The basic unit of an element that can retain the properties of that element in a chemical reaction 1. Protons (P+) 2. Neutrons (N0) 3. Electrons (e - ) Aka: Subatomic Particles Subatomic Particle Symbol Location Relative Mass Charge Proton P+ Nucleus 1 amu +1 Neutron N0 Nucleus 1 amu 0 Electron e- Electron cloud 0 -1 Changing the # of protons changes the identity of the element Changing the # of neutrons change the mass of the atom Changing the number of electrons changes the charge of the atom Since like charges repel, how does the nucleus stay together? Strong forces in the nucleus Atomic Number Tells us how many protons are in the nucleus of each atom of an element Represented by the letter Z What is the atomic number of carbon? How many protons are in the nucleus of a carbon atom? What is the atomic number of carbon? 6 How many protons are in the nucleus of a carbon atom? 6 Mass Number Tells us the number of protons and neutrons in the nucleus of each atom of an element Represented by the letter A Shorthand Notation: Element name – mass number Ex: carbon–12, carbon-14, chlorine-35 12, 14, 35 = mass # (protons + neutrons) Shorthand Notation: AZX notation: X =Element Symbol A =Mass Number Z =Atomic Number Ex: Chlorine-35 Cl always has 17 p+ What is the mass number of carbon-12? How many neutrons are in the nucleus of a carbon-12 atom? What is the mass number of carbon-12? 12 How many neutrons are in the nucleus of a carbon-12 atom? 12 - 6 = 6 Mass # # P+ Mass number = # of protons + # of neutrons Mass # = Atomic # + # of neutrons Number of neutrons = Mass # - Atomic # In a neutral atom, the number of electrons equal the number of protons Neutral: 0 charge (so # of negative charges (e-) = # of positive charges (P+) Isotopes are atoms of the same element that have a different number of neutrons. Changing the number of neutrons will change the mass number Ex: Carbon-11 11 6C Carbon-12 12 6C Carbon-13 Carbon-14 13 6C 14 Ex: 6C *Notice that all carbon isotopes have an atomic number (#of protons) of 6. The number of neutrons change so the mass will change* Single atom extremely small Ex: Fluorine atom mass = 3.155x10-23 More convenient to compare relative masses of atoms using a reference isotope as a standard Chosen reference isotope is carbon-12 Carbon-12 has atomic mass of exactly 12 atomic mass units What is the atomic mass of carbon? What is the atomic mass of chlorine? Single atom extremely small Ex: Fluorine atom mass = 3.155*10-23 More convenient to compare relative masses of atoms using a reference isotope as a standard Chosen reference isotope is carbon-12 Carbon-12 has atomic mass of exactly 12 atomic mass units 1 atomic mass unit (amu) = 1/12 mass of carbon-12 What is the atomic mass of carbon? 12.011 What is the atomic mass of chlorine? 35.45 Bottom Line: The atomic mass is a weighted average of the masses of an element’s isotope Use a weighted average Formula: (mass 1)(%abundance 1)+(mass2)(%abundance 2) +… **% abundances should be in decimal form** (take your percentage & divide by 100) Formula: (mass 1)(%abundance 1)+(mass2)(%abundance 2) +… **% abundances should be in decimal form** (take your percentage & divide by 100) Ex: Boron forms 2 stable isotopes, boron-10 and boron-11. The relative abundance of the isotope are 19.8% and 80.2% respectively. What is the atomic mass? Formula: (mass 1)(%abundance 1)+(mass2)(%abundance 2) +… **% abundances should be in decimal form** (take your percentage & divide by 100) Ex: Boron forms 2 stable isotopes, boron-10 and boron-11. The relative abundance of the isotope are 19.8% and 80.2% respectively. What is the atomic mass? (10amu)(.198) + (11amu)(.802) = 10.80 amu Check yourself: Atomic # should match periodic table An ion is an atom or group of atoms that has a charge A neutral atom has equal numbers of protons and electrons Ions form as atoms gain or lose electrons Don’t mess with the protons!! Examples 7 1+ 3Li 16 8 O2- 24 2+ Mg 12 Protons- 12 Neutrons- 12 Electrons- 10 *If the ion is positive, subtract e*If the ion is negative, add e- Examples 7 1+ 3Li 16 8 O2- 24 2+ Mg 12 Protons- 3 8 12 Neutrons- 7-3=4 16-8=8 12 Electrons- 2 10 10 *If the ion is positive, subtract e*If the ion is negative, add e-