Connect the Dots Nonmetal atoms bond covalently. The bonding tendencies of nonmetal atoms are directly related to the number of valence electrons they have. Lewis Dot symbols keep track of the valence electrons of different atoms. In covalent bonds, atoms share pairs of electrons, so only unpaired valence electrons available for bonding. We can use Lewis Dot symbols and the HONC 1234 rule to construct accurate structural formulas. Website Link: Lewis Dot Puzzle Pieces – Computer Simulation http://content.bfwpub.com/webroot_pubcontent/Conte nt/BCS_5/Stacy_Living%20By%20Chemistry%201e/Lewis %20Dot%20Puzzle%20App/LDP-5release_updated/LewisDotRedirect.html Instructions: The puzzle pieces on the left represent Lewis Dot symbols. they show how many valence electrons an atom of that element has. Notice that some electrons are paired whereas others are unpaired. In the drawing below, each H atom puzzle piece has one unpaired electron; the N atom has two paired electrons and three unpaired electrons. Atoms combine to form molecules where all the electrons are paired. The puzzle pieces allow you to pair up electrons and create molecules. Practice Step 1: Click on the practice mode above at the top center of the screen. Step 2: Click and drag an “N” and three “H” puzzle pieces over to the empty area to the right. Step 3: Connect the puzzle pieces like shown above and watch the pieces change as they fit together. If they do not connect, then it is not the correct way to connect the atoms. Click on a piece, or atom, and drag it where you need it. Also use the two arrows given to help rotate the atoms. Step 4: In the top right corner, use the pull down menu to find NH3. Then click on the check molecule box to see if you are correct. If correct, use the clear button to clear the screen. Part I: Create Molecules 1. Use the puzzle pieces to construct the molecules given below. Then draw, in each box, the Lewis dot structures for each molecule, leaving off the outline of each puzzle piece (like the last picture above to the right). PH3 HOCl F2 CH3Cl 2. Use the puzzle pieces to create more molecules following the directions. For each molecule, draw the Lewis dot structure and write the molecular formula. a. Use one S and as many Hs as you need. b. Use one Si and as many Fs as you need. c. Use two O s and as many Hs as you need. Molecular formula: Molecular formula: Molecular formula: 3. Use the puzzle pieces to construct a molecule with the molecular formula C2H6. Draw its Lewis dot structure and its structural formula (show bonds between atoms as lines). Lewis dot structure: Structural formula: 4. Use the puzzle pieces to construct all 3 possible isomers of C3H8O. Draw Lewis dot structures for each isomer. Do the molecules follow the HONC 1234 rule? Isomer #1 Isomer #2 Isomer #3 5. Use the puzzle pieces to construct the following molecules. Draw both the Lewis dot structures and the structural formulas (show bonds between atoms as lines). Lewis dot structure: H2S CH4 NI3 NO2- N2 C2H2 CH3CH2CCH Structural formula: Cl2CH2 H3NBF3 CH3CH2OH