11/24 I’m home with my baby today because my mother-in-law had to go home ;) But we are still learning! Sit in your assigned seat, 5th period! Over Thanksgiving Break • No homework • Spend time with the people you love Plan for today • Go over homework answers • Get a reminder on polar bonds and polar molecules • Complete a station ‘activity’ Homework answers – show your lewis structure to the sub to get homework credit Update your chart with the angles shown in green DO NOT TAKE NOTES • These slides are posted on the website • Just listen and try to understand • Ask questions • I mean, you can write down a bit if you really want to. I don’t think you need to, though…. What makes a molecule polar? • That depends on the polarity of the bonds in the molecule AND the arrangement of those bonds (shape of the molecule) Nonpolar Covalent Bonds • Covalent bonding involves sharing electrons between atoms. • Nonpolar covalent bond – equal sharing of electrons between two atoms. • Both atoms have same attraction for shared pair (they have the same electronegativity or very close). • Example: H – H Polar Covalent Bonds • Polar covalent bond – unequal sharing of electrons between atoms. • One atom has greater attraction for shared pair. (Think: Tug – of – War). • Example: H – Cl • This creates partial (d) charges on each atom in the bond. The atom with the higher electronegativity has the partial negative charge. • We have been talking about whether or not the bonds were polar • Now lets talk about whether or not the molecule is a polar as a result of the polar bonds Molecular Polarity • Of course, if you have a molecule with only one nonpolar bonds (because it’s the same atoms), that molecule will be a NONPOLAR MOLECULE regardless of the shape • Like H2 • Like ozone, O3 But what if the bonds are polar? Does that mean the molecule is polar? • Not necessarily…. Nonpolar Molecules • Molecules with polar bonds do not always create polar molecules. • Example: CCl4 • Shape is tetrahedral. • Because the polar bonds are spread out symmetrically in space, this has the net effect of cancelling each other out. • CCl4 is a nonpolar molecule. • Again, whenever polar bonds are symmetrically arranged, they produce nonpolar molecules. • Another example: CO2 + • Hey physics people, think of a molecule as being nonpolar when the vectors add to zero • If the polar bonds are arranged asymmetrically, the molecule is polar. • For example, see how there are hydrogen atoms on one side of the ammonia molecule and no hydrogen atoms on the other side? POLAR CHCl3 is commonly known as chloroform. • Are the bonds polar? Yes! • Chlorine is more electronegative than carbon. (ΔEN=0.61) • Carbon is more electronegative than Hydrogen. (ΔEN=0.30) • Is this molecule polar? • Yes! Because there are different differences in electronegativity (the ΔEN’s are different) FYI: anytime you have two different atoms attached to the same central atom, the molecule will be polar. • Just remember “SNAP” • SNAP Symmetrical Nonpolar Asymmetrical Polar • Molecular polarity is determined by the shape and distribution of charge in the molecule. To make your life easier, just look the atoms. • If the noncentral atoms on the molecule are different, the molecule is polar. Example: CHCl3 • If the atoms in the molecule are the same and arranged symmetrically, the charges are balanced by each other. The molecules are considered to be nonpolar. CH4 • However, if the molecule is asymmetrical, it is considered to be polar. NH3 • So if it is lopsided, it is polar. If it is balanced, it is nonpolar. You need • A piece of paper and a pencil/pen • Your chart with bond angles Station Review/Notes • You will complete a station review/notes activity • You will work with your FACE partner • If you don’t have a face partner, pair up with someone else who also doesn’t have a face partner • If there is an odd number, you can work in a group of 3 Station Review/Notes • If there are two pages at a station • If they are numbered (1 and 2), do 1 first • If there are no numbers, do them in any order • You can do the 8 stations in any order EXCEPT • Do station 1 before station 2 • You will be • Taking notes (if it’s stuff you know, don’t write it down; if you didn’t remember it or it is new, take notes) • Doing practice problems • Learning information • Reviewing information • Stations 1,3,and 7 have answers on yellow paper hanging on the far left board • Work until bell rings; you should get done with at least 5 of the stations (we will finish next time) Do not present the slides that follow Copy down the flow chart below • Determine if the following are polar or nonpolar • • • • • • • BI3 ClO2F Carbonate Phosphite Water Ammonia Carbon dioxide