Draw the Lewis Structure and give the molecular shape and molecular polarity of the following molecules: H2S 2. CHCl3 3. SO3 4. O2 1. Give the name or formula of the following provided the opposite. 1. 2. 3. 4. 5. H3PO4 CF4 NaNO3 C2H4 SO2 6. 7. 8. 9. 10. Methane Nitrogen trihydride Ammonium hydroxide Ethanol Hydrochloric acid A counting number (like a dozen) Avogadro’s 1 number (NA) mol = 6.02 1023 particles A large amount!!!! 1 mole of hockey pucks would equal the mass of the moon! 1 mole of basketballs would fill a bag the size of the earth! 1 mole of pennies would cover the Earth 1/4 mile deep! Mass of 1 mole of an element or compound. Atomic mass tells the... › atomic mass units per atom (amu) › grams per mole (g/mol) Usually rounded to 2 decimal places 1 mol of carbon 12.01 g/mol 1 mole of aluminum 26.98 g/mol 1 mole of zinc 65.39 g/mol water H2O 2(1.01) + 16.00 = 18.02 g/mol sodium chloride NaCl 22.99 + 35.45 = 58.44 g/mol sodium bicarbonate • NaHCO3 • 22.99 + 1.01 + 12.01 + 3(16.00) sucrose = 84.01 g/mol • C12H22O11 • 12(12.01) + 22(1.01) + 11(16.00) = 342.34 g/mol Is the same as Average Atomic Mass The percent of each isotope of an element is used to find the average mass of that element. (mass A1 x % of A1) + (mass A2 x % of A2) 100 = Average Mass of A This was done earlier in the year. Remember the Skittlesium Lab? Calculate the average atomic mass of rubidium if 72.17% of its atoms have a mass of 84.91 amu and 27.83% of its atoms have a mass of 86.91 amu (84.91 x 72.17%) + (86.91 x 27.83%) = 85.47 amu the percentage by mass of each element in a compound mass of element % composition 100 total mass Percentage Composition Find the % composition of Cu2S. %Cu = %S = 127.10 g Cu 159.17 g Cu2S 32.07 g S 159.17 g Cu2S 100 = 79.852% Cu 100 = 20.15% S Percentage Composition Find the percentage composition of a sample that is 28 g Fe and 8.0 g O. %Fe = %O = 28 g 100 = 78% Fe 36 g 8.0 g 36 g 100 = 22% O Percentage Composition How many grams of copper are in a 38.0-gram sample of Cu2S? Cu2S is 79.852% Cu (38.0 g Cu2S)(0.79852) = 30.3 g Cu Percentage Composition Find the mass percentage of water in calcium chloride dihydrate, CaCl2•2H2O? %H2O = 36.04 g 100 = 24.51% H2O 147.02 g Smallest whole number ratio of atoms in a compound C2H6 reduce subscripts CH3 1. Find mass of each element. If given percent, just say it’s a mass. 2. Find moles of each element. 3. Divide all moles by the smallest mole to find subscripts. 4. When necessary, multiply subscripts to get whole #’s. If number ends in… ≈ 0.50 ≈ 0.33 ≈ 0.25 multiply by… 2 3 4 Find the empirical formula for a sample of 25.9% N and 74.1% O. 25.9 g 1 mol 14.01 g 74.1 g 1 mol 16.00 g = 1.85 mol N 1.85 mol = 4.63 mol O 1.85 mol =1N = 2.5 O N1O2.5 Need to make the subscripts whole numbers multiply by 2 N2O5 “True Formula” - the actual number of atoms in a compound empirical formula CH3 ? molecular formula C2H6 1. Find the empirical formula (EF). 2. Find the empirical formula mass. 3. Divide the molecular formula (MF) mass by the empirical mass. 4. Multiply each subscript of the empirical formula by the answer from step 3. MF mass n EF mass EF n The empirical formula for ethylene is CH2. Find the molecular formula if the molecular mass is 28.1 g/mol? empirical formula mass = 14.03 g/mol 28.1 g/mol = 2.00 14.03 g/mol (CH2)2 C2H4