Matter 27 grams of aluminum react with 24 grams of oxygen. What mass of aluminum oxide forms? 0% 0% 0% 0% 1. 2. 3. 4. 27 grams 24 grams 25.5 grams 51 grams What coefficient should go in front of the H2 to properly balance this equation? 2 H 2 O ? H 2 + O2 0% 0% 0% 0% 1. 2. 3. 4. 1 2 3 4 Law of Conservation of Matter • Video 1 • Homer & Conservation of Mass 2 • Antoine Lavoisier's Discovery 3 Bibliography • Bohr Models from www.chemicalelements.com