Topic 4.1 The Mole and Stoichiometry 602,000,000,000,000,000,000,000 • Individual atoms and molecules are too small to see and count individually. We keep track of individual particles by a counting unit called the “Mole”. 602,000,000,000,000,000,000,000 1 mole =602,000,000,000,000,000,000,000 1mole = 6.02 x 1023 1 Dozen = 12 1 deca = 10 1 ream = 500 1 score = 1 mole = 6.02 x 1023 particles 2 moles = 2(6.02 x 1023) particles = 1.2 x 1024 particles 7 moles = 7(6.02 x 1023) particles = 4.2 x 1024 particles 0.5 moles = 0.5(6.02 x 1023) particles = 3.01 x 1023 particles 0.025 moles = 0.025(6.02 x 1023) particles = 1.5 x 1022 particles Ex: How many atoms are in 0.0001 moles of gold? • 1 mole = 6.02 x 1023 particles • multiply both sides by 0.0001: • 0.0001(1 mole) = 0.0001(6.02 x 1023 atoms) • 0.0001moles = 0.000602 x 1023 atoms • = 6.02 x 1019 atoms Molar Mass • Number of grams in 1 mole (refer to PTOE) • Equal to the numerical value of the atomic mass 1 mole of C atoms = 12.0 g 1 mole of Mg atoms = 24.3 g 1 mole of Cu atoms = 63.5 g 6 Learning Check Give the molar mass to 0.1 g A. 1 mole of Br atoms = ________ B. 1 mole of Sn atoms = ________ 7 Solution Give the molar mass to 0.1 g A. 1 mole of Br atoms = 79.9 g/mole B. 1 mole of Sn atoms = 118.7 g/mole 8 Molar Mass of Compounds Mass in grams of 1 mole equal numerically to the sum of the atomic masses 1 mole of CaCl2 = 111.1 g/mole 1 mole Ca x 40.1 g/mole + 2 moles Cl x 35.5 g/mole 1 mole of N2O4 = 74.0 g/mole 2 moles N x 14.0 g/mole + 4 moles O x 16.0 g/mole 9 Learning Check A. 1 mole of K2O = ______g B. 1 mole of antacid Al(OH)3 = ______g 10 Solution A. 1 mole of K2O = 94.2 g 2 K x 39.1 g/mole + 1 O x 16.0 g/mole B. 1 mole of antacid Al(OH)3 = 78.0 g 1 Al x 27.0 g/mole + 3 O x 16.0 g/mole + 3 x 1.0 11 Learning Check Prozac, C17H18F3NO, is a widely used antidepressant that inhibits the uptake of serotonin by the brain. It has a molar mass of 1) 40.0 g/mole 2) 262 g/mole 3) 309 g/mole 12 Molar Mass Factors Methane CH4 known as natural gas is used in gas cook tops and gas heaters. Express the molar mass of methane in the form of conversion factors. Molar mass of CH4 = 16.0 g 16.0 g CH4 1 mole CH4 and 1 mole CH4 16.0 g CH4 13 Calculations with Molar Mass molar mass Grams Moles 14 Moles and Grams Aluminum is often used for the structure of light-weight bicycle frames. How many grams of Al are in 3.00 moles of Al? 3.00 moles Al ? g Al 15 1. Molar mass of Al 1 mole Al = 27.0 g Al 2. Conversion factors for Al 27.0g Al 1 mol Al 3. Setup or 1 mol Al 27.0 g Al 3.00 moles Al x Answer 27.0 g Al 1 mole Al = 81.0 g Al 16