LAB #5 Key Points • • • • • • Types of compounds Types of bonds Writing formulas Solute Vs. Solvent Conductivity Ionic and Net Ionic Equations Ionic Compounds • Contain ionic bonds • taking of electrons. • Components have a large difference in electronegativity. • How can we get this? • Must contain a metal and a non-metal to obtain the large difference in electronegativity. • The bond has a positive side and a negative side. • Metals loose electrons and non metals gains electrons. • Example : Na+1+ Cl-1→ NaCl Molecular Compounds • Contain covalent bonds – • sharing of electrons small or no difference in electronegativity • Components have a • Usually two non-metals; two types of bonding: • (non-polar) • (polar covalent) Molecular Compounds with Non-Polar Bonds • No difference in electronegativity (diatomic elements) • Br2 Br–Br • Since both atoms are the same they have the same pull on the electron. Molecular Compounds with Polar Covalent Bonds • when the atoms are not the same: • CO2 • slight difference in electronegativity • The atom with the greater electronegativity will have a slight -side • The atom with the smaller electronegativity will have a + side. Ionic Compound Metal & Non-metal Molecular Compounds (2 types) Both 2 non-metals Mg2++2Cl-1→ MgCl2 Br–Br ( non-polar) Diatomic elements H2O (Polar covalent) +H H+ O-1 Remember + and – are not charges like ions, they are slightly positive and slightly negative sides of the compounds. Things to Remember: MgCl 2 Subscripts: tell how many atoms are present 1 Cl Superscripts: tell the charge Formula Writing: • (1) Write the names of the atoms Sodium Chloride • (2) Write the ions that they form: Na+1 + Cl-1 • (3) Finally how they combine Na1Cl1 • This gives us a set ratio Examples: • (1) Magnesium Chloride • (2) Mg 2+ + Cl1• (3) Mg1Cl2 • (1)Calcium Hydroxide • (2) Ca 2+ + OH1• (3) Ca1(OH)2 Ratio MgCl 2 •Tells us how many of each atom are present •Once the ratio is set it can’t be changed •Think of this ratio like a cookie recipe •I can change how much is present by multiplying The ratio like doubling a cookie recipe. How many atoms are present? MgCl 2 2MgCl 2 Mg = 1 Cl = 2 Mg = 2 Cl = 4 Ionic and Net Ionic Equations: • Ionic: simply tell us what ions are present in the equation. • Ionic: only has ions • Net: tells us which ions combine to form a solid. Example: Not in Lab Book Equation in words Copper II Chloride + Magnesium Hydroxide yields Magnesium Chloride + Copper (II) Hydroxide Ionic Equation Cu 2++2Cl1- + Mg Note: 2(OH) -1 2++ 2(OH)1- → Mg = (OH) -1 + (OH) -1 2++ 2Cl1 + Cu2+ 2(OH) 1- Net Ionic Equation example: Cu 2++2Cl1- +Mg 2++ 2(OH)1-→ Mg 2++ Ions 2Cl1- + Cu(OH)2 Solid • Cu 2++ 2(OH) 1- → + Cu(OH)2 • Both Cu and OH are ions on the left, and they form Cu(OH)2 solid on the right. • MgCl2 is soluble (ions stay in solution) • They are ions on the left and right side of the equation. Lab # 5 • • • • Table A Complete Table using data from demo Table B We will write the formulas for the following compounds and determine if they are soluble in water or Hexane. Table C & Rest of Lab Identify what is in the specific test tubes and describe the result. We will then write ionic and net ionic equations for our reactions. Ionic Equations (1) Equation # 4 write equation # 1in ionic form Na+1+Cl -1 + Ag+1+(NO3)-1 → Na+1 +(NO3)-1 + Ag+1 + Cl -1 Equation # 5 write Equation #2 in ionic form Mg+2+2Cl -1 + 2Na+1 + (CO3) -2 → Mg+2+(CO3)-2 + Na+1+Cl -1 Ionic Equations (2) 2K+1 + (SO4) -2 + Na+1 + (NO3) -1 → K+1 +(NO3) + 2Na+1 (SO4) -2 Net Ionic Equations pg 38 (1) Ionic equationMg+2+2Cl -1 + 2Na+1 + (CO3) -2→ Mg+2+(CO3)2 + Na+1+Cl -1 Net ionic equation Equation # 8 Mg+2 + (CO3) -2 → Mg(CO3) Net Ionic Equations pg 38 (2) • Ionic equation – 2K+1 + (SO4) -2 + Na+1 + (NO3) -1 → K+1 +(NO3) + 2Na+1 (SO4) -2 • Net ionic Equation• All ions stay in solution. • Use your chart for help, and remember that this chart only applies to the products. Pg 37 Equations Unbalanced #1 NaCl + Ag(NO3) → Na (NO3) + AgCl #2 MgCl2 + Na2(CO3) → Mg(CO3)+ NaCl #3 K2(SO4)+ Na(NO3) → K(NO3)+ Na2(SO4) Due Next Week • Complete lab: pgs 34-36 • Complete homework and exercises: pgs 39-40