Mrs. Ashley Glass is made up primarily of three substances ◦ Sand ◦ Soda ◦ Lime Most glass is Bottle Glass or also called SodaLime glass (90% of all glass) Windows are made from Float Glass which is soda lime glass that is allowed to cool on top of a liquid Radial Concentric bsapp.com A projectile hole is inevitably wider at the exit side bsapp.com Backscatter- when window breaks, most of the fragments will be carried forward, but some will be projected backwards, called backscatter Heat fracture-In a fire, glass may break due to heat fracture that looks like wavy fracture lines towards the heat source A fracture always terminates at an existing line of fracture bsapp.com Radial cracks are at Right angles to the Rear (side opposite the impact) Exceptions –tempered glass “dices” without forming ridges –very small windows held tightly in frame can’t bend or bulge appreciably – windows broken by heat or explosion no “point of impact” Do the glass particles from suspect and crime scene fit together? ◦ Most of the time the glass evidence is too fragmentary or too minute to permit a comparison of this type. ◦ Most often it is the composition of the glass that is examined and the method of how glass was broken. The general composition of most glass is the same. Density Refractive Index Each type of glass has a density that is specific to that glass. One method of matching glass fragments is by density comparison. Density (D) is calculated by dividing the mass (m) of a substance by its volume (V). The formula for calculating density can be written as D = m V Measure the density using a scale (be sure to zero scale before using and put to correct units – grams) Measure the volume by measuring the amount of water displaced using a graduated cylinder in milliliters. Use your calculator on phone to find M/V to find the density Refractive Index ◦ When light travels from one medium to another its speed changes relative to the density of the medium. This can be observed as the light bends when traveling from one medium to another. The speed of light in a vacuum is always the same, ◦ but when light moves through any other medium it travels more slowly since it is constantly being absorbed and reemitted by the atoms in the material. The ratio of the speed of light in a vacuum to the speed of light in another substance is defined as the index of refraction (aka refractive index or n) for the substance. This measurement does not have units The FBI has a database off over 2000 refractive indexes of different types of glass which shows that glass is very distinctive and helps assign an appropriate statistical probability that the two pieces of glass share a common source. Submersion method: Place glass fragment into different liquids of known refractive indexes. If a piece of glass and a liquid have the same refractive index, the glass fragment will seem to disappear when placed in the liquid. Submersion and Low Power of Microscope. Submerge fragment of glass in a liquid and then view it under low power using a compound microscope. If the refractive index (n) of the liquid medium is different from the refractive index of the piece of glass, a halo-like ring appears around the edge of the glass. This halo-like effect is called a Becke line Notice the halo of light on the inside perimeter of the glass sample. When the Becke line is inside the perimeter of the glass fragment, the refractive index of the glass is higher than the refractive index of the surrounding medium. Notice the halo of light (Becke line) is outside the perimeter of the glass fragment. When the Becke line is outside the perimeter of the glass sample, the refractive index of the medium is higher than the refractive index of the glass. You will use the submersion method by placing the piece of glass in substances with a known refractive indices. When the glass and the substance have the same refractive index, the glass will appear to disappear. In reality, if a piece of glass is immersed in a liquid with the same refractive index, the glass usually does not completely disappear. The reason is that there are other effects caused by light passing through glass. These are more pronounced when the glass is thick. The result is that we can still see faint borders of the glass even if they have the same refractive index. Remember to wear goggles and gloves until your lab is complete and area is clean Use forceps to pick up glass particles Once lab is complete, clean up your area and return all materials to the proper location. Complete the Study Guide on Glass Analysis, due Monday, April 28. Test on Glass Analysis Monday April 28, after we go over the study guide at beginning of class.