Orbital Notation, Valence Electrons & Lewis Dot Structures

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Orbital Notation, Valence Electrons

& Lewis Dot Structures

1.

Get out your notes

2.

Wait quietly

Electron Configuration Rules

1.

Aufbau Principle

Each electron MUST occupy the lowest energy orbital available first

2.

Pauli Exclusion Principle

A maximum of 2 electrons can occupy a single orbital, but only if the electrons have opposite spins

3.

Hund’s Rule

Single electrons with the same spin must occupy each equal energy orbital before additional electrons with opposite spins can occupy those same orbitals

Aufbau Principle

Each electron MUST occupy the lowest energy level and sublevel available first

Determine the order of energy levels, sub-levels, and the orbitals within the sub-levels

Energy levels are in the order of the periods down the periodic table

Order: 1, 2, 3, 4, 5, 6, and 7

Sub-levels: are in the order of s, p, d, and f

Aufbau Principle:

Notice that d and f sub-levels are “behind” s and p sub-levels

Pauli Exclusion Principle

A maximum of 2 electrons can occupy a single orbital, but only if the electrons have opposite spins

Remember the amount of orbitals in each sub-level

S-sublevel = 1 orbital = 2 electrons

P-sublevel = 3 orbitals = 6 electrons

D-sublevel = 5 orbitals = 10 electrons

F=sublevel = 7 orbitals = 14 electrons

Each energy level holds a set amount of electrons:

1 st energy level = 1 sublevel and 1 orbital = max 2 electrons

2 nd & 7 th energy level = 2 sublevels and 4 orbitals = max 8 electrons

3 rd & 6 th energy level = 3 sublevels and 9 orbitals = max 18 electrons

4 th – 5 th energy levels = 4 sublevels and 16 orbitals = max 32 electrons

Remember that d and f sublevels are behind s and p

Hund’s Rule

Single electrons with the same spin must occupy each equal energy orbital before additional electrons with opposite spins can occupy those same orbitals

Orbital Notation:

Shows the electrons in an orbital and their spin

S- 1 orbital, p- 3 orbitals, d – 5orbitals, and f – 7 orbitals

Lines/boxes represent the orbitals

The number of the energy level and its sublevel are written below the line

Uses up and down arrows to represent the electrons and their spins

Example: Lithium – 1s 2 2s 1

_________ _________

1s 2s

Hund’s Rule

Orbital Notation

Let’s Try Nitrogen:

1s 2 2s 2 2p 3

___________

1s

_____________

2s

__________ ___________ ___________

2p

*This is called an orbital diagram/notation

A little more of a challenge: Sulfur

What is Sulfur’s electron configuration?

________________________________________________________

What is Sulfur’s orbital notation?

*Remember:

S- 1 orbital, p- 3 orbitals, d – 5orbitals, and f – 7 orbitals

Your Turn:

Complete these in your notes

Write the orbital diagrams for the following elements:

Manganese

Potassium

Gallium

Valence Electrons

The electrons that determine the chemical properties of an element

The electrons in the highest (outermost) energy level

How do we know what is the highest/outermost energy level?

The electron configuration for Chlorine is:

1s 2 2s 2 2p 6 3s 2 3p 5

• The outermost energy level is the 3 rd energy level

• Chlorine has 7 valence electrons (2 + 5 = 7)

Valence Electrons

How many valence electrons are found in the following atoms?

Element Electron Configuration # of Valence Electrons

Sodium

Carbon

Gallium

Oxygen

Fluorine

Valence Electrons

THERE IS AN EASIER WAY!!!!

Lewis Dot Structure

A model that uses electron-dot structures to show how electrons are arranged in molecules.

Shows the valence electrons around the element symbol

What is an element symbol?

Aluminum =

Aluminum has _____ valence electrons

Imagine aluminum symbol with a box around it

Al

*Each side of the box can only hold 2 electrons

*Put 1 dot (to represent 1 electron) on each side before adding a second dot to that side of the box – Pauli’s Exclusion Principle

So the final product looks like this: Al

Give Sulfur a try:

How many valence electrons does Sulfur have? ______

S

Your turn:

Complete these in your notes

Draw the Lewis Dot Structure for the following elements:

Element Symbol and number of valence electrons

Lewis Dot Structure

Lithium

Nitrogen

Calcium

Bromine

Carbon

Selenium

Until the Bell Rings:

Work on your homework: Page 7 in packet and prelab

REMEMBER:

LAB TOMORROW YOU MUST BE DRESSED IN LAB

ATTIRE

Closed shoes

Long pants (no skin, not even ankles)

NO baggie sleeves

Hair pulled back

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