REVIEW – Ch. 8 Chemical Reactions 1. What are the indicators of a chemical change? • 1. gas produced • 2. precipitate formed • 3. changes color • 4. evolution of heat and light • 5. gets colder 2. State the Law of Conservation of Mass. How does it apply to a chemical equation? What else is balanced as a result? • Mass is neither created nor destroyed in a chemical reaction. • Mass of products = mass of reactants • Number of atoms 3. Identify the symbols that compose a chemical equation. – – – – – – – – (s) (aq) + (g) (l) Pt - solid - aqueous, dissolves in water - plus, and - produces, forms, yields – gas – liquid – Platinum (Pt) used as a catalyst – reactants must be heated 4. What is the difference between a coefficient and a subscript? 3CO2 Coefficient – means 3 molecules of carbon dioxide Subscript – means 2 oxygen atoms 5. List the 7 diatomic molecules. • Remember 7+1 on the periodic table • • • • • • • H2 N2 O2 F2 Cl2 Br2 I2 6. Define the following types of reactions: – Synthesis – two or more substances combine to form a new compound – Decomposition – a single compound undergoes a reaction that produces two or more simpler substances – Single Replacement – one element replaces a similar element in a compound – Double Replacement – the ions of 2 compounds exchange places in an aqueous solution to form two new compounds – Combustion – a substances combines with oxygen, releasing a large amount of energy in the form of heat and light 7. Balance the equations and identify them by their type of reaction: Single Replacement A. __2__ Li + __2__ HCl __2__ LiCl + ___1__ H2 Double Replacement B. __1__ NiSO4 + _2__ NaI __1__ NiI2 + __1__ Na2SO4 Synthesis C. __2__ H2 + __1__ O2 __2__ H2O Single Replacement D. __2__ Al + __1__ Fe2O3 __2_ Fe + __1__ Al2O3 Decomposition Double Replacement E. __2__ Al2O3 __4__ Al + __3__ O2 F. __1__ CaH2 + __2__ HNO3 __2__ H2 + __1__ Ca(NO3)2 Combustion G. __1__ C4H8 + __6__ O2 __4__ H2O + __4__ CO2 Synthesis H. ___1__ P4 + __5___ O2 __2__ P2O5 8. Define Activity Series. What does it predict? – A list of elements organized according to the ease with which the elements undergo certain chemical reactions – Used to predict whether a single replacement reaction will occur 9. What is the difference between an element in the Activity Series at the top and one at the bottom? • Most reactive metal at the top, it will replace any element below it. • Least reactive element at the bottom, it will not replace any element above it. 10. Predict what happens according to the Activity Series: • A. Fe + CuSO4→ FeSO4 + Cu • B. Ni + NaCl → No Reaction • C. Li + ZnCO3→ Li2CO3 + Zn • D. Al + CuCl2→ AlCl3 + Cu 11. Exothermic or Endothermic? – Reaction feels hot - Exothermic / Endothermic – Reaction feels cold - Exothermic / Endothermic – Breaking bonds – Exothermic / Endothermic – Making bonds – Exothermic / Endothermic 12. Find the molar masses of the following compounds: 103 g/mol 1) NaBr 2) PbSO4 303 g/mol 3) Ca(OH)2 74 g/mol 4) Na3PO4 164 g/mol 13. Convert each of the following from grams to moles: 1. 15.0 g C2H6 15.0 gC 2 H 6 1molC 2 H 6 0.50molC2 H 6 1 30 gC2 H 6 140.0 gNaOH 1molNaOH 3.50molNaOH 2. 140.0 g NaOH 1 40 gNaOH 3. 27.2 g H2O 4. 45.7 g CaCO3 27.2 gH 2O 1molH 2O 1.51molH 2O 1 18 gH 2O 45.7 gCaCO3 1molCaCO3 0.46molCaCO3 1 100 gCaCO3 14. Convert moles to grams in each of the following: 1. 1.5 moles NH3 1.50molNH 3 17 gNH 3 1 1molNH 3 25.5 gNH 3 2. 0.65 moles H2SO4 0.65molH 2 SO4 94 gH 2 SO4 61gH2 SO4 1molH 2 SO4 1 15. Convert the following to moles: 1. 3.01 x 1023 atoms Na 1molNa 3.01x10 23 atomsNa 0.50molNa 23 6.02 x10 atomsNa 1 2. 2.41 x 1024 molecules CO2 1molCO2 2.41x1024 moleculesC O2 4.0molCO2 23 6.02 x10 moleculesC O2 1 16. Find the percent compositions of all of the elements in the following compounds: 1) CuBr2 2) NaOH 3) (NH4)2S 63.5 gCu 100 28.4%Cu 223.3gCuBr2 159.8 gBr 100 71.6% Br 223.3gCuBr2 23gNa 100 57.5% Na 40 gNaOH 16 gO 100 40.0%O 40 gNaOH 1gH 100 2.5% H 40 gNaOH 28 gN 100 41.1% N 68.1g ( NH 4 ) 2 S 8 gH 100 11.7% H 68.1g ( NH 4 ) 2 S 32 gS 100 47.0% S 68.1g ( NH 4 ) 2 S 17. Find the empirical formula for a compound which contains 32.8% chromium and 67.2% chlorine. 32.8 gCr 1molCr 0.63molCr / 0.63molCr 1 1 52 gCr 67.2 gCl 1molCl 1.89molCl / 0.63molCr 3 1 35.5 gCl EmpiricalF ormula CrCl3 18. The percentage composition of acetic acid is found to be 39.9% C, 6.7% H, and 53.4% O. Determine the empirical formula of acetic acid. 39.9 gC 1molC 1 12 gC 3.3molC 6.7 gH 1molH 1 1gH 53.4 gO 1molO 1 16 gO 6.7molH / 3.3molC 2 / 3.3molC 1 3.3molO / 3.3molC 1 EmpiricalF ormula CH2O 19. The molar mass for the question above (#18) was determined by experiment to be 60.0 g/mol. What is the molecular formula? EmpiricalF ormula CH2O MolarMassC H 2O 30g / mol MolarMassE xperimental 60 g / mol 2 MolarMassE mpiricalFo rmula 30 g / mol 2 CH2O C2 H 4O2 MolecularF ormula C2 H 4O2