Atomic Structure

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Atomic Structure

What Is An Atom?

• the smallest particle of an element that retains the chemical properties of that element

• Can be subdivided into electrons (e ), protons

(p + ) and neutrons (n 0 )

Diagram Of An Atom

Important Info About Subatomic

Particles

Particle Relative

Electric Charge

Mass Number Relative Mass

(amu)

Actual Mass

(kg)

Electron (e )

Proton (p + )

Neutron (n o )

-1

+1

0

0

1

1

.0005486

1.007276

1.008665

9.109 x 10 -31

1.673 x 10 -27

1.675 x 10 -27

1 amu = (1/12)(mass of C-12 isotope in kg)

1 amu = 1.660540 x 10 -27 kg

Amu = atomic mass units

Atomic Number (Z)

• Tells us the number of protons in the nucleus of an atom

Z

Isotopes

• Some atoms of the same element will have different masses.

• These atoms are called isotopes because they have the same number of protons, but differ in the number of neutrons.

• Isotopes of the same element have different mass numbers.

• Mass number (A) is the total number of protons and neutrons in the nucleus of an isotope

How Are Isotope Symbols Denoted?

Hyphen Notation of Isotopes

• Isotopes can also be denoted through hyphen notation

• The element symbol will be listed, following a hyphen, and then a mass number (p + + n 0 )

• Ex. Hydrogen has 3 isotopes (H-1, H-2, H-3)

AKA “Protium”

99.985% Abundant

H-1

Hydrogen Isotopes

.015% Abundant

H-2

Radioactive, Prepared

Artifically

H-3

Sample Problems

• How many protons, electrons, and neutrons are there in a Cl-37 atom?

• How many protons, electrons, and neutrons are there in the following isotopes?

-1

Atomic Mass

• What is the atomic mass listed on the periodic table under each element really measuring?

• This mass is a weighted average of all of the naturally occurring isotopes of an element

• This mass is a relative average (compared to the C-12 isotope) in atomic mass units (amu)

How To Find The Atomic Mass of

Hydrogen

H-1 is 99.985% abundant with an atomic mass of 1.007825 amu

H-2 is .015% abundant with an atomic mass of 2.016490 amu

H-3 is not counted because of the fact that it is not naturally occurring

To find the weighted average:

(% abundance/100)(relative atomic mass of isotope 1) +

(% abundance/100)(relative atomic mass of isotope 2) +

(% abundance/100)(relative atomic mass of isotope 3)…

*Mass # may be substituted for the relative atomic mass when given

(99.985%/100)(1.007825 amu) + (.015%/100)(2.016940 amu)

= 1.0079 amu

Things To Remember…

• If you change the number of protons, you change the type of atom itself.

• If you change the number of electrons, you change the atom to an ion (charged particle).

• If you change the number of neutrons, you change the isotope of that element.

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