MVC CHEMISTRY 1A – Fall 2012 Course: Instructor: Course Website: Meetings: Office Hours: CHEM 1A – General Chemistry I Jessy M. Lemieux , M.S.; Jessy.Lemieux@rcc.edu www.LemieuxChem.com Lec.: MW 12:45 PM - 2:10 PM, HM 105 Lab: MW 2:20 PM - 5:30PM, SCI 261 TR 4 PM – 5 PM or by appointment. A. TENTATIVE SCHEDULE (this syllabus may be changed at the discretion of the instructor) Revised 8/8/12 DATE LECTURE AND READING LABORATORY 8-27 MATTER [Chapter 1] 8-29 IONIC BONDING AND NOMENCLATURE [2.7, 2.8] Quiz #1: Chapter 1 and Element Names HOLIDAY 9-3 9-5 Check-In, Safety, Experiment 1: Measuring Density of a 10% Salt Solution at Room Temperature Experiment 2: Effect of Concentration on Density of a Salt Water Solution Experiment 3: Exploding Particles 9-8 COVALENT BONDING AND NOMENCLATURE Quiz #2: Ionic Nomenclature LAST DAY TO DROP WITH A “W” 9-10 ELEMENTS [2.1 TO 2.6] Experiment 4: Compounds: Ionic Bonding 9-12 Experiment 5: Compounds: Covalent Bonding 9-17 MIXTURES [2.9] Quiz #3: Chapter 2 IONIC BONDING MODEL [9.1 TO 9.2] 9-19 COVALENT BONDING MODEL [9.3 TO 9.5] THE 9-24 SHAPES OF MOLECULES [10.1 TO 10.3] Library Research Orientation; Bonding in complex molecules (flavors and fragrances); Organic Models Experiment 7: Fun with Polymers EXAM 1 REVIEW 9-26 BONDING APPLICATIONS TO ENVIROMENT EXAM 1 (CHAPTER 1, 2, 9 AND 10) 10-1 STOICHIOMETRY [3.1 TO 3.3] Experiment 8: Stoichiometry 10-3 SOLUTION STOICHIOMETRY [3.4 TO 3.5] Quiz #4: Stoichiometry AQUEOUS IONIC REACTIONS [4.1 TO 4.4] Experiment 9: Law of Conservation of Mass 10-10 REDOX REACTIONS [4.5 TO 4.6] Quiz #5: Solutions and Stoichiometry Experiment 11: Preparation of Magnetite Experiment 12: Oxidation-Reduction Worksheet 10-15 GAS LAWS [5.1 TO 5.4] 10-17 KINETIC MOLECULAR THEORY [5.5 TO 5.6] Quiz # 6: Gas Laws Experiment 20: Charles’ Law Experiment 21: Pressure-Volume Relations of Gases Experiment 22: Molar Volume of Nitrogen 10-8 Experiment 6: The Valence Shell Electron Pair Repulsion Theory (VSEPR) Page 1 of 9 Experiment 10: Acid-Base Titrations MVC J. Lemieux CHEM 1A Fall 2012 DATE LECTURE AND READING LABORATORY 10-22 REVIEW FOR EXAM 2 EXAM 2 (CHAPTER 3, 4, AND 5) 10-24 ENERGY AND CALORIMETRY [6.1 TO 6.3] 10-29 HESS’S LAW [6.4 TO 6.6] Quiz #7: Energy and Calorimetry QUANTUM THEORY [7.1 TO 7.2] Experiment 15: Calorimetry: The Enthalpy Formation of MgO Experiment 14: Heat Reactions 10-31 11-5 Experiment 16: Emission Spectra and Atomic Structure Experiment 17: Absorption Spectrophotometry and Beer’s Law Experiment 13: Specific Heat of a Metal 11-7 ATOMIC SPECTRA [7.3 TO 7.4] Quiz #8: Stoichiometry PERIODIC TABLE [8.1 TO 8.2] 11-12 HOLIDAY 11-14 Experiment 18: The Alkaline Earths and Halogens 11-16 PERIODIC TRENDS [8.3 TO 8.4] Quiz #9: Periodic Table (8.1 to 8.2) LAST DAY TO DROP 11-19 REVIEW FOR EXAM 3 EXAM 3 (CHAPTER 6, 7, AND 8) 11-21 BONDING THEORIES [11.1 TO 11.3] Experiment 19: The Eight Solution Problem 11-26 INTERMOLECULAR FORCES [12.1 TO 12.3, 13.1] Quiz #10: Bonding Theories Experiment 25: Determination of Molar Mass By Freezing Point Depression 11-28 LIQUIDS AND WATER [12.4 TO 12.5] Experiment 23: Crystal Structure 12-3 SOLIDS [12.6] & SOLUTIONS [13.3 to 13.7] Quiz # 11: Intermolecular Forces Experiment 24: Chemistry of Aluminum Chemistry Survivor Game: The Rules 12-5 REVIEW Chemistry Survivor Game 12-10 12-12 B. FINAL EXAM IN SCI 261 AT 2:20 PM ASSIGNED HOMEWORK PROBLEMS FROM TEXTBOOK Homework assignments will be due at 12:45 AM on the day of the exam. They should be handwritten with all important calculation steps included. Each chapter set should be clearly labeled. I will select a small subset of the problems to grade and assign a score based on performance on the selected questions and based on how many questions were attempted. Remember, homework will only constitute about 10% of your total grade while exams will be worth much more. Therefore, understanding how to complete each problem in the homework assignments is more important than getting the points for completing it. Don’t rush through the problems. Instead, make sure you understand each and every assigned problem. Falling behind on homework is a disaster in any chemistry class because topics build upon one another very quickly. Being even a week behind will make lecture very confusing for you so be sure to keep up and ask for help right away if you need it. Page 2 of 9 MVC J. Lemieux CHEM 1A Fall 2012 Exam 1 CH 1: 5, 7, 27, 31, 33, 39, 43, 44, 48, 53, 55, 58, 61, 63, 67, 73, 77, 81, 84 CH 2: 21, 23, 44, 50, 57, 73, 75, 77, 85, 91, 97, 106, 122, 123, 132 CH 9: 7, 13, 15, 17b, 21, 25, 29, 31, 40, 46, 48, 63, 65, 67, 68, 74, 78 CH 10: 6, 8, 10, 12, 14, 16, 18, 22, 33, 35, 37, 39, 41, 58, 60, 62a,c,f,j,k,l, 63a,c,f,j,k,l 64, 74, 79, 83 Exam 2 CH 3: 9, 13, 17, 19, 35, 39a, 39b, 57, 59, 60, 67, 69, 73, 77, 79, 81, 92, 100, 102, 104, 108, 110, 124, 136 CH 4: 5, 15, 19, 30, 35, 36, 50b, 58, 67, 69, 73, 75b, 80, 81, 92, 96, 102 CH 5: 9, 21b, 21c, 29, 32, 38, 40, 48, 53, 56, 59, 72, 76, 84, 88, 89, 95, 96, 103 Exam 3 CH 6: 11, 27, 29, 36, 38, 40, 42, 47, 48, 53, 58, 59, 66, 70, 71, 78, 80, 83, 85, 86, 92, 100 CH 7: 10, 14, 24, 28, 30, 32, 34, 40, 44, 50, 52, 56, 58, 65, 73, 78 CH 8: 12, 22b, 24, 26, 34, 36, 38, 40, 42, 44, 46, 48c, 54, 56, 70, 76, 80, 82, 84, 89, 101 Final Exam CH 11: 2, 6, 8, 10, 12, 22, 24, 31b,c, 33, 37, 38, 47, 50 CH 12: 3, 15, 20, 22, 27, 40, 42, 46, 48, 52, 62, 64, 66, 89b, 95b, 138 CH 13: 10, 12, 14, 26b, 37a, 40, 45, 57, 65a, 71, 76, 91, 93, 95, 99, 118 C. CLASS GENERAL INFORMATION 1. Catalog Description. CHEM 1A is an introduction to college-level chemistry with an emphasis on the mole concept, thermochemistry, atomic and molecular structure, interactions, periodic chart, organic chemistry, solids, liquids, and gases. This course is 5 units, with three hours of lecture and six hours of lab each week. 2. Prerequisites. CHEM 2A or CHEM 3, and MATH 035 3. Important Dates. The following deadlines are in effect for this semester: a) Last day to drop without a “W”: September 8 b) Last day to drop with a “W”: November 16 4. Course Website. I will regularly be communicating with you through the course website, www.LemieuxChem.com. Regular access to this website is strongly advised, as announcements, handouts, practice worksheets, scores, and other information will be posted throughout the semester. Scores will be posted after I grade each exam and more frequently near the end of the quarter. Your scores will be posted according to a secret number that I will give you after the first exam. Please get in the habit of checking the course website frequently. 5. Course Objectives. After completion of the course, students should be able to: a) Solve multi-step problems (using formulae and unit-analysis) relating to atoms and elements, chemical bonding and molecular geometry, chemical reactions and stoichiometry, properties of the states of matter, phase changes and solutions. Analyze the nature of chemical bonding and reactions. b) Collect and analyze data from chemical experiments, including graphing, calculations and qualitative understanding of how data relates to the concept studied. Compose standard Page 3 of 9 MVC J. Lemieux CHEM 1A Fall 2012 operating procedures (SOPs) and/or papers in appropriate scientific format for these experiments. Design experiments that minimize sources of error for concepts studied in the course. Demonstrate laboratory safety protocols, including proper waste management. c) Construct and manipulate equipment to secure reasonably accurate measurements. d) Describe, analyze, apply, and assess chemical concepts of atoms and elements, chemical bonding and molecular geometry, chemical reactions and stoichiometry, properties of the states of matter, phase changes and solutions. e) Describe and apply a chemical vocabulary of approximately 500 words and apply the IUPAC system of chemical nomenclature. 6. Student Learning Outcomes. a) Students will demonstrate an understanding of the relationships between chemical quantities by using dimensional analysis to convert units of concentration, mass, moles, molecules, atoms or other stoichiometric variables. In addition, students will interpret the results of dimensional analyses to accurately predict the theoretical yields of chemical reactions and compare this to experimentally determined yields. b) Based on the conceptual visualization of the atomic realm utilizing the periodic table, theories of bonding, and determinations of molecular structures, students will appraise the physical and chemical properties of substances. D. REQUIRED CLASS MATERIALS 1. This Syllabus. Available from instructor and posted on the course website. 2. Textbook. Silberberg, Chemistry: The Molecular Nature of Matter and Change (6th Edition), 2012. ISBN: 978-0-07-340265-9 or any other good general chemistry text. Some free texts and resources are available on the website (listed on the left sidebar of the course website). 3. Lab Manual. Chemistry 1A Laboratory Experiments. Available on the course website. 4. Scientific Calculator. Graphics or text-memory calculators are not allowed for use during quizzes or exams. If you bring one you will have to perform calculations without a calculator! You are encouraged to obtain a scientific calculator with exponents and logarithms immediately. It is important to be comfortable with the calculator that you are using, rather than to be struggling to locate the keys for certain mathematical operations. For example, a TI-30X IIS is acceptable, and allows for parentheses. Please make sure you bring your calculator to each lecture & lab period. 5. Goggles. Goggles must be worn in the laboratory when experiments are being performed. There will be basic goggles available in the lab but more comfortable goggles can be found online at retailers (such as Amazon.com or others) for $10 to $20. It is often a worthwhile investment. Page 4 of 9 MVC J. Lemieux E. CHEM 1A Fall 2012 CLASS EXPECTATIONS AND GRADING POLICY 1. Attendance. Unexcused absences in either lecture or lab during the first week may result in being dropped from the class. You also may be dropped from the class if you miss: a) two laboratory periods, or b) two consecutive lecture periods or three total lecture periods. You must attend all exams, including the final exam, in order to pass the class. There are no make-up assignments; if you miss a class, you forfeit those points. Attendance and participation are critical aspects to success in this course. 2. Grade Basis. Your course grade will be based on your performance on: a) midterm exams, b) final exam (comprehensive), c) quizzes, d) homework, e) laboratory, and f) extra credit assignments. Work will be returned within a week of the assigned date, and grades will be posted on the course website after each exam. It is your responsibility to check the posted grades and to retain all exams, quizzes, etc. until your final course grade has been assigned. Any discrepancies between posted scores and graded assignments must be immediately brought to the attention of your instructor. Please do not wait until the end of the semester to point out any grading issues. A. Midterm Examinations: (300 points possible; 26%). Four examinations will be given (at 100 points each); there are no make-up exams. Exams will cover both conceptual aspects and calculations. The proper use of units and significant figures is required for calculations. Questions regarding exam grading must be submitted to your instructor during the period when the exams are returned. All exams may be photocopied before they are returned, and any request for regrade will be compared to the original. Any change on the original paper submitted for regrade consideration is cheating and will result in an immediate F for the course. B. Comprehensive Final Exam: (250 points possible; 23%). The final exam for the course is comprehensive, covering material presented during the entire semester. You must attend the final exam in order to pass the class. C. Lecture Quizzes: (150 points possible; 14%). Quizzes will be given throughout the semester, and are designed to be ~ 15 min in length. Eleven quizzes will be given. Each will be worth 15 points. Quizzes cannot be made up; however, the lowest quiz score will be dropped. Questions regarding quiz grades must be submitted to your instructor during the period when the quizzes are returned. D. Homework: (150 points possible; 14%). Working the homework problems represents an extremely important component in this course. Although you will work on lots of problems during class, it is important that you practice on your own in order to maximize your problem-solving skills. The homework problems from the textbook are listed on p. 2-3, along with their due dates. There are four assignments worth 30 pts each (120 points total). At the beginning of lecture on each exam day, you will submit your hand-written work for your homework assignments. You must show all work (i.e., for every problem) in order to receive full credit. Homework that is submitted showing answers only (for any part of the problem set) or that is submitted late will result in a low score for the entire assignment. An additional 30 points will be assigned for “homework” at the end of the quarter based on your participation in class. Low attendance or poor class citizenship will result in a low score in this section. E. Laboratory: (250 points possible; 23%). The laboratory grade is based on 25 lab reports (typically turned in at the end of the period, 10 pts. each) There are no make-up labs, but you can be excused from lab once if you have a valid, documented emergency. You must earn at least 50% of the total lab points in order to potentially receive a course grade higher than an F. Page 5 of 9 MVC J. Lemieux CHEM 1A Fall 2012 F. Extra credit: (50 points maximum). The opportunities listed here are the only possible sources of extra credit in this course. Although completing every assignment could lead to more than 50 points, there is a set maximum of 50 points total of extra credit. i. Supplemental Instruction (SI). As an incentive to encourage group-study, there is extra credit available to those who participate in weekly, facilitated peer-led SI sessions. The SI schedule will be announced during the first week of class. Attendance of each workshop is worth 2 points with a maximum of 50 points. You must be present for at least 90 min and must actively participate in the facilitator’s activities for the day. You are encouraged to continue to attend workshops even after you have reached the maximum extra credit. In past CHEM 1A classes, the students who regularly attended workshops typically demonstrated a better understanding of the material than those who did not attend. ii. Spontaneous bonus points (variable amounts). As an incentive to attend class and participate in the discussions, I will decide to assign bonus points for active involvement during class challenges, bonus quizzes, and other worthy activities. You must be present (and complete the activity) to receive bonus points. iii. Extra Credit Assignment: (30 points maximum). Extra credit can be earned by those students who exhibit an extra effort to expand the depth of their knowledge in the course. Read the article "The Octet Rule and Hypervalence: Two Misunderstood Concepts," Gillespie, R. J.; Silvi, B. Coordination Chemistry Reviews 2002, 234, 53-62. (provided on the course website) This article will be a hard read but will give you some insight into how some of the physical processes that we study in the course are still not fully understood and continue to be active areas of research. After reading, write a 1.5 page paper describing your best understanding of how the article you read differed from your textbook in its description of the octet rule and hypervalence. G. Summary of Points: Exam I Exam II Exam III Final Exam Quizzes Homework Laboratory TOTAL: 100 100 100 250 150 150 250 1,100 3. Letter Grades. Letter grades will be earned as follows: A: ≥ 90% B: 80 – 89% C: 70 – 79% Page 6 of 9 D: 60 – 69% F: < 60% MVC J. Lemieux * CHEM 1A Fall 2012 SPECIAL NOTE: You must accumulate at least 50% of the points in both lecture and lab, in order to not receive a failing grade (F) in the course. Acquiring less than 50% of the points in either lecture or lab will result in a course grade of F, regardless of your total percentage. In addition, your lecture average (quizzes, exams, final exam) must be at least 65%, in order for a course grade of a C or better to be possible. Once these thresholds are met, then your course grade is dictated by your overall percentage, as outlined above. Please note that simply meeting the 65% threshold in lecture does not guarantee a C or better if your overall percentage is less than 70%. I will provide frequent feedback to show your standing in the course, but feel free to inquire at any time if you are unsure. Please do not ask about additional extra credit to boost an undesired anticipated or final course grade; the only available extra credit is that described in the “extra credit” section. Likewise, please do not ask me to raise a grade because you wanted or needed a higher one. It is your responsibility as college students to keep up with the material as we go along, to study appropriately, and to get help when you need it. 4. Other. a) Tutoring Services: MVC offers free tutoring to students, in addition to your scheduled SI Sessions. MVC Tutorial Services is an outstanding resource (did I mention that it’s free?!) that exists for your use. You are also encouraged to form study groups with other students in the class, as discussing concepts and problems often leads to a better understanding of the material. Please visit http://www.mvc.edu/services/ts/ for more information. Also, don’t forget my office hours, as they are scheduled for your benefit. b) Electronic Devices: Please turn off your cell phones/pagers before coming to class; texting during class is prohibited. All types of headphones, earbuds, Bluetooth, etc. are not permitted to be worn during any lecture or lab period. Given the interactive nature of the lecture period, laptop computers are probably not useful for taking notes, although tape recorders are allowed. All cell phones and MP3 players must be put away and may not be accessible during an exam or a quiz. Interruption of the lecture by electronic devices or failure to adhere to this policy regarding electronic devices may result in dismissal from the class. c) Cheating: A student found cheating in any part of the course, including in the laboratory or on examinations will receive a zero on that assignment and may be referred to a disciplinary hearing, expelled, or receive a failing grade for the course. Students are not allowed to leave and return during any quiz or exam (lecture or lab); doing so potentially compromises academic integrity and will be considered academic dishonesty. Plagiarism, which is presenting the work of others as your own, is also cheating. Examples of plagiarism are not limited to copying text from the lab manual, textbook, or a website; but also include work or answers from another student (e.g., homework, exercises, lab reports). The same penalty will be applied to all partners in incidents involving academic dishonesty. The instructor will also report each student’s dishonest conduct to the campus administration for disciplinary action, which could mean dismissal from the College. YOU are responsible for understanding what constitutes cheating, as found in the Class Schedule. If you are not sure what is allowed, please ask me. d) Accommodations for Students with a Disability: If you require accommodation, please contact Disabled Student Programs and Services to make your request. They are located in SCI 150. You can call them at (951) 571-6138 Voice or (951) 571-6140 TDD. Page 7 of 9 MVC J. Lemieux F. CHEM 1A Fall 2012 CLASS SUGGESTIONS FOR SUCCESS This class is very demanding, and it is imperative to keep up with the material and not to fall behind! The college estimates that 3 hours of study time should be spent each week for every one course unit; therefore, your outside commitment to lecture material in this course should be at least 9 hours per week, every week. If your schedule does not permit this sustained level of commitment, then be advised that it will be difficult to pass this class. CHEM 1A is substantially more difficult than was CHEM 2A and requires more time on your part in order to be successful. The same effort required in CHEM 2A to earn a C will likely result in not passing CHEM 1A. Please feel free to discuss your individual situation with me if you would like some guidance. I strongly encourage a mix of study approaches, including working together with a study group, attending workshops, and practicing homework problems individually. It is important to understand that you must work problems over and over again in order to develop good problem-solving skills based on critical thinking. In other words, simply scratching the surface of the material in this course or looking for shortcuts will not be enough to demonstrate a thorough understanding. It will be very difficult, if not impossible, to pass this class by trying to cram at the last minute. In addition, it is not enough just to be able to plug numbers into an equation. I will also expect you to understand (and to be able to explain) the conceptual basis behind any calculations. H. LABORATORY 1. Attendance & Conduct. Punctual attendance at each laboratory period is required. If you miss more than two lab periods, you may be automatically dropped from the course and will not pass. It is understood that you have planned your laboratory session around other obligations (e.g., work, family). However, should an extreme situation arise (e.g., serious illness, etc.), please contact your instructor by email, as soon as possible. You are expected to be on time to lab—anyone arriving more than 10 minutes late without a legitimate reason may not be allowed to perform the experiment, and will receive a zero for the day’s assignment. Important safety information and demonstration of procedures will take place at the beginning of the lab period. All cell phones and pagers must be turned off for the duration of the lab period. Texting or internet browsing during lab is prohibited, and incoming or outgoing calls or text messages may result in dismissal from the laboratory. 2. Preparation for Lab. Being prepared for lab is essential, in order to perform the experiment effectively and efficiently. CHEM 1A experiments are much more detailed than those in CHEM 2A, and most of them are performed as individuals, rather than with lab partners. You are expected to read the assigned experiment before the lab meeting. In order to evaluate your understanding of the day’s experiment, a short pre-lab quiz may be given at the beginning of each experiment, and will be worth 25% of that lab grade (e.g., 2.5 pts out of 10). If you consistently choose not to prepare for the lab, then it will be impossible to earn better than a “C” in the laboratory portion of the class. 3. Laboratory Experiments. In order to receive credit for a given lab experiment, you must attend lab, wear goggles and closed-toe shoes (no sandals!), and conduct the experiment. There are no make-up labs, so be sure to attend each session and perform each lab. Borrowing experimental data from another student is not allowed. Lab reports are usually due at the end of the laboratory period, unless announced otherwise by your instructor. In the event that a lab report is due at the beginning of a lecture or lab period (e.g., long reports), anything submitted after the first 10 min of the period is considered late, and will receive a significantly reduced score. Please be sure that you clearly understand this policy for late assignments. Page 8 of 9 MVC J. Lemieux CHEM 1A Fall 2012 G. NOMENCLATURE For these elements, ions, and acids, you must know their names (spelling counts), symbols/formulas, and charge(s). In addition, you should be able to name any ionic or molecular compound consisting of these species. For the elements, you also need to know their classification (metal, nonmetal, metalloid), phase at room temperature, and classification/location on the periodic table. Common ionic charges are shown in parentheses. Alkali Metals (form +1 cations) Li Na K Rb Cs Fr Alkaline Earth Metals (form +2 cations) Be Mg Ca Sr Ba Ra Transition Metals Ag (+1) Cd (+2) Zn (+2) Ni (+2) Cu (+1, +2) Hg (+1, +2): Hg22+; Hg2+ Au (+1, +3) Co (+2, +3) Fe (+2, +3) Pt (+2, +4) V (+2, +3, +5) Cr (+2, +3, +6) Mn (+2, +3, +4, +7) Other Metals U Pu Np Ce Cf Al (+3) Ga(+3) In (+3) Sn (+2, +4) Pb (+2, +4) Metalloids B Si Ge As Sb Te Po Polyatomic Ions NH4+ H3O+ Noble Gases (Nonmetals) He Ne Ar Kr Xe Rn Halogens (Nonmetals) (form –1 anions) F* Cl* Br* I* At ammonium hydronium Other Nonmetals C CH3COO– (or C2H3O2–) CN– OH– MnO4– SCN– NO2– NO3– HSO3– HCO3– HSO4– H2PO4– acetate H (+1)* O (–2)* S (–2) Se (–2) N (–3)* P (–3) ClO4–, BrO4–, IO4– ClO3–, BrO3–, IO3– ClO2–, BrO2–, IO2– ClO–, BrO–, IO– per-root-ate (root=chlor, brom, iod) root-ate (root=chlor, brom, iod) root-ite (root=chlor, brom, iod) hypo-root-ite (root=chlor, brom, iod) O22– CO32– C2O42– CrO42– Cr2O72– SO42– SO32– S2O32– HPO42– peroxide carbonate oxalate chromate dichromate sulfate sulfite thiosulfate monohydrogen phosphate PO43– phosphate cyanide hydroxide permanganate thiocyanate nitrite nitrate hydrogen sulfite (bisulfite) hydrogen carbonate (bicarbonate) hydrogen sulfate (bisulfate) dihydrogen phosphate Acids HCl HBr HI † HF HNO3 HClO4 H2SO4 † H2CO3 † H2SO3 † H3PO4 HC2H3O2 (CH3COOH) *elemental diatomic: H2, N2, F2, O2, I2, Cl2, Br2 (Have No Fear Of Ice Cold Beer) † weak acids Some metals can take on more than one charge – you need to know these. But keep in mind that you can always figure out what the charge of the metal is in a particular compound. Page 9 of 9