Drill: Draw &
name 5 isomers
of C5H8
Review
Drill &
Test
11)
3
4
2
11)
1
11) 1,2,4-trimethylbenzene
3
4
2
1
12)
12) 4-methyl-5-phenyl2-hexyne
13) para-phenylcyclopropylbenzene
14)
14) trans-4-cyclobutyl3-methyl-2-pentene
15)
15) cis-7-cyclohexyl3,5-dimethyl-3-octene
16)
CH3-CH2
CH3
CH3-CH-CH-CH2-C-CH2-CH3
CH3
CH2-CH2-CH3
16) 6-ethyl-3,4,6trimethylnonane
CH3-CH2
CH3
CH3-CH-CH-CH2-C-CH2-CH3
CH3
CH2-CH2-CH3
17)
18)
CH
CH
CH
CH
CH3
C-CH2-CH-CH2-CH3
CH
19)
C
C
C
C
C
C
C
C
C
C
C
C
C
20)
Functional
Groups
Chm II/Org HW
• Review PP-40
• Complete the attached
assignment & turn it in
tomorrow
Are there any
questions on
previous
material?
Draw & Name
Isomers of:
C4 H 6
Functional Groups
•Chemically active
part of an organic
compound
Functional Groups
•Anything other than
singularly bonded
carbon & hydrogen in
an organic compound
Functional Groups
•The name of any
organic compound ends
with the suffix for the
most important
functional group
Terminology
•R- represents the part
of the organic
compound you are
not referring to
Terminology
•R-OH
•-OH is the functional
group
•R- anything else
Alkene
C=C
Alkyne
C=C
Halides
R-X
•X = F, Cl, Br, or I
•haloalkane
•alkylhalide
Halides
Cl
•2-chlorobutane
•2-butylchloride
Ethers
R1-O-R2
•alkylalkylether
•alkoxyalkane
Ethers
CH3CH2-O-CH3
•Methylethylether
•methoxyethane
Hydroxyl Group
C OH
Alcohols
R-OH
•hydroxyalkane
•alkanol
Alcohols
CH3-CH2-OH
•hydroxyethane
•ethanol
Carbonyl Group
C=O
Ketones
O
R-C-R
•Oxy or ketoalkane
•alkanone
Ketones
O
•3-pentanone
•3-oxypentane
Aldehyde
O
R-C-H
•alkanal
•alkanaldehyde
Aldehydes
O
H
•hexanal
•hexanaldehyde
Homework
•Draw & Name 5
isomers of C4H8O
Name the following:
OH
CH
H3C
Cl
CH
CH2 CH3
Name the following:
OH
CH
H3C
Cl
CH
CH2 CH3
4-chloro-2-pentanol
OH
CH
H3C
Cl
CH
CH2 CH3
Drill: Name the
following:
OH
O
OH
O
2-hydroxy-4-hexanone
5-hydroxy-3-hexanone
OH
O
Review Drill
&
Check HW
Organic HW
• Review PP-10
• Complete the attached
assignment & turn it in
tomorrow.
Are there any
questions on
previous
material?
Carboxyl Group
C=O
HO
Carboxylic Acid
O
R-C-OH
•Alkanoic Acid
Carboxylic Acid
O
CH3-CH2-C-OH
•Propanoic Acid
Drill: Draw & name 5
isomers of:
OH
OH
Review &
Collect Drill
& HW
CHM II/ORG HW
•Review PP 40
•Complete the attached
assignment & turn it in
tomorrow.
Any
Questions?
Functional Isomers:
•Isomers with different
functional groups:
•The suffix changes
O
Propanone
O
H
Propanaldehyde
Positional Isomers:
•Isomer’s functional
group in a new location
•The # before the main
chain name changes
OH
2-propanol
OH
1-propanol
Name the following:
CH3-CH2-CH2-OH
CH3-CH2-O- CH2-CH3
O
CH3-CH2-C-CH2-CH3
Name the following:
O
O
C
C
H3C
CH
OH
OH
Name the following:
O
O
C
C
H3C
CH
OH
OH
2-hydroxy-3-ketobutanoic acid
O
C
H3C
O
C
CH
OH
OH
Name the following:
O
CH3-CH2-CH2-C-OH
O
CH3-CH2-C-H
Carboxyl
Derivatives
C=O
O
Esters
O
R1-C-O-R2
•Alkylalkanoate
Esters
O
CH3-CH2-CH2-C-O-CH3
methylbutanoate
Anhydrides
O O
R1-C-O-C-R2
•Alkanoicalkanoic
anhydride
O
O
O
Butanoicpropanoic anhydride
Draw the following:
• 2-hydroxypentanal
• Methylpropylether
• Trichloroethanoic acid
• Ethylbutanoate
• Aceticformic anhydride
Drill: Draw &
Name 5 isomers of:
C3H6O2
Review Drill
&
Check HW
Organic HW
• Review PPs 1-40
• Begin the Final review
attached to Poly’s
Website
Name, then & Draw & name a
Functional Isomer of:
C
C
OH
C
C
C
O
C
C OH
C
C
OH
C
C
C
O
C
C OH
3-hydroxy-5methylhexanoic acid
C
C
OH
C
C
C
O
C
C OH
2,3-dihydroxy-5methylhexanal(dehyde)
C
C
OH
C
C
C
O
C
OH
C H
1,3-dihydroxy-5methyl-2-hexanone
C
C
OH
C
C
C
C
O
C OH
Name & Draw 1
Positional Isomer of:
C
C
OH
C
C
C
O
C
C OH
2-hydroxy-5methylhexanoic acid
C
O
C
C
C
C
C
OH
C OH
Name & Draw 1
Structural Isomer of:
C
C
OH
C
C
C
O
C
C OH
3-hydroxyheptanoic
acid
C
C
OH
C
C
C
O
C
C OH
Name & Draw 1
Optical Isomer of:
C
C
OH
C
C
C
O
C
C OH
To draw an optical
isomer, draw the
mirror image of an
assymetric compound
3-hydroxy-5methylhexanoic acid
C
C
OH
C
C
C
O
C
C OH
3-hydroxy-5methylhexanoic acid
HO
O
OH
C
C
C
C
C
C
C
Draw:
•2-phenylpropanoic acid
•3-hydroxy-2-iodopentanal
•2-cyclohexyl-3-octanone
•phenylbutanoate
Drill: Name:
Cl
C
C
O
C
C
OH
C
O
Cl
C
C
O
C
C
OH
C
O
4-chloro-2-keto-3phenylpentanoic acid
Cl
C
C
O
C
C
OH
C
O
Drill: Draw the
following:
•Butanoicpentanoic
anhydride
O
C
C
O
C
C
C
O
C
C
C
C
Review Drill
&
Check HW
Organic HW
• Review PP-10
• Complete the attached
assignment & turn it in
tomorrow.
Thiol
R-SH
•Sulfhydrylalkane
•Mercaptoalkane
•Alkanethiol
SH
•3-sulfhydrylpentane
•3-mercaptopentane
•3-pentanethiol
Sulfide
R1-S-R2
•Alkylalkylsulfide
•Alkylalkylthioether
Sulfide
S
•diethylsulfide
•diethylthioether
Disulfide
R1-S-S-R2
•Alkylalkyldisulfide
Disulfide
S-S
C
methylphenyldisulfide
Thioesters
O
R1-C-S-R2
•Alkylthioalkanoate
Thioesters
O
CH3-C-S-CH3
•Methylthioethanoate
Draw the Following:
• Methylthiobutanoate
• Methylphenyl ether
• Diphenyl thioether
• 2-propanethiol
Name:
SH
C
C
OH
C
C
C
Cl
O
SH
C
C
OH
C
C
C
Cl
O
3-chloro-2-mercaptopentanoic acid
SH
C
C
OH
C
C
C
Cl
O
Drill: Name:
O
C
C
C
C
C
O
Name:
O
C
C
C
C
C
O
Methyl-2-cyclohexyl
butanoate
O
C
C
C
C
C
O
Check Drill
& HW
CHM II/ORG HW
• Review PPs 22 – 40
• Begin the Final Review
attached to Poly’s Website
Amine Group
N:
Ammonia
:NH3
Ammonium
NH4
+
Primary Amines
R-NH2
•Aminoalkane
•alkylamine
Primary Amines
CH3-NH2
•Aminomethane
•methylamine
Secondary Amines
R2
R1-NH
Alkylalkylamine
CH3
CH3-CH2-NH
methylethylamine
Tertiary Amines
R2
R1-N-R3
Alkylalkylalkylamine
CH2-CH3
CH3-N:
CH2-CH2-CH3
methylethylpropylamine
Quaternary Amines
R2 +
R1-N-R3
R4
•Tetraalkylammonium
CH3
+
CH3-N-CH3
CH2-CH2-CH3
trimethylpropylammonium
CH3
+
CH3-N-H
CH2-CH2-CH3
dimethylpropylammonium
Amides
O
R1-C-NH2
•Alkanoamide
O
C-C-C-C-C
NH2
•Pentanoamide
Nitrile
R-C=N
•Cyanoalkane
•Alkanonitrile
Nitrile
CH3-C=N
•Cyanomethane
•Ethanonitrile
Name:
OH
C
C
OH
C
C
C
F
O
Name:
OH
C
C
OH
C
C
C
F
O
3-fluoro-4hydroxypentanoic acid
OH
C
C
OH
C
C
C
F
O
Draw & name
10 isomers of:
C4H9NO
Draw the following:
•2-phenyl-1-propanol
•Butylethenyl ether
Draw the following:
•phenylthioacetate
•methylisopropylsulfide
•2-mercaptobutanal
Name:
C
C
C
S
C
C
O
Name:
C
C
C
S
C
C
O
propylthioacetate
C
C
C
S
C
C
O
Name:
SH
OH
O
OH
Name:
SH
OH
O
OH
3-hydroxy-5-mercapto-6methyl-7-phenyloctanoic acid
SH
OH
O
OH
Draw & name
10 isomers of:
C4H8SO2
Drill: Name
O
H
SH
O
Drill: Name
O
H
SH
O
5-cyclohexyl-2-keto-3mercapto-4-phenylpentanal
O
H
SH
O
Homework
•Draw & Name 5
isomers of C4H9NO2
Name
N
C
OH
H
N
O
H
Name
N
C
OH
H
N
O
H
4-cyano-2-hydroxy-3methylhexanoamide
N
C
OH
H
N
O
H
Drill: Name
Cl
OH
OH
O
Name
Cl
OH
OH
O
4-chloro-2-hydroxy-3methylhexanoic acid
Cl
OH
H
N
O
Return Tests,
Review Drill,
& Review Tests
Organic HW
• Review PP-10
• Complete the attached
assignment & turn it in
tomorrow.
Discuss
Grades
Primary Amines
R-NH2
•Aminoalkane
•alkylamine
Secondary Amines
R2
R1-NH
Alkylalkylamine
Tertiary Amines
R2
R1-N-R3
Alkylalkylalkylamine
Quaternary Amines
R2 +
R1-N-R3
R4
•Tetraalkylammonium
Amides
O
R1-C-NH2
•Alkanoamide
Nitrile
R-C=N
•Cyanoalkane
•Alkanonitrile
Name
N
C
OH
NH2
O
Drill: Name
N
C
HO
NH2
O
trans-4-cyano-2-hydroxy3-methyl-3-heptenoamide
N
C
HO
NH2
O
Cyanate
R-O-C=N
•Alkylcyanate
Cyanate
O-C=N
•cyclohexylcyanate
Isocyanate
R-N=C=O
•Alkylisocyanate
Isocyanate
N=C=O
•1-pentylisocyanate
Thiocyanate
R-S-C=N
•Alkylthiocyanate
Thiocyanate
S-C=N
•2-propylthiocyanate
Isothiocyanate
R-N=C=S
•Alkylisothiocyanate
Isothiocyanate
CH3-N=C=S
•Methylisothiocyanate
Lab: 05
•Functional Groups
Containing
Nitrogen
Phosphates
O
-1
R-O-P-O
-1
O
•Alkylphosphate
Phosphates
O
-1
-O-P-O
-1
O
•Phenylphosphate
Diphosphates
O O
-1
R-O-P-O-P-O
-1
-1
O O
•Alkyldiphosphate
Diphosphates
O O
-1
CH3-O-P-O-P-O
-1
-1
O O
•Methyldiphosphate
Triphosphates
O O O
-1
R-O-P-O-P-O-P-O
-1
-1
-1
O O O
•Alkyltriphosphate
Triphosphates
O O O
-1
-O-P-O-P-O-P-O
-1
-1
-1
O O O
•2-butyltriphosphate
Phosphodiester
O
CH3-CH2-O-P-O-CH3
-1
O
•Methylethylphosphate
Carboxylic acid
Carboxylic acid derivative
Aldehyde
Ketone
Alcohol
Amine
Thiol
Drill: Draw &
Name 5 isomers of:
C3H7NO2
Drill: Name:
O
OH
C
Br
NH2
OH
Name the following:
O
OH
C
Br
NH2
OH
Organic HW
•Draw & Name 5
isomers of:
C3H6SO
Drill:
Draw & Name 5
Isomers of:
C4H7NO
Lab: Today
Review: Tomorrow
Test : Wednesday
Name the following:
N
C
O
C
OH
NH2
Name the following:
N
C
O
C
OH
NH2
3-cyano-2-hydroxy-7-methyl6-phenyloctanoamide
N
C
O
C
OH
NH2
Drill: Name the
following:
O
Cl
C
SH
NH
OH
Name the following:
O
Cl
C
SH
NH
OH
2-amino-3-chloro-4mercapto-N,7-dimethyl-6phenylnonanoic acid
O
Cl
C
SH
NH
OH
Test Tomorrow
on
Functional
Groups
Name the following:
O
F
OH
Name the following:
O
F
OH
3-fluoro-1-methoxy-4-methyl-2cyclopropylhepta-5-yn-1-ol
O
F
OH
Name the following:
PO4-2
OH
O
O
O
Name the following:
PO4-2
1
OH
2
O
O
O
4-methyl-3-phenyl-2phosphopentanoic-2hydroxypropanoic anhydride
PO4-2
OH
1
2
O
O
O
Draw:
• 3-mercaptohexanoamide
• Methyl-2-hydroxythioacetate
• Para-iodophenylformic acid
• Phenylpropylamine
• 2-amino-3-ethyl-4-keto-Nmethylhexanaldehyde
Draw & Name 10
isomers of:
C4H9SNO
Draw & Name 10
isomers of:
C4H9NO2
Name the following:
P3O10-4
NH
Name the following:
P3O10-4
NH
4-amino-6,7-dimethyl-Nphenyl-3-octyltriphosphate
P3O10-4
NH
Name the following:
SH
O
H
O
Name the following:
SH
O
H
O
3-mercapto-6,7-dimethyl4-phenoxynonanal
SH
O
H
O
Drill: Name:
N
C
NH2
O
OH
OH
Name:
N
C
NH2
O
OH
OH
3-amino-5-cyano-4hydroxyhexanoic acid
N
C
NH2
O
OH
OH
Name the following:
N
C
S
O
O
Br
Name the following:
N
C
S
1
O
O
Br
propyl-4-bromo-3-cyclobutyl5-thiocyanatohexanoate
N
C
S
1
O
O
Br
Name the following:
O
Cl
OH
Name the following:
O
Cl
OH
3-chloro-2-cyclopropyl-4methylpentanoic acid
O
Cl
OH
Drill: Name the
following:
O
O
F
O
Drill: Name the
following:
O
O
2
F
O
1
Methyl-3-fluoro-2-keto-4methylpentanoate 1
O
O
2
F
O
Name the following:
N
C
S
OH
O
Name the following:
N
C
1
S
2
OH
O
Ethyl-2-cyano-3hydroxythiohexanoate
N
1
C
S
2
OH
O
Draw the Following:
•3-methyl-5-propyloctanoamide
•Octylbutanoate
Draw the Following:
•Aceticpentanoic
anhydride
•2-cyano-3mercaptohexanoic acid
Drill Draw &
name 5 isomers
of:
•C4H7NO
Draw:
•Benzoic acid
Draw:
•4-hydroxy-Nmethylbenzoamide
Drill: Draw:
4-hydroxy-2mercapto
pentanoic acid
Review
C=C
O
R C
O R
R N C O
R-SH
R-NH2
O
R C
OH
O
C
R
R
R-OH
O
C
R
O
C
O
R
R C N
H
:N R
R
O
R C
NH2
O
R C
H
RO C N
R1-O-R2
R-I
R +
R N R
R
C=C
R +
R NH
R
R1-S-R2
O
R C
S R
R S C N
-2
O
O P O R
O
R
:N R
R
R-S-S-R
R N C S
Drill: Name:
NH2
SH
OH
O
Name the
compounds on
the board
Draw the
compounds on
the board
Draw & Name
10 isomers of
C4H7SNO
C4H7NO