U4 S1 L1 Defining Oxidation and reduction LEO & Mervin Textbook Readings MHR •page 712: Oxidation-Reduction Reactions •pages 713-715: Defining Oxidation and Reduction •pages 715-716: Half Reactions Textbook Practice Items MHR •page 715: items 1, 2, 3 and 4 •page 716: items 5, 6, 7 and 8 •page 720: items 1, 2, 3, 4, 5 and 6 OIL RIG Upon completion of this lesson, you should be able to: • define oxidation and reduction in terms or loss or gain of electrons • identify electron transfer in redox equations • state that a chemical entity loses electrons when it is oxidized and that a chemical entity gains electrons when it is reduced • identify oxidation and reduction half-reaction equations in an oxidation reduction (redox) equation • identify a redox equation as the sum of the oxidation half-reaction and the reduction half-reaction • identify the species oxidized, the species reduced, the oxidizing agent, and the reducing agent in simple redox equations • Oxidation-reduction reactions involve the transfer of electrons from one species to another. • The species that loses electrons is said to be oxidized • The species that gains electrons is said to be reduced • In order for an oxidation-reduction reaction to take place, we need both process to occur. That is, we cannot have oxidation with out reduction. Why not? • LEO is an OX – Loss of Electrons is Oxidation • OIL RIG Oxidation Is Loss Reduction Is Gain 2 Na( s ) Cl2( g ) 2 NaCl( s ) Interpret using a Lewis dot diagram: Net ionic equations: • Write a net ionic equation for the reaction of solid zinc and an aqueous solution of copper (II) sulphate. • Word equation: • Balanced Chemical equation: • Total Ionic equation • Net ionic equation Zn(s) + Cu2+(aq) → Half reactions: Zn(s) Zn2+(aq) + Cu(s) → Zn2+(aq) + 2 e- • Zn(s) lost 2 electrons (thus Zn(s) was oxidized.) Cu 2+ (aq) + 2 e- → Cu(s) • Cu 2+ gained 2 electrons (thus Cu 2+ was reduced.) • In this case, the electrons were transferred from zinc to copper. – Zn(s) was oxidized by Cu2+ so we say that Cu2+ was an oxidizing agent. • the oxidizing agent is the species causes the the oxidation (it gets reduced) – Similarly we can say that Zn(s) was acting as the reducing agent. • the reducing agent is the species that causes the reduction (it gets oxidized) • Why? • Write a net ionic equation and half reactions for the reaction of magnesium with aqueous aluminum sulphate. • Identify the species oxidized, reduced, the reducing agent and the oxidizing agent. • Disproportionation reaction: – An oxidation reduction reaction in which a single species is both oxidized and reduced. ( aq ) 2Cu 2 ( aq ) Cu( s ) Cu 2Hg(aq ) Hg(l ) Hg(2aq )