Chapter 29 Nuclear Physics Milestones in the Development of Nuclear Physics 1896 – the birth of nuclear physics Becquerel discovered radioactivity in uranium compounds Rutherford showed the radiation had three types Alpha (He nucleus) Beta (electrons) Gamma (high-energy photons) More Milestones 1911 Rutherford, Geiger and Marsden performed scattering experiments Established the point mass nature of the nucleus Nuclear force was a new type of force 1919 Rutherford and coworkers first observed nuclear reactions in which naturally occurring alpha particles bombarded nitrogen nuclei to produce oxygen Milestones, final 1932 Cockcroft and Walton first used artificially accelerated protons to produce nuclear reactions 1932 Chadwick discovered the neutron 1933 the Curies discovered artificial radioactivity 193 Hahn and Strassman discovered nuclear fission 1942 Fermi and collaborators achieved the first controlled nuclear fission reactor Some Properties of Nuclei All nuclei are composed of protons and neutrons Exception is ordinary hydrogen with just a proton The atomic number, Z, equals the number of protons in the nucleus The neutron number, N, is the number of neutrons in the nucleus The mass number, A, is the number of nucleons in the nucleus A=Z+N Nucleon is a generic term used to refer to either a proton or a neutron The mass number is not the same as the mass Symbolism A Z X X is the chemical symbol of the element Example: 27 13 Al Mass number is 27 Atomic number is 13 Contains 13 protons Contains 14 (27 – 13) neutrons The Z may be omitted since the element can be used to determine Z More Properties The nuclei of all atoms of a particular element must contain the same number of protons They may contain varying numbers of neutrons Isotopes of an element have the same Z but differing N and A values 14 13 12 Example: 11 C C C C 6 6 6 6 Charge The proton has a single positive charge, +e The electron has a single negative charge, -e The neutron has no charge Makes it difficult to detect e = 1.60217733 x 10-19 C Mass It is convenient to use atomic mass units, u, to express masses 1 u = 1.660559 x 10-27 kg Based on definition that the mass of one atom of C-12 is exactly 12 u Mass can also be expressed in MeV/c2 From ER = m c2 1 u = 931.494 MeV/c2 Summary of Masses Masses Particle kg u MeV/c2 Proton 1.6726 x 10-27 1.007276 938.28 Neutron 1.6750 x 10-27 1.008665 939.57 Electron 9.101 x 10-31 5.486x10-4 0.511 The Size of the Nucleus First investigated by Rutherford in scattering experiments He found an expression for how close an alpha particle moving toward the nucleus can come before being turned around by the Coulomb force The KE of the particle must be completely converted to PE Size of the Nucleus, cont d gives an upper limit for the size of the nucleus Rutherford determined that 4k e Ze 2 d mv 2 For gold, he found d = 3.2 x 10-14 m For silver, he found d = 2 x 10-14 m Such small lengths are often expressed in femtometers where 1 fm = 10-15 m Also called a fermi Size of Nucleus, Current Since the time of Rutherford, many other experiments have concluded the following Most nuclei are approximately spherical Average radius is r ro A 1 3 ro = 1.2 x 10-15 m Density of Nuclei The volume of the nucleus (assumed to be spherical) is directly proportional to the total number of nucleons This suggests that all nuclei have nearly the same density Nucleons combine to form a nucleus as though they were tightly packed spheres Nuclear Stability There are very large repulsive electrostatic forces between protons These forces should cause the nucleus to fly apart The nuclei are stable because of the presence of another, short-range force, called the nuclear force This is an attractive force that acts between all nuclear particles The nuclear attractive force is stronger than the Coulomb repulsive force at the short ranges within the nucleus Nuclear Stability, cont Light nuclei are most stable if N = Z Heavy nuclei are most stable when N > Z As the number of protons increase, the Coulomb force increases and so more nucleons are needed to keep the nucleus stable No nuclei are stable when Z > 83 Binding Energy The total energy of the bound system (the nucleus) is less than the combined energy of the separated nucleons This difference in energy is called the binding energy of the nucleus It can be thought of as the amount of energy you need to add to the nucleus to break it apart into separated protons and neutrons Binding Energy per Nucleon Binding Energy Notes Except for light nuclei, the binding energy is about 8 MeV per nucleon The curve peaks in the vicinity of A = 60 Nuclei with mass numbers greater than or less than 60 are not as strongly bound as those near the middle of the periodic table The curve is slowly varying at A > 40 This suggests that the nuclear force saturates A particular nucleon can interact with only a limited number of other nucleons Radioactivity Radioactivity is the spontaneous emission of radiation Experiments suggested that radioactivity was the result of the decay, or disintegration, of unstable nuclei Radioactivity – Types Three types of radiation can be emitted Alpha particles The particles are 4He nuclei Beta particles The particles are either electrons or positrons – A positron is the antiparticle of the electron – It is similar to the electron except its charge is +e Gamma rays The “rays” are high energy photons Distinguishing Types of Radiation The gamma particles carry no charge The alpha particles are deflected upward The beta particles are deflected downward A positron would be deflected upward Penetrating Ability of Particles Alpha particles Beta particles Barely penetrate a piece of paper Can penetrate a few mm of aluminum Gamma rays Can penetrate several cm of lead The Decay Constant The number of particles that decay in a given time is proportional to the total number of particles in a radioactive sample ΔN = -λ N Δt λ is called the decay constant and determines the rate at which the material will decay The decay rate or activity, R, of a sample is defined as the number of decays per second N R N t Decay Curve The decay curve follows the equation N = No e- λt The half-life is also a useful parameter The half-life is defined as the time it takes for half of any given number of radioactive nuclei to decay T1 2 ln 2 0.693 Units The unit of activity, R, is the Curie, Ci 1 Ci = 3.7 x 1010 decays/second The SI unit of activity is the Becquerel, Bq 1 Bq = 1 decay / second Therefore, 1 Ci = 3.7 x 1010 Bq The most commonly used units of activity are the mCi and the µCi QUICK QUIZ 29.1 What fraction of a radioactive sample has decayed after two half-lives have elapsed? (a) 1/4 (b) 1/2 (c) 3/4 (d) not enough information to say QUICK QUIZ 29.1 ANSWER (c). At the end of the first half-life interval, half of the original sample has decayed and half remains. During the second half-life interval, half of the remaining portion of the sample decays. The total fraction of the sample that has decayed during the two halflives is: 1 11 3 2 22 4 QUICK QUIZ 29.2 The activity of a newly discovered radioactive isotope reduces to 96% of its original value in an interval of 2 hours. What is its half-life? (a) 10.2 h (c) 44.0 h (b) 34.0 h (d) 68.6 h QUICK QUIZ 29.2 ANSWER (b). If the original activity is R0, the activity remaining after an elapsed time t is R = R0e-λt = R0e-(0.693/T1/2)t . Solving for the half-life yields T1/2 = [0.693/ln(R/R0)]t. If R = 0.96R0 at t = 2.0 hr, the half-life is: T1/2 = [-0.693/ln(0.96)](2.0 h) = 34 h. Alpha Decay When a nucleus emits an alpha particle it loses two protons and two neutrons N decreases by 2 Z decreases by 2 A decreases by 4 Symbolically X A Z A 4 Z 2 Y He 4 2 X is called the parent nucleus Y is called the daughter nucleus Alpha Decay -- Example Decay of 226 88 226 Ra 4 Ra222 Rn 86 2 He Half life for this decay is 1600 years Excess mass is converted into kinetic energy Momentum of the two particles is equal and opposite Decay – General Rules When one element changes into another element, the process is called spontaneous decay or transmutation The sum of the mass numbers, A, must be the same on both sides of the equation The sum of the atomic numbers, Z, must be the same on both sides of the equation Conservation of mass-energy and conservation of momentum must hold QUICK QUIZ 29.3 If a nucleus such as 226Ra that is initially at rest undergoes alpha decay, which of the following statements is true? (a) The alpha particle has more kinetic energy than the daughter nucleus. (b) The daughter nucleus has more kinetic energy than the alpha particle. (c) The daughter nucleus and the alpha particle have the same kinetic energy. QUICK QUIZ 29.3 ANSWER (a). Conservation of momentum requires the momenta of the two fragments be equal in magnitude and oppositely directed. Thus, from KE = p2/2m, the lighter alpha particle has more kinetic energy that the more massive daughter nucleus. Beta Decay During beta decay, the daughter nucleus has the same number of nucleons as the parent, but the atomic number is one less Symbolically A Z X Y e A Z X Y e A Z 1 A Z 1 Beta Decay, cont The emission of the electron is from the nucleus The nucleus contains protons and neutrons The process occurs when a neutron is transformed into a proton and an electron Energy must be conserved Beta Decay – Electron Energy The energy released in the decay process should almost all go to kinetic energy of the electron Experiments showed that few electrons had this amount of kinetic energy Neutrino To account for this “missing” energy, in 1930 Pauli proposed the existence of another particle Enrico Fermi later named this particle the neutrino Properties of the neutrino Zero electrical charge Mass much smaller than the electron, probably not zero Spin of ½ Very weak interaction with matter Beta Decay – Completed Symbolically XZA1Y e A Z X Y e A Z 1 is the symbol for the neutrino is the symbol for the antineutrino To summarize, in beta decay, the following pairs of particles are emitted An electron and an antineutrino A positron and a neutrino A Z Gamma Decay Gamma rays are given off when an excited nucleus “falls” to a lower energy state Similar to the process of electron “jumps” to lower energy states and giving off photons The excited nuclear states result from “jumps” made by a proton or neutron The excited nuclear states may be the result of violent collision or more likely of an alpha or beta emission Gamma Decay – Example Example of a decay sequence The first decay is a beta emission The second step is a gamma emission 12 5 B C * e 12 6 C*126 C 12 6 The C* indicates the Carbon nucleus is in an excited state Gamma emission doesn’t change either A or Z Uses of Radioactivity Carbon Dating Beta decay of 14C is used to date organic samples The ratio of 14C to 12C is used Smoke detectors Ionization type smoke detectors use a radioactive source to ionize the air in a chamber A voltage and current are maintained When smoke enters the chamber, the current is decreased and the alarm sounds More Uses of Radioactivity Radon pollution Radon is an inert, gaseous element associated with the decay of radium It is present in uranium mines and in certain types of rocks, bricks, etc that may be used in home building May also come from the ground itself Natural Radioactivity Classification of nuclei Unstable nuclei found in nature Nuclei produced in the laboratory through nuclear reactions Give rise to natural radioactivity Exhibit artificial radioactivity Three series of natural radioactivity exist Uranium Actinium Thorium Decay Series of 232Th Series starts with 232Th Processes through a series of alpha and beta decays Ends with a stable isotope of lead, 208Pb Nuclear Reactions Structure of nuclei can be changed by bombarding them with energetic particles The changes are called nuclear reactions As with nuclear decays, the atomic numbers and mass numbers must balance on both sides of the equation QUICK QUIZ 29.4 Which of the following are possible reactions? QUICK QUIZ 29.4 ANSWER (a) and (b). Reactions (a) and (b) both conserve total charge and total mass number as required. Reaction (c) violates conservation of mass number with the sum of the mass numbers being 240 before reaction and being only 223 after reaction. Q Values Energy must also be conserved in nuclear reactions The energy required to balance a nuclear reaction is called the Q value of the reaction An exothermic reaction There is a mass “loss” in the reaction There is a release of energy Q is positive An endothermic reaction There is a “gain” of mass in the reaction Energy is needed, in the form of kinetic energy of the incoming particles Q is negative Threshold Energy To conserve both momentum and energy, incoming particles must have a minimum amount of kinetic energy, called the threshold energy KEmin m 1 Q M m is the mass of the incoming particle M is the mass of the target particle If the energy is less than this amount, the reaction cannot occur QUICK QUIZ 29.5 If the Q value of an endothermic reaction is -2.17 MeV, the minimum kinetic energy needed in the reactant nuclei if the reaction is to occur must be (a) equal to 2.17 MeV, (b) greater than 2.17 MeV, (c) less than 2.17 MeV, or (d) precisely half of 2.17 MeV. QUICK QUIZ 29.5 ANSWER (b). In an endothermic reaction, the threshold energy exceeds the magnitude of the Q value by a factor of (1+ m/M), where m is the mass of the incident particle and M is the mass of the target nucleus. Radiation Damage in Matter Radiation absorbed by matter can cause damage The degree and type of damage depend on many factors Type and energy of the radiation Properties of the absorbing matter Radiation damage in biological organisms is primarily due to ionization effects in cells Ionization disrupts the normal functioning of the cell Types of Damage Somatic damage is radiation damage to any cells except reproductive ones Can lead to cancer at high radiation levels Can seriously alter the characteristics of specific organisms Genetic damage affects only reproductive cells Can lead to defective offspring Units of Radiation Exposure Roentgen [R] is defined as That amount of ionizing radiation that will produce 2.08 x 109 ion pairs in 1 cm3 of air under standard conditions That amount of radiation that deposits 8.76 x 10-3 J of energy into 1 km3 of air Rad (Radiation Absorbed Dose) That amount of radiation that deposits 10-2 J of energy into 1 kg of air More Units RBE (Relative Biological Effectiveness) The number of rad of x-radiation or gamma radiation that produces the same biological damage as 1 rad of the radiation being used Accounts for type of particle which the rad itself does not Rem (Roentgen Equivalent in Man) Defined as the product of the dose in rad and the RBE factor Dose in rem = dos in rad X RBE Radiation Levels Natural sources – rocks and soil, cosmic rays Upper limit suggested by US government Background radiation About 0.13 rem/yr 0.50 rem/yr Excludes background and medical exposures Occupational 5 rem/yr for whole-body radiation Certain body parts can withstand higher levels Ingestion or inhalation is most dangerous Applications of Radiation Sterilization Radiation has been used to sterilize medical equipment Used to destroy bacteria, worms and insects in food Bone, cartilage, and skin used in graphs is often irradiated before grafting Applications of Radiation, cont Tracing Radioactive particles can be used to trace chemicals participating in various reactions Example, 131I to test thyroid action CAT scans Computed Axial Tomography Produces pictures with greater clarity and detail than traditional x-rays Applications of Radiation, final MRI Magnetic Resonance Imaging When a nucleus having a magnetic moment is placed in an external magnetic field, its moment processes about the magnetic field with a frequency that is proportional to the field Transitions between energy states can be detected electronically Radiation Detectors A Geiger counter is the most common form of device used to detect radiation It uses the ionization of a medium as the detection process When a gamma ray or particle enters the thin window, the gas is ionized The released electrons trigger a current pulse The current is detected and triggers a counter or speaker Detectors, 2 Semiconductor Diode Detector A reverse biased p-n junction As a particle passes through the junction, a brief pulse of current is created and measured Scintillation counter Uses a solid or liquid material whose atoms are easily excited by radiation The excited atoms emit visible radiation as they return to their ground state With a photomultiplier, the photons can be converted into an electrical signal Detectors, 3 Track detectors Various devices used to view the tracks or paths of charged particles Photographic emulsion – Simplest track detector – Charged particles ionize the emulsion layer – When the emulsion is developed, the track becomes visible Cloud chamber – – – – Contains a gas cooled to just below its condensation level The ions serve as centers for condensation Particles ionize the gas along their path Track can be viewed and photographed Detectors, 4 Track detectors, cont Bubble Chamber Contains a liquid near its boiling point Ions produced by incoming particles leave tracks of bubbles The tracks can be photographed Wire Chamber Contains thousands of closely spaced parallel wires The wires collect electrons created by the passing ionizing particle A second grid allows the position of the particle to be determined Can provide electronic readout to a computer