THE MAJOR FUNCTION OF CARBOHYDRATES… Energy PRODUCTION (and STORAGE) POLYSACCHARIDES • Macromolecules • Common ones based upon glucose Branched polysaccharides • Amylose & amylopectin (starches) are synthesised in plants. • Glycogen is synthesised in animals, more highly branched than starches = more compact Unbranched polysaccharides Cellulose in plant cell walls © 2007 Paul Billiet ODWS LIPIDS Composed of CARBON HYDROGEN OXYGEN LIPIDS C, H, O • More hydrogen (more reduced) than carbohydrates. • Insoluble in water, soluble in organic solvents (alcohols, acetone, chloroform etc) © 2007 Paul Billiet ODWS COMMONLY CALLED: • FATS animal lipids • OILS plant lipids • WAXES plants and animals BASIC Unit (monomer) of lipids are: FATTY ACIDS + GLYCEROL FATTY ACIDS: CARBOXYLIC ACID + LONG HYDROCARBON CHAIN A saturated fatty acid Carboxylic acid O CH3 Hydrocarbon chain C OH An unsaturated fatty acid O CH3 C OH Saturated fatty acids Unsaturated fatty acids no double bonds one or more double bonds abundant in fats abundant in oils more reduced less reduced more energy less energy high melting point low melting point Lipid Fatty Acid chains linked to Glycerol Head Space-filling model of a fat A fatty acid 3 MAJOR CHEMICAL TYPES Sterol Fat Phospholipid THE MAJOR FUNCTION OF LIPIDS… Used by the organism as: 1. Stored Energy Source 2. Chemical messengers 3. Major part of cell membranes The Degree Of Saturation In A Fat Affects Its Physical And Nutritional Properties The Degree Of Saturation In A Fat Affects Its Physical And Nutritional Properties saturated monounsaturated polyunsaturated Sterols Are Part of Cellular Membranes and Act as Hormones Note the four ring structure common to all sterols. Sterols As Hormones Estrogen Testosterone Progesterone LIPIDS ARE HYDROPHOBIC! Hydrophilic Head Group And Hydrophobic Tails: Keys To Phospholipid Function Phospholipids have a Jekyll and Hyde personality. Phospholipids are Building Blocks of Cellular Membranes The hydrophilic head group and hydrophobic tails are the keys to phospholipid function. Phospholipids Form Biological Membranes PROTEINS Composed of CARBON HYDROGEN OXYGEN NITROGEN BASIC UNIT (monomer) of proteins are: AMINO ACIDS Proteins are Linear Chains of Linked Amino Acids Protein THE key elements of life. Forget DNA, proteins rule. PROTEIN STRUCTURE DEPENDENT UPON PROTEIN FUNCTION! Some of the Diverse Functions of Proteins Amino Acids, Peptide Bonds, Polypeptides, Protein Proteins are linear chains of 20 different building blocks called amino acids. Peptide bonds Amino acids are linked by peptide bonds – a form of covalent bond. Shape and Function of Proteins Depend on Amino Acid Sequence ENZYMES Special Proteins that help to increase the rate of chemical reactions. Aka “CATALYSTS” ENZYMES WORK BY… Lowering the ACTIVATION ENERGY (EA) of chemical reactions! WHAT IF THERE WERE NO ENZYMES IN ORGANISMS? • enzymes are usually named with the suffix -ase ex: protease lipase lactase • enzymes are specific !!!! specific enzymes for specific substrates! ENZYMES ARE… • Reusable!! LOCK AND KEY MODEL INDUCED FIT MODEL Nucleic Acids Two Types: DNA RNA DNA NUCLEIC ACIDS COMPOSED OF CARBON HYDROGEN OXYGEN NITROGEN PHOSPHORUS Basic Unit (monomer) of nucleic acids: NUCLEOTIDES Nucleotides are DNA and RNA Building Blocks NUCLEIC ACID FUNCTIONS DNA Deoxyribonucleic Acid contains genetic info. RNA Ribonucleic Acid aids in making proteins Another Function of Nucleotides…