Why Study Chemistry in Biology? Banana Cell with Starch Granules The Size of an Atom The Atom Definition: smallest particle of an element C. Composition Subatomic Particle Charge Mass Location Proton +1 1 Nucleus Neutron 0 1 Nucleus Electron -1 1/1840 the mass of a proton Orbiting nucleus D. If Neutral Atom: protons will = electrons II. Elements A. Definition: substance that cannot be broken down into other substances B. Biologically important elements i. Major: C H O N ii. Minor: Ca Fe Mg I Se P K Na Cl C. Symbol: usually from first letter or two of full name Elements Con’t. Mass Number Atomic Mass 12.0107 amu D. Atomic Number: # of protons in nucleus i. Mass number: count of the total number of protons and neutrons in an atom's nucleus ii. Atomic mass: average mass of an atom based on the relative abundance of its isotopes F. Isotopes i. Definition: forms of the same element have same # of protons but different # of neutrons Mass Number ii. Radioactive isotopes: An isotope having an unstable nucleus that decomposes spontaneously G. Location of Electrons i. First level is closest to nucleus- holds TWO electrons ii. Second level is further out- holds EIGHT electrons iii. Third level can hold up to 18 electrons Fill the orbital closest to nucleus first 1. Valence electrons: outermost electrons, participate in BONDING See the different i levels?! H. Chemical Compounds i. Molecules definition: two or more atoms held together by COVALENT bonds ii. Compound definition: a substance containing two or more elements in a fixed ratio – Ex: H2O, NaCl Decoding Chemical Formulas?? C6H12O6 Element subscript is the NUMBER of ATOMS So in this molecule, there are 6 carbon atoms, 12 hydrogen, and 6 oxygen 2H2O • The number in front of H2O means two entire molecules of H2O • Think of it like 2 x (H20) • Sooooo… how many total atoms of H are there? • Of oxygen? • Atoms want to fill their outer energy levels to be • In order to do this, they will meet up with other atoms and either share or exchange electrons • Atoms share electrons so that both atoms fill their outer energy level B. Ionic Bonds: gimme that electron! • Atoms transfer electrons, becoming (+) or (-) charged • This attraction brings them together – Ex: Na and Cl i. Ions > An electrically charged atom CATIONS: positively charged ions, have more PROTONS ANIONS: negatively charged ions, have more ELECTRONS Hydrogen Has 1 electron, needs 1 to fill its orbital Carbon Has 4 electrons in outer level, needs 4 more to fill its orbital Can form ONE bond Can form FOUR bonds V. WATER LIFE DEPENDS ON THE UNIQUE PROPERITIES OF WATER Questions to think about • Why do put salt on the roads? • Why do we salt a pot of pasta water? • At a higher altitude why must we cook “boil” something longer? A. Human Composition: Cells are 70–90% water B. Plant Composition As much as 95% plants can be made of water C. Formula: H2O D. Bonds: i. Hydrogen bonds: the slightly (+) H atoms are attracted to nearby (-) O atoms, and develop a weak bond. Hydrogen Bonds • Hydrogen Bondsweak bonds slightly positive H is attracted to the slightly negative O of another water molecule ii. Covalent bonds: are shared between oxygen and hydrogen in a single molecule. E. Polarity • Polar molecule: molecule in which opposite ends have opposite electric charges • Why? Water is a polar molecule: because Oxygen is an electron HOG • POLAR COVALENT BOND The polar nature of water and the effects of hydrogen bonding explain most of water's unique properties. • • • • • Cohesion Adhesion Solubility Temperature moderation The lower density of ice i. Cohesion • Definition: Water “sticks” to each other • Surface tension 1-inch paperclip over-filled water 3oz Dixie cup Jesus Christ Lizard ii. Adhesion 1. Definition: Water molecules are also attracted to certain other molecules. 2. Ex. In trees/plants water goes against gravity Called capillary action iii. Solubility Water is the a Universal Solvent 1. Water is able to dissolve other Polar & ionic compounds when mixed by causing the ions to break away and surround them. • Water dissolves Salt (Na+Cl-) Water (Polar) will not dissolve (Nonpolar) • Like dissolve Like • Water won’t dissolve oils Temperature and Water Boiling Point: 100 oC • When you heat molecules move faster • When you cool molecules move slower • Water takes more energy to heat because energy must break hydrogen bonds 212 oF iv. Boiling Point Does water boil faster if you add salt to it? • Water Boils when it has enough energy for the molecules to leave v. Freezing Point 0 oC or 32 oF • What would happen if our oceans did not have salt in them? • Why do we put salt on our roads? • Why at effect does salt have on FREEZING POINT? LOW DENSITY OF ICE • Density- amount of matter in a volume • In most substances the solid state is more dense than the liquid state • Water is the opposite ICE IS LESS DENSE THAN WATER and will FLOAT LOW DENSITY OF ICE • WHY????? • Hydrogen bonds in ice (solid) keep molecules spaced out LOW DENSITY OF ICE • Floats • Ice insulates the liquid water below allowing life to persist G. Acids and Bases i. A water molecule can react to form ions ii. An ion is when a molecule breaks down and the atoms get a charge 1. Example: H+ and OH- iii. pH Scale 1. How? Scale of 0-14; each pH unit represents a tenfold change in the concentration of H+ ions 2. Acid definition: pH 0-6 3. Base definition: pH 8-14 4. Buffer definition: substances that cause a solution to resist changes in pH.; works by accepting H+ ions when levels rise and donating H+ ions when levels fall, maintaining a constant pH a. Weak acid or base