Equilibrium: ICE Tables Learning Target: I can solve equilibrium problems using ICE tables. ICE tables are used to calculate equilibrium concentrations of the reactants and products from the initial concentrations. Steps to use “ICE” table: 1.“I” = Tabulate known ___________ concentrations (and equilibrium concentrations if known) of all species in equilibrium expression 2.“C” = Determine the concentration ______________ for the species where initial are known •Use stoichiometry to calculate concentration changes for all other species involved in equilibrium 3.“E” = Calculate the _________________ concentrations Sample Problem 1: Enough ammonia is dissolved in 5.00 L of water at 25ºC to produce a solution that is 0.0124 M ammonia. The solution is then allowed to come to equilibrium. Analysis of the equilibrium mixture shows that [OH1-] is 4.64 x 10-4 M. Calculate Keq at 25ºC for the reaction: NH3 (aq) + H2O (l) ↔ NH41+ (aq) + OH1- (aq) Sample Problem 2: When hydrogen iodide (HI) is placed in a closed container it will decompose into its elements hydrogen and iodine and an equilibrium will be established: 2 HI (g) H2(g) + I2(g) Initial concentration of HI: 0.025 mol/L Kc=2.2x10-3 Sample Problem 3: A 5.000-L flask is filled with 5.000 x 10-3 mol of H2 and 1.000 x 10-2 mol of I2 at 448ºC. The value of Keq is 1.33. What are the concentrations of each substance at equilibrium? H2 (g) + I2 (g) ↔ 2 HI (g) ** Calculate concentrations