Name: ANSWER KEY Date: __________________ Period: _________ Organic Chemistry Review Sheet I. Introduction to Organic Chemistry 1. Which of the following compounds is formed by covalent bonding? a) Na2S b) AlCl3 c) C6H12O6 d) LiH 2. Which of the following molecules contains a nonpolar covalent bond? a) H2O b) HF c) F2 d) NH3 3. Which of the following molecules is polar? (Circle all that apply.) a) H2O b) HF c) F2 d) NH3 4. Which of the following molecules has the strongest London dispersion force attractions? a) CH4 b) C2H6 c) C3H8 d) C4H10 5. Which of the following nonpolar molecules has the lowest boiling point? a) CH4 b) C2H6 c) C3H8 d) C4H10 6. Which of the following substances is organic? a) NaCl b) NH3 c) CH4 d) H2O 7. Which of the following substances is insoluble in water? a) NaCl b) NH3 c) CH4 d) H2O 8. When 2 carbon atoms form a double bond, how many pairs of e- will be shared between them? TWO 9. An organic compound is heated in the presence of oxygen. If a high enough temperature is reached, what chemical reaction will take place? COMBUSTION 10. An alkane has 5 carbon atoms. How many hydrogen atoms will it have? 12 11. An alkene has 3 carbon atoms. How many hydrogen atoms will it have 4 12. An alkyne has 4 carbon atoms. How many hydrogen atoms will it have? 8 II. Naming & Drawing Simple Organic Molecules A) Name the following compounds: butane heptane ethane 2-hexene propene 1-hexene 7. C2H6 ethane Homologous Series: ALKANE 8. C3H4 propyne Homologous Series: ALKYNE 9. C4H8 butene Homologous Series: ALKENE B) Draw the following compounds. Then, draw and name one isomer of the compound. Butane Isomer of Butane 2-methylpropane 1-Butyne Isomer of 1-Butyne 2-butyne Pentane Isomer of Pentane 2-methylbutane 1|Page III. Naming & Drawing Substituted Hydrocarbons A) Name the following compounds: 2,2-dichlorobutane 1-chloropropane 1,2-difluoroethane 1,1-difluoroethane 2-methylpentane 2,5-dimethylheptane B) Draw the following compounds. 2 chloro propane 1,2 dichloro butane 1,4 dichloro pentane 3 methyl heptane 2,2 dimethyl octane 3,4-dichloro-1,3-hexadiene 2|Page IV. Organic Chemical Reactions 1. Which of the following reactions is an addition reaction? a) C2H6 + Cl2 --> C2H5Cl + HCl c) C2H4 + Cl2 --> C2H4Cl2 b) C2H6 + Cl2 --> C2H5Cl + HCl d) C3H8 + HBr --> C3H7Br + H2 2. Which of the following hydrocarbons can undergo an addition reaction? a) C3H8 b) C4H8 c) C5H12 d) CH4 3. Which of the following products can form when propene reacts with diatomic chlorine? a) C3H8Cl2 b) C3H7Cl2 c) C3H6Cl2 d) C3H8Cl 4. Complete the following reactions and indicate whether they are addition or substitution reactions. Give the name of the organic reactants and products, only. a) SUBSTITUTION: ethane + bromine bromoethane + hydrogen bromide b) ADDITION: propene + bromine 1,2-dibromopropane c) SUBSTITUTION: ethane + hydrogen bromide bromoethane + hydrogen d) ADDITION: propene + hydrogen bromide bromoethane 5. State what kind of reaction can form the following products and identify the reactants that are needed to make those products. a) 1 fluoro butane Type of reaction: Substitution Reactants needed: Butane + Fluorine 3|Page b) 1,2 dichloro butane Type of reaction: Addition Reactants needed: Butene + Chlorine V. Functional Groups A) Draw the structures of the following organic compounds and indicate if the functional group is attached to a primary or secondary carbon. Name Functional Group Structural Formula Ketone 2-pentanone Organic Acid Propanoic acid Amine Ethanamine Amide Butanamide Methyl ethanoate Ester Ether Methyl propyl ether 2- pentanol BE SPECIFIC! Monohydroxy, Secondary Alcohol 4|Page 1-pentanol B) BE SPECIFIC! Monohydroxy, Primary Alcohol Which of the following molecules is an isomer of propanol? a) propanone b) methyl ethyl ether c) propanal d) propanoic acid ***NOTE*** Don’t forget to review the organic reactions “Let’s Practice” handout on page 33, as well as the videos on fractional distillation and cracking on Ms. Roman’s website. 5|Page