What are they? There are different definitions for acids and bases depending on the circumstances. Acid—produces hydrogen ions (H+) in solution Bases—produces hydroxide ions (OH-) in solution 1. 2. 3. 4. 5. 6. 7. Acids react with carbonates to produce carbon dioxide gas. change pink phenolphthalein to colourless make litmus paper turn red or stay red make bromothymol blue turn yellow taste sour have a pH below 7 react with most metals producing hydrogen gas 1. 2. 3. 4. 5. 6. Bases don’t react with carbonates to produce carbon dioxide gas. change colourless phenolphthalein to pink make litmus paper turn blue or stay blue make bromothymol blue stay blue taste bitter have a pH above 7 Common Acids Acid Formula Weak or Strong Use Sulfuric Acid H2S04 Strong Car batteries Hydrochloric Acid HCl Strong Stomach Acetic Acid CH3COOH Weak vinegar Phosphoric Acid H3PO4 Strong Softdrinks, fertilizers Nitric Acid HNO3 Strong Nitroglycerine, fertilizers, plastics Common Bases Base Formula Weak or Strong Use Ammonia NH3 Weak Windex Sodium Hydroxide or Lye NaOH Strong Drain Cleaners Calcium Carbonate CaCO3 Weak Antacids such as Tums, Rolaids Potassium hydroxide KOH Strong Bio diesel, soaps What substances in water make acids acidic and bases alkaline? •All aqueous solutions have H+ ions and OH1- ions. •When the quantities of these ions are equal the solution is neutral since the H+ ions and OH1- ions combine to form H2O. •Lets look at an aqueous solution below: Is the solution below acidic or basic? basic Notice water molecules will sometimes break apart. •The pH scale has been established to measure the quantities of H+ and OH1in a aqueous solution. •A neutral substance with a pH of 7 has 1+ 1equal quantities of H and OH . •An acidic substance has a pH below 7. •A basic substance has a pH above 7. More H1+ than OH1- More OH1- Than H1+ -1 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 N Increasing basicity Increasing acidity e How much more Since this is a acidic is pH 1 than u logarithmic scale t pH 9 is 10x’s more pH 5? r basic than pH 8, pH 10 000 x’s What pH is 1000x’s a 12 is 1000 x’s more more acidic than l basic than pH 9 pH 2? pH of -1 Acid - Base Neutralizations Acids and bases react producing salt and water. HCl + NaOH NaCl + H2O What kind of a reaction is this? A double displacement. NaOH HCl What are the products? H2O and NaCl Water and an ionic compound or an ionic salt HCl NaOH What are the products when carbonic acid is added to calcium hydroxide? 1st write the balanced chemical equation H2CO3 + Ca(OH)2 CaCO3 + 2 H2O The salt’s name is calcium carbonate What are the products when nitric acid is added to potassium hydroxide? 1st write the balanced chemical equation. HNO3 + KOH KNO3 + H2O The salt’s name is potassium nitrate What are the products when chloric acid is added to lithium hydroxide? 1st write the balanced chemical equation. HClO3 + LiOH LiClO3 + H2O The salt’s name is lithium chlora Antacids (ex. Tums or Rolaids) •Antacid tablets used to treat excess stomach acid (heartburn) are reallybases which neutralize acids. •Antacids cause a neutralization reaction in your stomach that produces salt and water. Factors that Affect an Acid or Base’s Strength 1. Concentration More molecules of acid or base per litre of water Factors that Affect an Acid or Base’s Strength 2. Percent Ionization Strong acids and bases have a high percent ionization A high % of molecules of strong acid will break into ions (ionize) when mixed with water Ex #1. HCl H+ + Cl100 molecules 99 cations 99 anions A low % of molecules of weak acid will break into ions (ionize) when mixed with water Ex #1. CH3COOH H+ + CH3COO100 molecules 4 cations 4 anions Oxides of Elements • Metal oxides in aqueous solutions tend to produce bases Ex. Sodium reacting in water produces Sodium hydroxide • Non-metal oxides in aqueous solutions tend to produce acids Sulfur and nitrogen oxides react with water to produce sulfuric acid and nitric acid (cause of acid precipiation)