10/6 - Q of D - Chemistry Why do we study chemistry in biology class? After you finish your answer please go to the side counter and pick up the notes for this chapter. Why do we study chemistry in biology class? – Chemistry explains how and why chemicals interact with each other – Cells are composed of chemicals, elements and molecules – To understand how cells work you must have a basic understanding of chemistry Chapter 2 Chemistry Please get 3 (different) colored pencils or crayons from side counter. Chemistry is divided into 2 branches – Inorganic Small simple substances Basic molecules of life Nonliving substances Examples: oxygen, water, salt – Organic Larger and more complex Come from living organisms Contain Carbon (except: ) Examples: carbohydrates, fats, proteins Chemistry Basics Atoms are the building blocks of the universe; everything is made of atoms Atoms from a Greek word that means “unable to cut” Keystone Definition: ATOM – the smallest unit of an element that retains the chemical and physical properties of that element. Atoms are made of smaller units called subatomic particles Protons – are small, positively charged particles found in nucleus Neutrons – are neutrally charged particles, in nucleus Electrons – negatively charged particles, found orbiting around the nucleus in electron shells/energy levels The atomic number tells the # of protons and # of electrons The atomic mass number tells the # of protons + the # of neutrons Normally the number of protons is equal to the number of electrons making the atom electrically neutral or stable. Elements The simplest substances on earth Made from only one type of atom 92 naturally occurring elements Each has different properties and characteristics that make it unique (solid, liquid, gas, helpful, flammable, poisonous etc.) Biological Elements There are 4 major elements for life – – Carbon (C), – Hydrogen (H), – Oxygen (O) and – Nitrogen (N). These are called the BIG 4 elements They make up 96% of all organisms on earth Minor Elements Phosphorus (P) Magnesium (Mg) Potassium (K) Calcium (Ca) Sodium (Na) Sulfur (S) Chlorine (Cl) Low percentages in the body – about 2.5% of the body is made of these elements. They are important for body functions. Trace Elements Boron (B) Fluorine (F) Iodine (I) Selenium (Se) Zinc (Zn) Chromium (Cr) Iron (Fe) Manganese(Mn) Cobalt (Co) Silicon (Si) Copper (Cu) Molybdenum (Mo) Very low percentages in the body (about 1%) but are very important for the body processes We get all our needed elements (vitamins) through our food or supplements. Isotopes Sometimes the number of neutrons in an element can change when everything else stays the same. Atoms of the same element that differ in the number of neutrons they contain are called isotopes. Some isotopes are radioactive and can be very useful for scientists – called radioisotopes. Ex: Carbon 12 is normal carbon has 6p, 6e, and 6 n. Carbon 14 is a radioisotope and has 6p, 6e, and 8n. It is used for carbon dating artifacts. Other uses include medical tests, drug tests, radiation for cancer treatments, diagnosing diseases, tracing pathways in an organism, and sterilizing food. Common isotopes used are Fe, Na, Co and I Putting Elements Together A compound is 2 or more elements chemically bonded together in a definite proportion Chemical or molecular formula shows the numbers of atoms of each element in the compound Example: H2O CH4 C6H12O6 A structural formula shows how the atoms are bonded together. Example: There are 2 major types of bonds 1. Ionic bonds Formed when atoms gain or lose electrons An atom with extra electrons in its valence shell will transfer them to an atom that needs electrons in its valence shell. This causes a positive ion and a negative ion The opposites attract and the atoms are held together. Examples: NaCl 2. Covalent bonds Formed when atoms share electrons – 1 pair of e- are shared = single bond – 2 pairs of e- shared = double bond – 3 pairs of e- shared = triple bond More common in many of the substances found in organisms Are very strong bonds Examples: sugar, fats, propane NaCl KF CH4 NH3 Acids Substances that have more H+ ions Taste sour Between 0-7 on the pH scale Examples of acids would be lemon juice, stomach acid, coffee, tomatoes, saliva Bases Substances that have more OH- ions Taste bitter Between 7-14 on the pH scale Examples of bases would be saltwater, soap, bleach, cleaners pH Measure of acidity is pH. Scale from 0-14 Water is a pure substance – only made from Hydrogen and Oxygen so it is neutral or 7 on the scale. It is important that the body maintain the proper pH in order for reactions to occur. Most reactions in humans occur at pH of 7.4 (slightly basic) You can die if your overall body pH goes lower than 7 or higher than 7.8 Your body has buffering systems in place to maintain this pH (homeostasis) WATER ¾ of the earth’s surface 70% of the human body. Most chemical reactions in the body take place in water Only common substance on earth to exist in all 3 physical forms – gas, liquid, solid. Vital for life as we know it Properties of Water Water is a polar molecule. This means that it has an unequal distribution of charge on different sides of the molecule. Because it is polar, water is the universal solvent. Can dissolve many substances. Important because many substances in our bodies must be dissolved in water for reactions to occur. Water molecules are attracted to each other and form hydrogen bonds between them. Water has cohesion – means that water molecules stick to each other. This produces surface tension. Water acts as if it has a “thin skin” Water has adhesion – water molecules stick to other types of molecules Water displays capillary action (capillarity) – can move upward through small tubes against gravity. Plants use cohesion, adhesion and capillarity to move water from roots to leaves. Water has a high specific heat. This means that water resists temperature changes – takes a lot of heat/energy to raise the temperature. This helps to keep the temperatures on Earth stable and allows organisms to remain at stable temperatures even when environment changes This also helps animals cool off by sweating, panting and bathing. Solid water is LESS dense than liquid water….this is not what most liquids do! Water has it greatest density at 4oC – this means that water expands when it freezes and ice floats. Important for water habitats. Helps to insulate the water below the ice so that aquatic creatures can survive. ACID RAIN Precipitation is naturally slightly acidic due to reactions with carbon dioxide in the atmosphere. The term acid rain describes precipitation that has a pH lower than 5.5. It can be acid rain, snow or fog. What causes acid rain? Burning of fossil fuels (coal) releases pollutants including sulfur dioxide and nitrogen oxide. These pollutants react with water droplets in the upper atmosphere and make sulfuric acid and nitric acid. These acids then fall to the ground in rain/snow Effects of Acid Rain 1. Water ecosystems are disturbed – Makes rivers, lakes more acidic – Water organisms begin to die or have their life cycles disrupted Organisms Preferred pH range Aquatic plants (algae) 6.5 to 12.5 Carp, catfish, some insects 6 to 9.5 Bluegill 6.5 to 9.5 Snails 7 to 10 Stonefly and caddisfly larvae 7 to 8.5 One of the things that can be done to help correct the pH of water and soil is to add limestone. This acts as a buffer and helps to neutralize the acids. In some areas limestone is added to lakes and streams to help prevent the organisms from dying. 2. Harms vegetation – Damages leaves of plants – disrupts the way that plants take in and release water, carbon dioxide and oxygen, – disrupts the amount of food the plant can make through photosynthesis – decreases the amount of food we can harvest 3. Deteriorates buildings and historical monuments – Acid “eats” away at the structures 4. Damage human health – Causes more lead to be released from water pipes – Still unknown effects 5. Financial Impact – Estimated that effects of acid rain cause 5 billion dollars of damage a year in the eastern US. The greatest Acid Rain problems are in… – Mid Atlantic States (Ohio, New York, PA) –WESTERN PENNSYLVANIA! WHY????? – Almost half of all emissions in the US are from big industrial cities in Indiana, Illinois, Michigan, Ohio and Missouri – Winds carry these gases in a northeast direction How bad is the problem? The average pH of Pennsylvania rainfall is between 4.1 and 4.3 Pennsylvania receives one of the highest concentrations of acid precipitation in the US and the world. What is helping in PA In PA we have a lot of limestone. This is a natural way for the acid rain to be buffered before entering the lakes, streams. This lessens the impact of acid rain in this area and prevents us from seeing the most severe effects of the precipitation. Other areas do not have this natural limestone and have seen the full effects. What is being done? The Clean Air Acts of the 1990’s require a reduction in the amount of pollutants from industry. This acts are still being implemented in phases. Conservation is stressed – conserve electricity to reduce the amount of coal burned. Use cars less to reduce pollution Is it working? The measures are working – the pH is making slow changes – moving a little towards neutral. Has been a 22% reduction in the amount of sulfur dioxide released from power plants. As more measures are enforced expected to keep getting better. Ways you can help Use less fossil fuels – Reduce pollution by using your car less. – Conserve electricity in your house – Turn off/unplug appliances when not in use – Reduce heating/cooling of home – Buy local products – Use alternative energy sources if possible The END of chapter 2 ! Assignment: Pg 47 # 1-3,5,7, and short response