Cari Robin Hart Module 8 November 3, 2013 Introduction to Organic Chemistry Welcome to Introduction to Organic Chemistry. In this course you will learn about the structure and bonding of molecules, acids and bases, organic molecules, functional groups, alkanes, and stereochemistry. Class will be held synchronously on Mondays, from 6:00-8:50, via Google Hangout and MediaSite. Class will also be held asynchronously on Blackboard. Instructor for the course: Robin Hart Texas Tech University, Department of Chemistry & Biochemistry Memorial Circle & Boston, Lubbock, TX 79409-1061 robin.hart@ttu.edu T 806.742.3067 | F 806.742.1289 Instructor Bio: BS in Secondary Education, Texas Tech University, 1983; MS in Multidisciplinary Science, Texas Tech University, 2012; PhD student in Curriculum and Instruction, Math and Science, Texas Tech University. Areas of research include Lewis acid catalysis in the production of biodiesel and graphene applications. Office Hours: Monday 2:00-4:00 Room 130 Textbook: Organic Chemistry, Janice G. Smith, ISBN-10: 007340277X Course Policies Attendance for synchronous class is mandatory. Please inform the instructor prior to class if you are unable to attend, as participation is part of the final grade. Assignments will be due at 11:59 p.m. on Friday of each week. Course Outline 1 Cari Robin Hart Module 8 November 3, 2013 Module 1 • Structure and Bonding Module 2 • Acids and Bases Module 3 • Organic Molecules and Functional Groups Module 4 • Alkanes Module 5 • Stereochemistry Instructional Activities Monday, January 13: Structure and Bonding Friday, January 17: Module 1 Assignment Due/Discussion Due Monday, January 20: Acids and Bases Friday, January 24: Module 2 Assignment Due/Discussion Due Midterm will be open and available on Monday, January 27 on Blackboard and will close on Friday, January 31. Monday, January 27: Organic Molecules and Functional Groups Friday, January 31: Module 3 Assignment Due/Discussion Due Monday, February 3: Alkanes Friday, February 7: Module 4 Assignment Due/Discussion Due Monday, February 10: Stereochemistry Friday, February 14: Module 5 Assignment Due/Discussion Due Monday, February 17: Final Friday, February 21: Discussion Due The final will be on Monday, February 24 on Blackboard. It will be available from 5:00 p.m. to 10:00 p.m. Goals and Objectives Module 1: The student will be able to: draw Lewis structures; predict molecular shapes; determine what orbitals are used to form bonds; understand how electronegativity affects bond polarity. Module 2: The student will be able to: define and classify Bronsted-Lowry and Lewis acids and bases; draw the products formed from the acid-base reactions; determine the Ka and pKa of selected compounds; rank compounds by increasing rate of acidity. Module 3: The student will be able to: identify functional groups and intermolecular forces; determine physical properties of compounds based on structure; predict solubility. Module 4: The student will be able to: classify carbons and hydrogens by degrees; draw constitutional isomers; give the IUPAC name for compounds; classify isomers; classify reactions as oxidation, reduction, or neither. Module 5: The student will be able to: classify constitutional isomers versus stereoisomers; find and draw stereogenic centers; determine chirality and draw mirror images of compounds. 2 Cari Robin Hart Module 8 November 3, 2013 Reading Assignments Module 1: Organic Chemistry, Janice G. Smith: pages 6-47 Module 2: Organic Chemistry, Janice G. Smith: pages 54-75 Module 3: Organic Chemistry, Janice G. Smith: pages 81-106 Module 4: Organic Chemistry, Janice G. Smith: pages 113-153 Module 5: Organic Chemistry, Janice G. Smith: pages 159-190 Discussion Questions Module 1: Can a compound be nonpolar if it contains one polar bond? Answer with a brief explanation and an example to illustrate your answer. Module 2: Amino acids such as glycine are the building blocks of large molecules called proteins that give structure to muscle, tendon, hair, and nails. Explain why glycine does not actually exist in the form with all atoms uncharged, but actually exists as a salt called a zwitterion. Module 3: Most mayonnaise recipes call for oil, vinegar, and egg yolk. The last ingredient is a source of phospholipids that act as emulsifying agents. Explain. Module 4: Ethylene glycol is unusual in that the gauche conformation is more stable than the anti conformation. Offer an explanation. Module 5: Give an example of enantiomers with different properties. Module 6: Why is it important that drug companies are able to isolate enantiomers? Assignments Module 1: Prior to coming to class, watch the video entitled: “Structure and Bonding.” The link is provided in Blackboard under Module 1. Use the dynamic periodic table, found at http://www.ptable.com/ to explore the orbitals of the following elements: hydrogen, carbon, nitrogen, and oxygen. Also, use the dynamic periodic table to explore the electronegativity of carbon, nitrogen, and oxygen, as well as for the elements in group 7. Due on Friday, January 17 at 11:59 p.m.: Problems 1.391.91, pages 49-53. Scan and upload your work and email the document using the Blackboard email system. In the subject line write: Module 1 assignment. Module 2: Prior to coming to class, watch the video entitled: “Acids and Bases.” The link is provided in Blackboard under Module 2. Complete interactive practice at http://www.biology.arizona.edu/biochemistry/problem_sets/ph/01q.html Due on Friday, January 24 at 11:59 p.m.: Problems 2.34-2.71, pages 75-79. Scan and upload your work and email the document using the Blackboard email system. In the subject line write: Module 2 assignment. Module 3: Prior to coming to class, watch the video entitled: “Organic Molecules and Functional Groups.” The link is provided in Blackboard under Module 3. Download a trial version of ChemDraw and 3 Cari Robin Hart Module 8 November 3, 2013 draw the functional groups listed on pages 84-86. Copy and paste each compound into a Word document and submit via Blackboard email. Due on Friday, January 31 at 11:59 p.m.: Problems 3.19-3.49, pages 106-111. Scan and upload your work and email the document using the Blackboard email system. In the subject line write: Module 3 assignment. Module 4: Prior to coming to class, watch the video entitled: “Alkanes.” The link is provided in Blackboard under Module 4. Complete interactive practice at http://www.stolaf.edu/depts/chemistry/courses/toolkits/247/js/names/dnames.htm Due on Friday, February 7 at 11:59 p.m.: Problems 4.36-4.79, pages 53-158. Scan and upload your work and email the document using the Blackboard email system. In the subject line write: Module 4 assignment. Module 5: Prior to coming to class, watch the video entitled: “Stereochemistry.” The link is provided in Blackboard under Module 5. Complete interactive practice at http://www2.chemistry.msu.edu/faculty/reusch/VirtTxtJml/sterisom.htm#isom4 Due on Friday, February 14 at 11:59 p.m.: Problems 5.35-5.71, pages 190-195. Scan and upload your work and email the document using the Blackboard email system. In the subject line write: Module 4 assignment. Module 6: Review for finale by taking the practice exam available by link in the Blackboard under Module 6. Class discussion will be focused on questions by the students. If you would like to submit your question prior to class, please email it to me via the Blackboard email. Midterm and Final The midterm will be open and available on Monday, January 27 on Blackboard and will close on Friday, January 31. You may use your textbook and other sources, but you may not ask others for any answers on the midterm. The final will be on Monday, February 24 on Blackboard. It will be available from 5:00 p.m. to 10:00 p.m. You may use your textbook and other sources, but you may not ask others for any answers on the final. Assessment Final Exam 40% The exam will be a 40 question multiple choice test. Midterm 10% The midterm will be a ten question short answer exam. Assignments 40% The assignments will usually require a short answer or a drawing. Discussion 10% Use the posts of other to help you synthesis the information. If you do not engage with other students, you will only get half credit. Only one reply to another idea is required. You may ask the other student to clarify or defend their position. If other students persuade you that your original post was incorrect, you may change your answer and cite their argument as your reason. 4 Cari Robin Hart Module 8 November 3, 2013 5. Please provide a half-page description for each weekly set of instructional activities you will include in your course syllabus. Be sure to include a variety of technology components that use synchronous and asynchronous methods of communication. Module 1: Prior to coming to class, watch the video entitled: “Structure and Bonding.” The link is provided in Blackboard under Module 1. Use the dynamic periodic table, found at http://www.ptable.com/ to explore the orbitals of the following elements: hydrogen, carbon, nitrogen, and oxygen. Also, use the dynamic periodic table to explore the electronegativity of carbon, nitrogen, and oxygen, as well as for the elements in group 7. Due on Friday, January 17 at 11:59 p.m.: Problems 1.391.91, pages 49-53. Scan and upload your work and email the document using the Blackboard email system. In the subject line write: Module 1 assignment. Asynchronous activities include students watching the class lecture and practicing using the interactive dynamic periodic table. Students will also complete questions independently and asynchronously. Students will communicate asynchronously with each other on the discussion board on Blackboard. Synchronous activities will occur during the scheduled class time on Monday nights. The instructor will use an interactive whiteboard and live discussion with question and answer time. Students will pose questions as well as be called upon to answer questions verbally and as well as by drawing on the interactive whiteboard. Module 2: Prior to coming to class, watch the video entitled: “Acids and Bases.” The link is provided in Blackboard under Module 2. Complete interactive practice at http://www.biology.arizona.edu/biochemistry/problem_sets/ph/01q.html 5 Cari Robin Hart Module 8 November 3, 2013 Due on Friday, January 24 at 11:59 p.m.: Problems 2.34-2.71, pages 75-79. Scan and upload your work and email the document using the Blackboard email system. In the subject line write: Module 2 assignment. Asynchronous activities include students watching the class lecture and practicing using the interactive link listed above. Students will also complete questions independently and asynchronously. Students will communicate asynchronously with each other on the discussion board on Blackboard. Synchronous activities will occur during the scheduled class time on Monday nights. The instructor will use an interactive whiteboard and live discussion with question and answer time. Students will pose questions as well as be called upon to answer questions verbally and as well as by drawing on the interactive whiteboard. Module 3: Prior to coming to class, watch the video entitled: “Organic Molecules and Functional Groups.” The link is provided in Blackboard under Module 3. Download a trial version of Chem Draw and draw the functional groups listed on pages 84-86. Copy and paste each compound into a Word document and submit via Blackboard email. Due on Friday, January 31 at 11:59 p.m.: Problems 3.19-3.49, pages 106-111. Scan and upload your work and email the document using the Blackboard email system. In the subject line write: Module 3 assignment. Asynchronous activities include students watching the class lecture and practicing using the Chem Draw. Students will also complete questions independently and asynchronously. Students will communicate asynchronously with each other on the discussion board on Blackboard. Synchronous activities will occur during the scheduled class time on Monday nights. The instructor will use an interactive whiteboard and live discussion with question and answer time. Students will pose questions as well as be called upon to answer questions verbally and as well as by drawing on the interactive whiteboard. Module 4: Prior to coming to class, watch the video entitled: “Alkanes.” The link is provided in Blackboard under Module 4. Complete interactive practice at http://www.stolaf.edu/depts/chemistry/courses/toolkits/247/js/names/dnames.htm 6 Cari Robin Hart Module 8 November 3, 2013 Due on Friday, February 7 at 11:59 p.m.: Problems 4.36-4.79, pages 53-158. Scan and upload your work and email the document using the Blackboard email system. In the subject line write: Module 4 assignment. Asynchronous activities include students watching the class lecture and practicing using the interactive link listed above. Students will also complete questions independently and asynchronously. Students will communicate asynchronously with each other on the discussion board on Blackboard. Synchronous activities will occur during the scheduled class time on Monday nights. The instructor will use an interactive whiteboard and live discussion with question and answer time. Students will pose questions as well as be called upon to answer questions verbally and as well as by drawing on the interactive whiteboard. Module 5: Prior to coming to class, watch the video entitled: “Stereochemistry.” The link is provided in Blackboard under Module 5. Complete interactive practice at http://www2.chemistry.msu.edu/faculty/reusch/VirtTxtJml/sterisom.htm#isom4 Due on Friday, February 14 at 11:59 p.m.: Problems 5.35-5.71, pages 190-195. Scan and upload your work and email the document using the Blackboard email system. In the subject line write: Module 4 assignment. Asynchronous activities include students watching the class lecture and practicing using the interactive link listed above. Students will also complete questions independently and asynchronously. Students will communicate asynchronously with each other on the discussion board on Blackboard. Synchronous activities will occur during the scheduled class time on Monday nights. The instructor will use an interactive whiteboard and live discussion with question and answer time. Students will pose questions as well as be called upon to answer questions verbally and as well as by drawing on the interactive whiteboard. 7