Phases of Matter and Phase Changes Unit 7 Chapter 13 Phases of Matter Liquids and Solids Molecular Level Comparison of Gases, Liquids and Solids. Liquid Properties •Molecular Motion -Kinetic-molecular theory predicts the constant motion of the liquid particles •Individual liquid molecules do not have fixed positions in the liquid. •Volume - Forces of attraction between liquid particles limit their range of motion so that the particles remain closely packed in a fixed volume. •Shape - Liquids can take the shape of their container Properties of Liquids Density - Like gases, liquids can be compressed. But the change in volume for liquids is much smaller because liquid particles are already tightly packed together. •Diffusion - A liquid diffuses (mix) more slowly than a gas at the same temperature, however, because intermolecular attractions interfere with the flow. Properties of Solids •Exist in ordered patterns Most solids have a crystalline shape repeated over and over Exception: Glass (considered an amorphous solid, which means that the molecules are in stuck in random positions •Molecular Motion - Particles are in fixed positions so they just vibrate in place. •Diffusion - Cannot diffuse (cannot mix spontaneously with other solids) More Solid Properties •Density - The particles in a solid are more closely packed than those in a liquid. Solids are usually the most dense of the three states Exception: Water •Cannot be compressed – therefore they have fixed volumes. Changes In State Solid Freezing Sublimation Deposition Melting Vaporization Liquid Condensation Gas Exothermic vs. Endothermic Exothermic Change – Heat Energy is released to the surroundings. Molecules slow down, extra energy is transferred to surrounding. Cooling phase changes are exothermic •Endothermic Change – Heat energy is absorbed by the system -Molecules move faster as they absorb energy -Phase changes that require energy (or heat) are endothermic Temperature oC Heating & Cooling Curve For a Pure Substance Boiling/condensation Temperature Liquid and gas Melting Solid & Liquid Solid heating Melting/Freezing Temperature Vaporization Energy Added Liquid heats Gas heats Another graphic