MADISON’S CURRENT WEATHER Madison Weather at Madison Weather at 1000 AM CDT WED JUN 18 2003 Updated twice an hour at :05 and :25 Sky/Weather: MOSUNNY Temperature: 79 F (26 C) Dew Point: 63 F (17 C) Relative Humidity: 57% Wind: W7 MPH Barometer: 29.89F (1012.2 mb) Current Surface Weather Map with Isobars (“iso” = equal & “bar” = weight), Fronts & Radar Isobars ATM OCN 100 Summer 2004 4 Current Surface Weather Map with Isobars (“iso” = equal & “bar” = weight), Fronts & Radar Isobars ATM OCN 100 Summer 2004 7 Clouds Current Visible Satellite Image Current Visible Satellite Image ATM OCN 100 Summer 2004 8 Current Temperatures (°F) & Isotherms (“iso” = equal +”therm” = temperature) ATM OCN 100 Summer 2004 9 Yesterday’s Surface Weather Map with Isobars (“iso” = equal & “bar” = weight), Fronts & Radar Isobars ATM OCN 100 Summer 2004 11 Current Surface Weather Map with Isobars (“iso” = equal & “bar” = weight), Fronts & Radar Isobars ATM OCN 100 Summer 2004 12 Tomorrow AM Forecast Map ATM OCN 100 Summer 2004 13 ATM OCN 100 – Summer 2004 LECTURE 2A PHYSICAL & CHEMICAL COMPOSITION of EARTH’S ATMOSPHERE A. PRACTICAL QUESTIONS – What makes Planet Earth special? – How has the atmosphere evolved? ATM OCN 100 Summer 2004 16 Earth-Rise (Apollo Mission) ATM OCN 100 Summer 2004 17 SUNRISE FROM SPACE From STS-52 (JSC-NASA) ATM OCN 100 Summer 2004 18 B. PRESENT EARTH’S ATMOSPHERE Background – Early Greek Thought The 4 Elements: Earth, Air, Water, Fire. – “Modern” Chemistry (since 18th century) Element Compound Mixture Chemical Composition – Air is a mixture – With the following gases: ATM OCN 100 Summer 2004 19 Atmospheric Gases isolated by 18th Century Chemists Nitrogen (N2) D. Rutherford 1772 Oxygen (O2) J. Priestley & A. Lavoisier 1774 Carbon Dioxide (CO2) J. Black 1756 ATM OCN 100 Summer 2004 20 See Table 2.1 Moran (2002) FRACTIONAL VOLUMETRIC COMPOSITION OF DRY AIR in HOMOSPHERE O2 21% Ar CO2 0.03% 0.93% N2 78% ATM OCN 100 Summer 2004 21 B. PRESENT EARTH’S ATMOSPHERE (con’t.) Vertical Variations of Atmospheric Composition – Criterion Chemical – Divisions HOMOSPHERE HETEROSPHERE – Where ... ATM OCN 100 Summer 2004 22 VERTICAL COMPOSITION VARIATIONS (con’t.) HOMOSPHERE – – – “Homo” = same (percentage composition); Turbulent mixing; Below 80 km altitude. HETEROSPHERE – – – “Hetero” = different (composition); Fractional diffusion (by molecular weight); Above 80 km altitude. ATM OCN 100 Summer 2004 23 CONSTITUENTS OF AIR in the HOMOSPHERE (Below 80 km) Principal Permanent Gases of “Dry Air” Principal Variable gases Anthropogenic Gases Aerosols – Liquids or solids suspended in Atmosphere Clouds – Liquid droplets or ice crystals in Atmosphere ATM OCN 100 Summer 2004 24 PRINCIPAL FIXED GASES in the “Dry” Homosphere Nitrogen (N2) – Importance in Food Chain (Nitrogen Fixation) Oxygen (O2) – Critical Importance for Life (Respiration) Argon (Ar) – Unknown Importance Carbon Dioxide (CO2) – Critical Importance for Life (Photosynthesis) (also Asphyxiation) ATM OCN 100 Summer 2004 25 See Table 2.1 Moran (2002) FRACTIONAL VOLUMETRIC COMPOSITION OF DRY AIR in HOMOSPHERE O2 21% Ar CO2 0.03% 0.93% N2 78% ATM OCN 100 Summer 2004 26 PRINCIPAL VARIABLE GASES in the Homosphere Water Vapor (H2O) < 4% by volume Carbon Dioxide (CO2) 360 ppm = 0.036% Methane (CH4) < 1700 ppb = 0.00017% Ozone (O3) < 8 ppm = 0.0008% ATM OCN 100 Summer 2004 27 Recent Atmospheric CO2 Concentrations See Fig. 3.24, Moran (2002) ATM OCN 100 Summer 2004 28 Mauna Loa Observatory, HI ATM OCN 100 Summer 2004 29 Ozone A paradox – Good and Bad Natural production & destruction where… ATM OCN 100 Summer 2004 31 Ozone Formation Figure 3.18 Moran (2002) ATM OCN 100 Summer 2004 32 Ozone Destruction (Natural) Figure 3.18 Moran (2002) ATM OCN 100 Summer 2004 33 Ozone A paradox Natural production & destruction Location in Atmosphere ATM OCN 100 Summer 2004 34 VERTICAL OZONE PROFILE ALTITUDE [km] US STANDARD ATMOSPHERE 1976 140 120 100 80 60 40 20 0 8 ppmv = 0.0008% 0 1 2 3 4 5 6 7 8 9 MIXING RATIO [PPMV] ATM OCN 100 Summer 2004 35 ANTHROPOGENIC SUBSTANCES Chlorofluorocarbons (CFCs) Volatile – Organic Compounds (Hydrocarbons) Oxides of nitrogen (NO, NO2) Oxides of carbon (CO, CO2) Sulfur compounds (H2S, SO2, SO3) Suspended particulates ATM OCN 100 Summer 2004 36 AEROSOLS What they are – Suspended solid particles or liquid droplets in atmosphere. Sources – Natural – Human activity Where…. ATM OCN 100 Summer 2004 37 Aerosols from Wildfires 11 May 2000 (NOAA-15) ATM OCN 100 Summer 2004 38 Aerosols from Colorado Wildfires 10 June 2002 (SSEC - MODIS) ATM OCN 100 Summer 2004 39 Aerosols from Volcanoes Mt. St. Helens, WA May 1980 ATM OCN 100 Summer 2004 40 Volcanic Plume from Mt. Etna 23 July 2001 (NOAA-14) ATM OCN 100 Summer 2004 41 Aerosols-Dust from Mongolia 10 Apr 2001 ATM OCN 100 Summer 2004 42 Aerosols from Blowing Dust ATM OCN 100 Summer 2004 43 Aerosols from Sea Spray (Calif. Coast) ATM OCN 100 Summer 2004 44 Aerosols from Natural Vegetation in Great Smoky Mtn. Nat'l Park, NC-TN ATM OCN 100 Summer 2004 45 Aerosols from Urban Pollution Madison (from Space Science & Eng. Center) ATM OCN 100 Summer 2004 46 Relative sizes of dust – Coarse sand 2 mm – Beach sand 0.5 mm – Granulated sugar 0.4 mm – Table salt 0.1 mm – Typical Mideast particles Fine sand Silt, dust – Talcum powder ATM OCN 100 Summer 2004 0.06 mm 0.05 mm or less 0.01 mm 47 PRINCIPAL VARIABLE GASES in the Heterosphere (above 80 km) Diatomic nitrogen (N2) 85 to 200 km Monatomic oxygen (O) 200 to 1100 km Helium (He) 1100 to 3500 km Atomic hydrogen (H) 3500 to 11,000 km ATM OCN 100 Summer 2004 48 C. ORIGIN & EVOLUTION of Earth’s Atmosphere How did our current atmosphere evolve? General History of the Atmosphere – 4.5 billion yr ago - Solar System formed – And then… ATM OCN 100 Summer 2004 50 Early Atmosphere before 3 billion years BP Outgassing of H2O CO2 CH4 NH3 Formation of Oceans ATM OCN 100 Summer 2004 51 Fossil algae 2 billion yrs old vs. living algae Photosynthesis Water + Carbon Dioxide + Sunlight ---> Sugar + Oxygen 6H2O + 6CO2 + Sunlight ---> C6H12O6 + 6O2 ATM OCN 100 Summer 2004 52 C. ORIGIN & EVOLUTION of Earth’s Atmosphere ATM OCN 100 Summer 2004 53 ATMOSPHERIC ORIGIN & EVOLUTION (con’t) Rationale Planet Earth is special because of large amounts of O2; – Atmosphere & Life Co-evolved. Human Intervention – Humans could possibly affect concentrations of some gases, with following… – ATM OCN 100 Summer 2004 58 Enhanced “Greenhouse Effect” Background ATM OCN 100 Summer 2004 59 Enhanced “Greenhouse Effect” Increases in “Greenhouse Gases” – CO2 and CH4 Why more CO2? – Burning of fossil fuels – Deforestation – Changes in Sea Surface Temperature ATM OCN 100 Summer 2004 60 Global CO2 Emissions Marland, et.al. 2001 ATM OCN 100 Summer 2004 Carbon Dioxide Information Analysis Center 61 ATM OCN 100 Summer 2004 62 CO2 measurements at Mauna Loa, HI See Fig. 3.24 Moran (2002) ATM OCN 100 Summer 2004 63 CO2 measurements at South Pole ATM OCN 100 Summer 2004 64 Enhanced “Greenhouse Effect” (con’t.) Increases in “Greenhouse Gases” – CO2 and CH4 Why more CO2? – Burning of fossil fuels – Deforestation – Changes in Sea Surface Temperature Potential Implications – Ice cap melting & coastal flooding – Changes in agricultural areas – Increases in diseases and pests ATM OCN 100 Summer 2004 65 See Fig. 3.25 Moran (2002) ATM OCN 100 Summer 2004 66 “Ozone Hole” Background Destruction of Stratospheric Ozone – From CFCs ATM OCN 100 Summer 2004 67 Destruction of ozone by CFCs. See pg 49-51, Moran (2002) ATM OCN 100 Summer 2004 68 CFC & other Solvent Concentrations in Atmosphere (Source: NOAA/CMDL) ATM OCN 100 Summer 2004 69 Evolution of the “Ozone Hole” ATM OCN 100 Summer 2004 NASA TOMS Project 70 Recent “Ozone Hole” Status NASA TOMS Project ATM OCN 100 Summer 2004 71 “Ozone Hole” Changes 1980-2002 (TOMS Project – NASA GSFC, 2003) ATM OCN 100 Summer 2004 72 “Ozone Hole” (con’t.) Background Destruction of Stratospheric Ozone – From CFCs Potential Implications – Increased skin cancer – Increased cataracts – Unknown changes to food chain ATM OCN 100 Summer 2004 74 D. ATMOSPHERES of OTHER PLANETS General – Composition Considerations: Planetary Size (influences planetary gravity) – Closeness to Sun (influences temperature) Atmospheric Composition of Planets Inner Planets – Outer Planets – ATM OCN 100 Summer 2004 75 E. VARIATION OF CHARGED PARTICLES WITH HEIGHT Composition Ions: Charged Particles Location – Ionosphere – Magnetosphere Implications – Radio Communications – Aurora Borealis (Australis) The Reason - Active Sun – ATM OCN 100 Summer 2004 78 Ionosphere See pg. 35, Moran (2002) ATM OCN 100 Summer 2004 79 Magnetosphere See Fig. 2.13 Moran (2002) Northern Lights Planetarium ATM OCN 100 Summer 2004 80 MAGNETOSPHERE ATM OCN 100 Summer 2004 82 AURORA BOREALIS ATM OCN 100 Summer 2004 (from Univ. of Alaska) 83 Aurora from Space Shuttle ATM OCN 100 Summer 2004 86 Atmosphere in Perspective (UCAR) ATM OCN 100 Summer 2004 90