Exothermic and Endothermic Chemical Reactions When a chemical reaction takes place, chemical bonds in the reactants are broken and new bonds are formed. Depending on the bonds involved, a reaction will either release energy to, or absorb energy from, the surroundings as heat. When a process releases energy into the surroundings it's called exothermic (from the Greek thermo meaning heat, and exo meaning outside). The most obvious effect of an exothermic chemical reaction is a rise in the temperature of the reaction mixture. However, some processes absorb heat energy from the surroundings, in which case they're called endothermic reactions (endo in Greek means within). The effect of an endothermic chemical reaction is a drop in the temperature of the reaction mixture. Both physical and chemical changes can be endothermic or exothermic. Changes of state involve a solid melting, a liquid freezing, a liquid boiling, or a gas condensing. When steam condenses, heat is released. Likewise when liquid water freezes, heat is given off. Our experience makes it easy for us to realize that to boil water or any liquid and thus convert into a gas, heat is required and the process is endothermic. It is less easy to see that when a gas condenses to a liquid, heat is given off and the process is exothermic. Like phase changes, chemical reactions can occur with the addition or release of heat. Those that require heat to occur are described as endothermic, and those that release heat as exothermic. We are probably very familiar with exothermic chemical reactions: Almost everyone has experienced the warmth of a fireplace or campfire. Burning wood provides heat through the exothermic chemical reaction of oxygen (O) with wood (C6H10O5) to produce carbon dioxide (CO), steam (H2O) and heat. The chemical reaction describing the process is C6H10O5 + 6O2 → 6CO2 + 5H2O + heat. All combustion reactions (such as burning fuel) are exothermic. The reaction between iron and moist air that creates rust is a very exothermic process and produces lots of heat, but this reaction takes place so slowly that the release of heat is undetectable. Fireworks, explosives and fuels, on the other hand, all involve very fast and extremely exothermic chemical reactions. An easy way to tell if a reaction is endothermic is if it feels cold. This doesn’t always happen, though; anytime you cook something, you are performing an endothermic reaction. This is because you have to input heat to make the chemical reaction occur. Exothermic Processes making ice cubes formation of snow in clouds condensation of rain from water vapor a candle flame rusting iron burning sugar forming a chemical bond Endothermic Processes melting ice cubes conversion of frost to water vapor evaporation of water baking bread cooking an egg producing sugar by photosynthesis breaking a chemical bond Guidelines for Graphic Notes The notes are “graphic”…meaning they MUST contain both WRITTEN information AND DRAWINGS. They will go on pg _____ of your notebook. 1. Keep your drawings simple! They need to be easy to understand, neat (not sloppy) and in color. 2. Make sure to include: Definitions for endothermic and exothermic reactions At least 3 examples of each type of reaction (great place for pictures “hint, hint”) The obvious effects of each type of reaction (in other words, how can you tell if it was an exothermic or endothermic reaction?) 3. Use color appropriately: Use red for your vocab and definitions, and black or blue ink for all other content/key facts. Sources: http://www.pbs.org/weta/roughscience/series3/ice/handwarmers.html http://antoine.frostburg.edu/chem/senese/101/thermo/faq/exothermic-endothermic-examples.shtml http://www.scientificamerican.com/article/what-is-an-exothermic-rea/