14/15 Academic Year Energy (TKK-2129) Instructor: Rama Oktavian Email: rama.oktavian86@gmail.com Office Hr.: M - F.13-15, oktavianrama.lecture.ub.ac.id Outlines 1. Natural gas: Intro and sources 2. Natural gas: Properties 3. Natural gas: Exploration 4. Natural gas processing (overview) Natural gas: Intro What is Natural Gas? • Gas obtained from natural underground reservoir • Contains mostly methane (CH4) • Usually contains some impurities such as H2S and CO2 • As one of primary energy sources in Indonesia Natural gas: Intro What is Natural Gas? Natural gas: Intro What is Natural Gas? http://www.naturalgas.com.au/about/references.html Natural gas: Intro Pollution comparison http://www.propane.ca/en/about-propane/environmental-benefits Natural gas: Intro Natural gas reserves Natural gas: Intro Natural gas production http://www.eia.gov/todayinenergy/detail.cfm?id=4790 Natural gas: Intro Natural gas production http://www.eia.gov/todayinenergy/detail.cfm?id=5810 Natural gas: Intro Natural gas reserves in Indonesia Natural gas: Intro Natural gas reserves in Indonesia Natural gas: Intro Natural gas: Intro http://www.eia.gov/countries/cab.cfm?fips=id Natural gas: Intro Natural gas industry in Indonesia The largest of these are found in: 1. Arun, Aceh (Sumatra) 2. Bontang (East Kalimantan) 3. Tangguh (Papua) 4. Natuna Island Natural gas: Intro PT. ARUN ARUN KAPASITAS : 12,85 MMTPA PT. MARUTA BUMI PRIMA PT. BADAK LANGKAT CHEVRON BONTANG KAPASITAS : 17 MTPA TJ. SANTAN KAPASITAS LNG: 21,64 MMTPA KAPASITAS : 90 MMTPA KAPASITAS LPG: 1 MMTPA PT. PERTAMINA (PERSERO) UP I PANGKALAN BRANDAN KAPASITAS : 44 MTPA CONOCO PHILLIPS BELANAK PT. PERTAMINA (PERSERO) KAPASITAS : 525 MTPA UP V BALIKPAPAN PETROCHINA KAPASITAS : 91 MTPA PT. PERTAMINA (PERSERO) ARAR UP II DUMAI PETROCHINA KAPASITAS : 14 MTPA KAPASITAS : 68 MTPA TJ. JABUNG PT. PERTAMINA (PERSERO) KAPASITAS : 600 MTPA UP III MUSI PT. MEDCO LPG KAJI KAPASITAS : 131 MTPA KAJI KAPASITAS : 73 MTPA PT. E1 PERTAGAS PT. SURYA ESA PERKASA HESS LEMBAK UJUNG PANGKAH, JATIM KAPASITAS : 46 MTPA SUNGAI GERONG KAPASITAS 259 MTPA PT. TITS SAMPURNA PRABUMULIH KAPASITAS : 113 MTPA PT. MEDIA KARYA SENTOSA BP GRESIK, JATIM TANGGUH KAPASITAS : 58 MTPA KAPASITAS : 7,6 MMTPA PT. TUBAN LPG INDONESIA KAPASITAS : 73 MTPA TUBAN KAPASITAS : 131 MTPA PT. PERTAMINA (PERSERO) UP VI BALONGAN DAN MUNDU PT. GASUMA FEDERAL INDONESIA KAPASITAS : 584 MTPA TUBAN KAPASITAS : 22 MTPA PT. SUMBER DAYA KELOLA TUGU BARAT PT. WAHANA INSANNUGRAHA KAPASITAS : 7 MTPA PT. PERTAMINA (PERSERO)* TAMBUN PT. YUDISTIRA ENERGY KAPASITAS : 55 MTPA PONDOK TENGAH KAPASITAS 50 MTPA * Hak Pengelolaan Sementara CEMARA, JABAR KILANG LNG (42,09 MMTPA) KAPASITAS : 37 MTPA KILANG LPG (4,12 MMTPA) PT. YUDHISTIRA HAKA P. PT. PERTAMINA (PERSERO) CILAMAYA, JABAR UP IV CILACAP KAPASITAS : 44 MTPA KAPASITAS : 318 MTPA RENCANA PEMBANGUNAN Natural gas: Intro Natural gas based on its source 1. Conventional natural gas is usually obtained from Deep reservoir 2. Natural gas usually presents in crude oil (Associated gas) 3. Natural gas in reservoirs that contain little or no crude oil (Non-associated gas) 4. Associated gas is produced with the oil and separated at the casinghead or wellhead 5. Non-associated gas is sometimes referred to as gas-wellgas or dry gas Natural gas: Intro Natural gas based on its source Natural gas: Intro Natural gas compositions Natural gas: Intro Natural gas compositions Natural gas: Intro Natural gas product specification 1. The composition of natural gas varies considerably from location to location 2. Natural gas product specification includes: - Wobbe number, - heating value, - total inerts, - water, - oxygen, - and sulfur content. The first two criteria relate to combustion characteristics. The latter three provide protection from pipeline plugging and corrosion Natural gas: Intro Natural gas properties Colorless, odorless, tasteless, shapeless, and lighter than air Natural gas: Intro Natural gas properties Specific gravity For gas mixtures: Compressibility factor Z can be function of Pr and Tr Natural gas: Intro Natural gas properties Compressibility factor can be function of Pr and Tr Natural gas: Intro Compressibility factor can be function of Pr and Tr Natural gas: Intro Natural gas product specification Natural gas: Intro Liquid product specification 1. As with gases, specifications for liquid products are based upon both composition and performance criteria 2. the performance specifications include Reid vapor pressure, water, oxygen, H2S, and total sulfur content 3. Safety considerations make vapor pressure especially important for the liquid products because of regulations for shipping and storage containers Natural gas: Intro Liquid product specification Natural gas: Properties Combustion characteristics 1. Pipeline gas is normally bought and sold (custody transfer) on the basis of its heating value, ex: MMBtu/cuft 2. Heating value: the amount of heat released during the combustion of a specified amount of it 3. the heating value of a fuel involves two arbitrary but con-ventional standard states for the water formed in the reaction: - All the water formed is a liquid (gross heating value, frequently called higher heating value [HHV]) – including latent heat of vaporization - All the water formed is a gas (net heating value, frequently called lower heating value [LHV]) - the heating value is normally calculated at 60°F and 1 atm (15.6°C and 1.01 atm), standard conditions for the gas industry Natural gas: Properties Wobbe Number 1. defined as the gross heating value (Btu/scf) of the gas divided by the square root of the specific gravity (the ratio of the density of the gas divided by the density of air Natural gas: Exploration Photo courtesy of OSHA Natural gas: Exploration Petroleum System Elements Gas Cap Oil Entrapment Water Seal Rock Reservoir Rock Migration 120° F Generation 350° F 24803 Reprint permitted by the American Association of Petroleum Geologists Natural gas: Exploration Reprint permitted by the American Association of Petroleum Geologists Natural gas: Exploration Reprint permitted by the American Association of Petroleum Geologists Christmas Tree Pipeline to Flow Process and Storage Surface Casing Cement Intermediate Casing Cement Production Casing Tubing Completion Fluid Packer Well Fluids Cement Oil or Gas Zone Perforations Natural gas processing Natural gas processing Natural gas processing LNG Processing (CO2 removal) CO2 concentration in natural gas is high It will freeze below -160 C, it will block the flow The most commonly method is absorption Widely used absorbents : K2CO3 aqueous solutions 2. MEA,DEA,TEA aqueous solutions Recent update? 1. Natural gas processing LNG Processing (H2O removal) The presence of H2O can affect the LNG quality (combustion properties) It will freeze below -160 C, it will change its state to solid and form gas hydrate, thus it will block the flow The most commonly method is absorption and adsorption Widely used absorbents : ethylene glycol Widely used adsorbents : silica gel, molecular sieve Natural gas processing Fractionation 1. Methane separation (C1) - Using SCRUB COLUMN (De-Methanizer). - To produce C1 as feed for LNG processing. 2. Ethane separation (C2) - Using DE-ETHANIZER column - To produce C2 as MAKE-UP MCR REFRIGERANT 3. Propane separation(C3) - Using DE-PROPANIZER column - To produce propane as MAKE UP PROPANE REFRIGERANT and LPG. 4. Butane separation(C4) - Using DE-BUTANIZER column - To produce butane as LPG. Natural gas processing Liquefaction Using refrigeration process Operating temperature -1600C Refrijeran : ammonia (-140C), freon (-500C) refrigerant) C3, MCR (multi componen Natural gas processing Refrigeration concept Qc 3 2 2 Comp Condenser 3 JT-valve Qr 1 4 1 4 Evaporator Natural gas transportation Pipeline Transmission System Natural gas transportation Floating LNG ConocoPhillips_Cascade_LNG_Project1.jpg Natural gas transportation FSRU Natural gas uses Ammonia processing Natural gas uses Methanol processing