Electron Configuration MS. HOANG ACP CHEMISTRY Review 1. Electrons travel in orbits or orbitals? _______________ 2. How many principal energy levels are there theoretically? _____________ 3. Fill in the table Principal Energy Level Sublevels (s, p, d, f) Orbitals Electrons (↑ or ↓) #'s Electrons Total #'s electrons n=1 n=2 n=3 Pauli Exclusion Principle Spin: up and down-spin An atomic orbital can hold a maximum of two electrons and those two electrons must have opposite spins Example: Fill in the table Principal Energy Level Sublevels (s, p, d, f) Orbitals Electrons (↑ or ↓) n=1 n=2 Aufbau Principle + Hund’s Rule Aufbau: Orbitals of lowest energy are filled first Hund’s Rule: when there are multiple orbitals of the same energy, fill the electrons in each of them first before doubling up (“no empty bus seat” rule) Spot the mistake! 3p 3s 2p 2s 1s + Spot the mistake! 3p 3s 2p 2s 1s + Spot the mistake! 3p 3s 2p 2s 1s + s 1 2 3 4 5 6 7 p 1s 2s f 2p 3s d (n-1) 4s 3d 4p 5s 4d 5p 6s 5d 6p 7s 6d 7p 6 (n-2)7 3p 4f 5f 1s Electron Configuration v. Orbital Diagram H = 1s1 1s He = 1s2 1s Li = 1s2 2s1 1s 2s 1s 2s 1s 2s 2px 2py 2pz 1s 2s 2px 2py 2pz Be = 1s2 2s2 C = 1s2 2s2 2p2 S = 1s2 2s2 2p4 3s 3px 3py 3pz Atomic Sizes in Periodic Table Ionization Energy in Periodic Table