What are the six types of chemical reactions? Types of Chemical Reactions 1. Synthesis (A+ B ----> AB) 2. Decomposition (AB------> A + B) 3. Single Replacement (A+ BC ---> B + AC) 4. Double Replacement (AB + CD ---> CB + AD) 5. Combustion (CxHx + O2 ----> CO2 + H2O) 6. Neutralization (Acid + Base--> H2O + Salt) Replacement Reactions Directions: Predict products, balance equations, and predict the states of matter for each substance. (s, l, g, aq) Single Replacement Reaction: Ex. Li + MgCl2 -----> Double Replacement Reaction: Ex. CaCl2 + Na3(PO4) ---> Replacement Reactions Single Replacement Reaction: Ex. Li + MgCl2 -----> LiCl2 + Mg Double Replacement Reaction: Ex. CaCl2 + Na3(PO4) ---> Ca3(PO4)2 + NaCl Replacement Reactions Single Replacement Reaction: Li (s) + MgCl2(aq) -----> LiCl2 (aq) + Mg (s) Double Replacement Reaction: 3CaCl2(aq) + 2Na3(PO4) (aq) ---> Ca3(PO4)2 (aq) + 6NaCl (aq) Do replacement reactions always occur? Single Replacement Reactions Li + MgCl2 -----> Double Replacement Reactions • Usually will occur because the reactants are aqueous solutions (mobile ions able to interact equally with other ions of opposite charge). 3CaCl2(aq) + 2Na3(PO4) (aq) ---> Ca3(PO4)2 (aq) + 6NaCl (aq) • Can use the solubility table to determine if one of the products of a double replacement reaction is insoluble in solution (precipitate/solid) 3CaCl2(aq) + 2Na3(PO4) (aq) ---> Ca3(PO4)2 (?) + 6NaCl (?) Acids and Bases dissolve and dissociate in water. Ionic vs. Covalent Compounds • Most covalent compounds (exception acids), will not dissociate in solvents. Ionic solution Covalent solution Electrolytes Electrolytes: Solutes that dissociate in solvents. Non-electrolytes: Solutes that do NOT dissociate in solvents. Chem II: 9/3/13 Objectives: • Evaluate hypothesis for Activity Series and Solubility Labs with peers. • Record, analyze, and establish conclusions for each lab. Homework: • Conclusion and Balance equations from labs if needed. • Read pgs. 276-280: Synthesis and Decomposition Rxtns. • Stoichiometry Enrichment Problems (3pts.) Stoichiometry Lab: Enrichment 1.Calculate the amount of 6M HCl (in mL) needed to sufficiently react with 2.0 grams of Na(HCO3). (Hint: Density of 6M HCl = 1.09 g/mL) 2. Validate why the calculated volume of 6M HCl above could increase percent yield of products. 3.Compare the calculated volume of 6M HCl with the actual amount you added in the expt. *Can add 3 pts. to chem I review exam * *Due Thursday * Chem II: 9/4/13 Objectives: • Complete Activity Series and Solubility Lab • Address Chem I Exams • Address Predicting Products in Synthesis and Decomposition Reactions (pgs. 276-280) Homework: • Stoichiometry Enrichment problem (3pts to test) • Synthesis and Decomposition Practice problems on webpage Replacement Reaction Labs • Establish a purpose for each lab. • First evaluate hypothesis on white boards. with peers. (data table with hypothesis) • As perform mini reactions, record data on your lab sheet and on white board. • Use white board to discuss results with peers and complete conclusion section on your lab sheet. Waste: Use water bottle to remove waste from spot plates into trash cans. Rinse and dry spot plates. Chem II: 9/5/13 Objectives: • Analyze results from replacement reaction labs. • Establish the net ionic equation for each reaction in the double replacement lab. • Discuss Predicting Products in Synthesis and Decomposition Reactions (pgs. 276-280) • Address Chem I Exams Homework: • Complete net ionic equations for double replacement lab. • Predicting products worksheet (webpage) • Quiz tomorrow: Activity Series and Solubility Activity Series Lab Results CuCl2 Cu (copper II) Mg Zn Ca Ag(NO3) HCl H(OH) Activity Series Lab • For those reactions that occurred in the lab, use the solubility diagram to determine if the ionic compound formed is soluble or insoluble in solution. Solubility Lab Results Ag(NO3) Na2(CO3) Na3(PO4) Na(OH) Na2(SO4) NaCl Pb(NO3)2 CaCl2 Solubility: Dissolving • The degree substances dissolve (physically mix) with one another. • Like dissolves like. Salt added to water Soluble Insoluble Dissociation • The degree a solute separates into its ions in a solvent. • Ionic compounds, acids, and bases can dissociate. NaCl dissociated in H2O Acids and Bases dissolve and dissociate in water. Chem II: 9.13 Infinite Campus Update: • Molarity vs. Molality Lab Objectives: • Chemical Reactions Exam • Address solubility rules misconceptions • Introduce Acidic and Basic Solutions Homework: • Enjoy the weekend! Ionic vs. Covalent Compounds • Most covalent compounds (exception: acids), will not dissociate in solvents. Ionic solution Covalent solution Electrolytes Electrolytes: Solutes that dissociate in solvents. Non-electrolytes: Solutes that do NOT dissociate in solvents. Net Ionic Equations Purpose: • Determines which ions actually react in a solution. Na2(CO3) + Ag(NO3) Na(NO3) + Ag2(CO3) Net Ionic Equations Spectator Ions: Do not participate in the reaction. “Watch the reaction only.” Chem II: 9/6/13 Objectives: • Gallery Walk: Activity Series, Solubility, Net Ionic Equations • Activity Series and Solubility Quiz • Address Chem I Exam and Enrichment Problem • Discuss Predicting Products in Synthesis and Decomposition Reactions (pgs. 276-280) Homework: • Predicting Products and Net Ionic Equation Wksht. (webpage) Net Ionic Equations KI + Pb(NO3)2 ----> PbI2 + K(NO3) 1. Balance the chemical equation and establish states of matter. 2. Re-write the equation emphasizing the ions in the reaction. 3. Cancel out spectator ions. 4. Re-write equation with ions that participate in the reaction. Gallery Walk • Activity Series Table (Single Replacement) • Solubility Table for Ionic Compounds • Establish Net Ionic Equations for Double Replacement Reactions Chem II: 9/9/13 Due: Acitivty Series and Solubility Lab Objectives: • I can predict products and states of matter for most chemical reactions. • I can establish Net Ionic Equations for Double Replacement Reactions. • Address Chem I exam and stoichiometry enrichment problem. • Assess Activity Series/Solubility Quiz • I can distinguish between moles and molarity. Chemical Reactions For each reaction: 1. Classify type of reaction 2. Predict products 3. Balance Equations 4. Predict states of matter for each substance. 5. If double replacement, establish net ionic equation. Synthesis Reactions • Oxides of active metals react with water to produce metal hydroxides. Ex. CaO (s) + H2O(l) -----> Ca(OH)2 (s) • Oxides of some non-metals react with water to produce oxyacids.(containing oxygen). Ex. SO2(g) + H2O (l) ----> H2(SO3) (aq) Decomposition Reactions • Decomposition of less active metal oxides: Ex. HgO (s) ----> Hg(l) + O2(l) (breaks into elements) • Decomposition of metal carbonates: Ex. Ca(CO3) --->CaO + O2 (metal oxide + CO2) • Decomposition of metal chlorates Ex. K(ClO3) (S) ----> KCl (S) + O2 (g) (metal chloride + O2) • Decomposition of metal hydroxides (reverse of synthesis) • Decomposition of acids (reverse of synthesis) Molarity Calculations 1. If a 3.5 L solution contains 0.5 moles sodium chloride, what is the solution’s molarity? 2. What is the molarity of a solution containing 5.85 g of KI dissolved in enough water to make 0.125L of solution? Chem II: 9/10/13 Objectives: • I can predict products and states of matter for most chemical reactions. • I can establish Net Ionic Equations for Double Replacement Reactions. • Address Chem I exam and stoichiometry enrichment problem. • I can distinguish between Molarity (M)) and Molality (m). Homework: Molarity vs. Molality Practice problems Molarity vs. Molality Lab: complete conclusion Chemical Reactions: Predicting Products Webpage Problems: *9. SO2 + H2O ----> Synthesis Reactions • Oxides of active metals react with water to produce metal hydroxides. Ex. CaO (s) + H2O(l) -----> Ca(OH)2 (s) • Oxides of non-metals react with water to produce oxyacids. Ex. SO2(g) + H2O (l) ----> H2(SO3) (aq) Chem I Review Exam Stoichiometry Lab: Enrichment Na(HCO3) + HCl NaCl + CO2 + H2O 1.Calculate the amount of 6M HCl (in mL) needed to sufficiently react with 2.0 grams of Na(HCO3). (Hint: Density of 6M HCl = 1.09 g/mL) Molarity Calculations Molarity vs. Molality Lab Background: One can calculate the concentration of a solution by molarity (M) or molality (m). Purpose: Understand the difference between molarity and molality through a lab application. Chem II: 9.11 Infinite Campus Update: • Activity Series/Solubility Lab (30 pts.) • Replacement Reaction Quiz (16pts.) Objectives: • Bell Ringer :Chemical Reactions • Distinguish between molarity and molality concentrations of solutions. • Address solubility rules misconceptions Homework: • Complete conclusion for Molarity vs. Molality Lab • Review chemical reaction material (exam 9.12) Bell Ringer: Chemical Reactions 1. Determine if the following reactions would occur. If so, predict products, balance equation, and establish states of matter for each substance in the reaction. a. Al + Sr(OH)2 ---> c. I2 + NaCl b. K + H2O ----> d. Cl2 + BaBr2 2. Classify each reaction, predict products, balance equations, and establish the state of matter for all substances in the reaction. a. Pb(NO3)4 + BaI2 -----> b. Mg(OH)2 -----> c. SO3 + H2O -----> d. Mn(ClO3)2 3. Establish the net ionic equation for the double replacement reaction in qts. 2. Molality Wksht Net Ionic Equations The first pair that can prove with written evidence that this double replacement reaction can be simplified will get a free homework pass and gator tag. Al(OH)3 + H(NO3) ---> Molarity vs. Molality Lab Chem II: 9.13 Infinite Campus Update: • Molarity vs. Molality Lab Objectives: • Chemical Reactions Exam • Address solubility rules misconceptions • Introduce Acidic and Basic Solutions Homework: • Enjoy the weekend! Chem II: 9.16 Infinite Campus Update: • Molarity vs. Molality Lab (12pts.) Objectives: • Address solubility rules misconceptions • Distinguish between suspensions, colloids, and solutions. • Introduce Acidic and Basic Solutions Homework: Bell Ringer: Mixtures Section: 12.1 1. a.Distinguish between homogenous mixtures and heterogenous mixtures. b. Give an example of each. 2. a. What is the difference between a suspension and a colloid and give an example of each. b. Classify each as a homogenous or heterogenous mixture. 3.a. What is the Tyndall Effect? b. How is it useful to scientists? Solubility “Like solvents dissolves like solutes” • Polar solvents dissolve polar solutes. Ex. salt water • Non-polar solvents dissolve non-polar solutes. Ex. oil-based paints dissolved in paint thinner. en.wikipedia.org Electronegativity and Polar Molecules Solubility Table • Overall very reliable (confirmed from lab). • Soluble: > 0.1M concentration of solute dissolved in solution. • Insoluble: < 0.0001M concentration of solute dissolved in solution. • Slightly soluble: between 0.0001M and 0.1 M of solute dissolved in solution. Soluble vs. Insoluble Substance C6H12O6 Mg(OH)2 Al(ClO3)3 H3(PO4) Ba(CO3) Soluble in water ? (aqueous) Dissociates in water? Bell Ringer: Mixtures Section: 12.1 1. a.Distinguish between homogenous mixtures and heterogenous mixtures. b. Give an example of each. 2. a. What is the difference between a suspension and a colloid and give an example of each. b. Classify each as a homogenous or heterogenous mixture. 4. a. What is the Tyndall Effect? b. How is it useful to scientists? Suspension vs. Colloids Suspensions: Colloids: Tyndall Effect When light is scattered by particles in a colloid, because they are not uniformly distributed. schools.birdville.k12.tx.us Acids and Bases • Define and illustrate the difference between an acid and a base. Acids and Bases dissolve and dissociate in water. Properties of Acids • Proton (H+) donors • Have a pH lower than 7. • Effects indicators ( blue litmus paper/ methyl orange) • Taste sour • Neutralizes bases Ex. HCl + Na(OH) ----> NaCl + H2O • Reacts with strong metals to produce H2 gas. Ex. Mg + HCl ---> MgCl2 + H2(g) Strong vs Weak Acids and Bases Strong Acids/Bases: Dissociates 100% in solution. Wead Acids/Bases: Dissocates less than 5% in solution. Weak Acid: H(NO2) Strong Acid: HCl www.chem.wisc.edu Properties of Bases • Proton (H+) acceptors. (OH)- + H+ ----> H2O • Have a pH higher than 7. • Effects indicators (red litmus paper/phenolphthalein) • Taste bitter and can feel slippery • Neutralizes acids Ex. Mg(OH)2 + HCl ----> MgCl2 + H2O Strength of Acids and Bases Predict whether or not each example below is classified as strong or weak. 1. HF 9. K(OH) 2. Na(OH) 10. Mg(OH)2 3. Ca(OH)2 4. H2(CO3) 5. H(C2H3O2) 6. H(NO3) 7. H2(SO4) 8. H3(PO4) Chem II: 9.17 Objectives: • Distinguish between suspensions, colloids, and solutions. • Classify strong and weak acids/bases. • Identify oxidation numbers in substances. Homework: Mixtures Classify the following as a solution, suspension, or colloid. a. sugar and water b. soluble starch and water c. clay and water d. food coloring and water e. sodium borate and water f. cooking oil and water g. gelatin and water h. 2% milk Strength of Acids and Bases Look over section 1 from Chpt 14 to validate if correct or not. 1. HCl 2. Na(OH) 3. Ca(OH) 4. H2(CO3) 5. H(C2H3O2) 6. H2(CO3) Strong Acids and Bases http://chem1180.blogspot.com Weak Acids and Bases Weak Bases: Weak Acids: • NH3 ammonia • HC2H3O2(acetic acid) • NH4(OH) ammonium • HF (hydrofluoric acid) hydroxide • HCN (hydrocyanic acid) • HNO2 (nitrous acid) • H2(CO3) (carbonic acid) Oxidation Numbers