Chapter 7: Chemical Compounds Putting Atoms Together Most things are made up of individual atoms. Atoms can be chemically joined together with other atoms to form small units called molecules. Atoms combine to become more stable. The most stable elements on the periodic table are the noble gases (group #18). They are considered to be the most stable because they have the maximum number of electrons in their outermost (valence) shell – Helium has 2 electrons in its valence shell, and all other noble gases have 8 electrons in their valence shell. Elements that do not have the maximum number of electrons in their valence shell combine with other elements to obtain this maximum number of electrons. Atoms become stable by gaining, losing, or sharing electrons. Molecules are two or more atoms of the same or different elements that are chemically joined together in a unit. For example) Air is composed of many kinds of molecules: 80% nitrogen molecules, 20% oxygen molecules, and small amounts of water and carbon dioxide molecules. A chemical formula is a notation that indicates the type and number of atoms in a pure substance. For example) Nitrogen gas is written as N2 – the subscript “2” indicates that there are two nitrogen atoms joined together to create the molecule of nitrogen gas. Molecular Elements A molecular element is a molecule consisting of atoms of the same element. There are 7 elements that form molecules that consist of two atoms. These molecular elements are commonly called diatomic molecules (the prefix “di” indicates two). The 7 diatomic molecules are: H2, N2, O2, F2, Cl2, Br2, and I2. A non-sensical word to remember the diatomic molecules is: HOF BrINCl (it rhymes with Bullwinkle). Molecular Compounds (Non-metal + Non-metal) A molecular compound is a molecule that consists of two or more different elements. Molecular compounds are formed between two non-metal elements. For example) H2O is water. It is made up of two hydrogen atoms and one oxygen atom. For example) CH4 is methane. It is made up of one carbon atom and four hydrogen atoms. For example) C12H22O11 is table sugar. It is made up of 12 carbon atoms, 22 hydrogen atoms, and 11 oxygen atoms. Molecular compounds are created when a covalent bond forms between two or more non-metals. A covalent The combining capacities (the number of covalent bonds the element will form) for the non-metal bond is a bond formed when non-metals share their valence electrons. elements are: 1 2 3 4 F Cl Br I O S Se N P As C Si Practice Problems for Creating Molecular Compounds: a) Nitrogen gas N2 d) Ammonia NH3 b) Oxygen gas O2 e) Methane CH4 c) Water H2 O f) Carbon dioxide CO2 Alloys (Metals and Metals) Metals form mixtures with other metals. These mixtures are called alloys. Alloys are created by melting two or more metals and then mixing these hot liquids. After mixing, the alloy is allowed to solidify. Alloys are different from compounds because in compounds, atoms join together chemically in a specific ratio to form pure substances. Alloys are solutions of metals. The metals do not combine chemically. For example) Sterling silver is a solution of 92.5% silver and 7.5% copper. Ionic Compounds (Metals + Non-metals) Some compounds are made up of charged particles called ions. An ion is a particle that has either a positive or a negative charge. Ions form when an atom loses or gains one or more electrons without changing its number of protons. A Cation is a positively charged ion. A cation is always a metal. Metals always have 1, 2, or 3 electrons in their valence shell. Remember that a full shell has 8 electrons. It is easier (takes less energy) to lose 1, 2, or 3 electrons and have a full inner shell than it is to find another 5, 6, or 7 more electrons in order to fill its original valence shell. Since the metal element lost its valence electrons to become stable, it will now have more protons than it does electrons. And, since protons are positively charged, the metal will be a positively charged ion. For example) Calcium is in group #2 which means that it has 2 electrons in its valence shell. Calcium has 20 protons and 20 electrons. It is easier for calcium to lose these 2 electrons and have a full inner shell than it is to find 6 more electrons to fill its valence shell. If calcium loses its 2 valence electrons, it will now have 18 electrons, while still having 20 protons. Since protons are positively charged and electrons are negatively charged, calcium will now have a +2 overall charge (+20 and -18 = +2) An Anion is a negatively charged ion. An anion is always a non-metal. Non-metals always have 5, 6, or 7 electrons in their valence shell. Remember that a full shell has 8 electrons. It is easier (takes less energy) to gain 1, 2, or 3 electrons and fill that valence shell than it is to lose all 5, 6, or 7 electrons in order to have a full inner shell. Since the non-metal element gains more electrons to its valence shell to become stable, it will now have more electrons than it does protons. And, since electrons are negatively charged, the non-metal will be a negatively charged ion. For example) Fluorine is in group #17 which means that it has 7 electrons in its valence shell. Fluorine has 9 protons and 9 electrons. It is easier for fluorine to gain 1 other electron and have a full valence shell than it is to lose all 7 valence electrons in order to have a full inner shell. If fluorine gains another electron, it will now have 10 electrons, while still having 9 protons. Since protons are positively charged and electrons are negatively charged, chlorine will now have a -1 overall charge (+9 and -10 = -1) An Ionic Compound is a compound that consists of positively and negatively charged ions. Remember that metals lose electrons and become cations (positively charged ion) while nonmetals gain electrons and become anions (negatively charged ion). Cations and anions attract each other because they have opposite charges. An ionic compound is formed when a positively charged metal gives a negatively charged non-metal its valence electrons. An ionic bond is formed by the giving and taking of valence electrons between a metal and a non-metal. How to Write and Create Ionic Compounds Always write the chemical symbol of the metal first, then the non-metal. Write the metal’s charge number above its symbol; do the same for the non-metal. “Criss-cross” the charge numbers to create the subscripts of the ionic compound. The charge number of the metal will become the subscript of the non-metal and visa versa. Do not write a subscript of “1”. If necessary, reduce any subscripts. For example) Mg2O2 can be reduced to MgO When naming an ionic compound, write the name of the metal first. Then, write the name of the non-metal with its ending changed to “-ide”. For example) Magnesium oxide. Practice Problems for Ionic Compounds…… 1) Combine the following elements to create an ionic compound: Provide the name and formula. a) Potassium and Oxygen b) Aluminum and Nitrogen c) Beryllium and Chlorine 2) Provide the name of the ionic compounds. a) Li2S b) NaF c) Mg3P2 3) Provide the chemical formula for the ionic compounds. a) Calcium nitride b) Aluminum oxide c) Potassium fluoride