Chemistry I Mid-Term Review and Study Guide The following guide is intended to be a study aid for the upcoming mid-term exam in Chemistry. If you work to know the topic areas listed below you will be well prepared for this test. The majority of the exam will cover the topics listed below, although all information we went over in class may potentially be on the test. I advise that you structure your study time to focus on the points in this outline, but reserve some time to review all the material we covered. Good luck with your studies! Know the definitions of: Chapters 1 & 2 -Intro/FOS/Co review Scientific Method Hypothesis Experiment Theory Law Independent Variable Dependent Variable Scientific Notation Significant Figures Accuracy Precision Certainty Unit Analysis Conversion Factor Law of Definite Proportions Chapter 12.1 - KMT Kinetic Theory of Matter Phase Diagram Melting/Freezing Vaporization/Condensation Sublimation/Deposition Pressure Barometer Vapor Pressure Page 1 of 6 Chapter 3 - Matter Substance Matter Element Compound Physical Property Extensive Property Intensive Property Chemical Property States of Matter Solid Liquid Gas Vapor Physical Change Chemical Change Law of Conservation of Mass Density Chapter 13.1 - Gas Laws Boyle’s Law Charles’s Law Gay-Lussac’s Law Combined Gas Law Chemistry I Mid-Term Review and Study Guide Know: Components of the scientific method: observation, hypothesis, experiment, conclusion. Determine precision and certainty (Percent error); I’ll give you the formula of Experimental Value - Accepted value Accepted value x 100 = % Error Apply the law of Conservation of Mass Apply the law of Definite Proportions Density is mass/volume Use the Gas Laws (Boyle, Charles, Gay-Lussac, Combined). Convert units of pressure and temperature. Apply the law of conservation of mass How to add, subtract, multiply, divide numbers and get proper number of significant figures. Dimensional analysis to solve problems. Know the Definitions of: Dalton’s Atomic Theory Nucleus Proton Neutron Electron Chapters 4 - The Atom Atomic Number Isotope Mass Number Atomic Mass Unit (amu) Atomic Mass Chapter 5 - Electrons of Atom Electromagnetic Radiation Quantum Mechanical Model of atom Atomic Orbital Wavelength (λ) Principal Quantum Number Frequency (ν) Amplitude Principal Energy Level Electromagnetic Spectrum Energy Sublevel Quantum Electron Configuration Photoelectric Effect Aufbau Principle Photon Pauli Exclusion Principle Atomic Emission Spectrum Hund’s Rule Ground State Valence Electron Electron (Lewis) Dot Structure Page 2 of 6 Chemistry I Mid-Term Review and Study Guide Know also: Dalton’s Atomic Theory Charge on a Proton, Neutron, and Electron What makes up the nucleus Rutherford’s Experiment and what that showed about the nucleus Atomic Number = Number of Protons = Number of Electrons Mass number = Number of Protons + Number of Neutrons; know how to find any one given the other two. What shorthand notation means. i.e. C-14 means Carbon has 14 protons + neutrons, Carbon (C) is element #6 so it has 6 protons. C-14 than has 8 neutrons. Know how to calculate the atomic mass of an element given the mass and the abundance of the isotopes. Energy of a EM radiation is proportional to its frequency The atomic orbitals (s, p, d, f) How to fill the atomic orbitals of a given element Number of orbitals in an energy level, n. (# orbitals = n2) Number of electrons in an energy level, n (#electrons = 2n2) Electron orbital notation. Ex. B = 1s22s22p1 Orbital Box Diagram. Example: Carbon o 1s 2s 2p ↑↓ ↑↓ ↑ ↑ How to spot violations of Aufbau, Hund’s rule, and the Pauli Exclusion Principle Know Definitions of: Chapter 6 - Periodic Trends Periodic Law Transition element/metal Group, Family, Column Metal Period Alkali Metal Representative Element Alkaline Earth Metal Inner Transition Metal Nonmetal Halogen Noble Gas Metalloid Ion Ionization Energy Octet Rule Electronegativity Metallic Character Z* (Zeff) = Z - S Page 3 of 6 Chemistry I Mid-Term Review and Study Guide Know also: The classification of an element (metal, nonmetal, metalloid) How to locate an element by period, group, and block Whether the element is a representative element or a transition element Trends of Zeff, atomic radius, ionic radius, ionization energy, metallic character and electronegativity as you move across and down the periodic table. Size relationship between a neutral atom its corresponding ion Know the definitions of: Chapter 7 – Ionic Compounds and Metals Binary compound Oxidation number Chemical Bond Polyatomic ion Cation Electron sea model Anion Delocalized electrons Ionic bond Metallic bond Lattice Energy Alloy Formula unit Interstitial alloy Monoatomic Ion Substitutional alloy Multivalent Metal Hydrate Know how to: Make a compound neutral when you have positive and negative ions. Show that column (group) of the element effects its oxidation number. Explain that lattice energy is affected by ion size and charge Read the ion chart to identify elemental ions like oxide (O2-) and polyatomic ions like carbonate (CO32-) Write out a formula from the name of the compound (Ex. potassium nitrate is KNO3), and what to do when you have a transition element (Ex. Cobalt(II) chloride is CoCl2) and a hydrated compound (Ex. Barium iodide dihydrate is BaI2•2H2O). Write out a name when you have a formula. Ex. PbSO4 is lead(II) sulfate. Same ideas as previous bullet point, just in reverse. Metallic bonding is the metal ions in a “sea of electrons” Note: You do NOT have to know the nomenclature rules for the oxyanions Page 4 of 6 Chemistry I Mid-Term Review and Study Guide Chapter 8 – Covalent Bonding Covalent Bond Bond dissociation energy Molecule Lone pair electrons Lewis structure Allotrope Sigma (σ) bond VSEPR Theory Pi (π) bond Tetrahedral shape Endothermic Linear Exothermic Trigonal planar Structural formula Trigonal bipyramidal Polar covalent bond Octahedral Electronegativity Pyramidal 2 3 Hybridization (sp, sp , sp ) Bent Know how to: Name a molecular compound. (Ex. N2O5 is dinitrogen pentoxide) Write out a formula for a covalent compound if given the name. Identify simple common acids or bases (H3PO4 is phosphoric acid, HCl is hydrochloric acid, etc.) Distinguish between an ionic compound and a covalent molecule. Draw Lewis structures of simple compounds and ions, be able to label bonding electrons and lone pair electrons Determine type of bond between the two elements based on their electronegativity difference Qualitatively determine how number of bonds and bond length affects bond strength (i.e. double bonds are shorter and take more energy to break them than single bonds) Shapes of simple molecules: Linear, trigonal, tetrahedral, etc. Relate shape of molecule to hybridization (Google Classroom assignment) Page 5 of 6 Chemistry I Mid-Term Review and Study Guide Remember for the mid-term, I will give you a booklet of: a periodic table a table of electronegativities a table of conversion factors an electromagnetic spectrum a list of equations and constants (Including the gas laws) maximum number of electrons an orbital holds (s=2; p=6; d=10; f=14), block and dot structure periodic tables a list of ions with their respective charges a list of the hydrate/covalent compound prefixes a list of some common transition metals It is your responsibility to know how to use them. 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