Outline • Announcements • Heitman’s soil E method • Solute movement Soil Physics 2010 Announcements • Review sessions this week: • Noon today, Agronomy 1581 • Another one later? • Homework due Wednesday • Quiz? Soil Physics 2010 Heitman’s soil E method Key concept #1: q = 0.01 is small relative to measurement error, but LE for q = 0.01 is big S (heating the soil) Soil Physics 2010 Key concept #2: LE in the soil is about E, not ET LE (evaporation from the soil) Sensible heat balance can be used to estimate the latent heat (LE) used for evaporation. LE = (H1 – H2) – DS <0 Condensation =0 No net change >0 Evaporation Upper sensible heat flux H1 Sensible heat storage DS Lower sensible heat flux H2 Soil Physics 2010 LE Components of heat flow into / out of this thin layer: e, mm/day Heitman’s soil E method Stage I Stage II Stage III time Negligible in Stages II & III Liquid water flow up/down Soil temperature warming/cooling Phase change water evaporating / condensing Given by Fourier’s law Calculate by difference Soil Physics 2010 Heat Pulse (HP) sensors a heat-pulse sensor 0 mm C 1, k 1 T1 dT/dz1 H1 3 mm 6 mm C 2, k 2 1 2 T2 9 mm 12 mm DS dT/dz2 H2 3 T3 LE = (H1 – H2) – DS Soil heat flux: H = -k(dT/dz) Change in soil heat storage: DS = C (Dz) (dT/dt) Soil Physics 2010 Measuring heat flow into tiny layers T T Fourier: C k t z z Active C1 C2 k1 k2 Passive Dz1 Dz2 T1 Radiation Conduction T2 Convection Latent heat T3 LE = (H1 – H2) – DS Soil Physics 2010 T T → LE k C z z t HP probes installed in top 6 cm of bare field 6 cm In 2007 Summer Soil Physics 2010 In 2008 Summer Improved Heat Pulse probe (“Model T”) First used summer 2009 mm Side view 0 6 12 18 24 30 36 42 48 10 mm Soil Physics 2010 T (˚C) Temperature (T , °C) 80 0 mm 6 mm 12 mm 60 40 20 0 174 175 176 177 178 Day of year 2007 Soil Physics 2010 179 180 Temperature, Heat capacity, & Thermal conductivity T (˚C) 80 60 40 0 mm 6 mm 12 mm 0 3 1.2 C. (3-9 mm) . (3-9 mm) k 2 175 176 177 178 Day of year 2007 Soil Physics 2010 0.8 0.4 1 0 174 k (W m -1 ˚C -1) C (MJ m-3 ˚C -1) 20 179 0 180 Evaporation (mm/hr) Evaporation within soil layers 0.8 0.6 3-9 mm 1st depth 9-15 mm 2nd This is the “drying front” we’ve mentioned earlier – now actually observed. 15-21 mm 3rd 0.4 21-27 mm 4th 0.2 0 -0.2 174 175 176 177 178 179 180 Day of year 2007 Soil Physics 2010 Heitman, J.L., X. Xiao, R. Horton, and T. J. Sauer (2008), Sensible heat measurements indicating depth and magnitude of subsurface soil water evaporation, Water Resource Research 44, W00D05 Daily Evaporation (mm) Comparison of methods 4 Micro-lysimeter 3 Bowen ratio 2 y = 1.02 x - 0.05 2 R = 0.94 1 0 0 Soil Physics 2010 1 2 3 Daily Evaporation by HP (mm) 4 Heitman, J.L., X. Xiao, R. Horton, and T. J. Sauer (2008), Sensible heat measurements indicating depth and magnitude of subsurface soil water evaporation, Water Resource Research 44, W00D05 Solute Transport Flow Diffusion Convection Dispersion Soil Physics 2010 Steady-State Diffusion Under steady-state conditions we get a straight line, just as we did with Darcy’s law. C1 C0 Q D A L C1 C0 Soil Physics 2010 L just like Q = -KiA Transient diffusion For transient diffusion, we need to know the initial and boundary conditions. C C D 2 t x 2 Soil Physics 2010 C/C0 Suppose we have Ci = 0 x > 0, t = 0 C0 = 1 x = 0, t = 0 Ci = 0 x = ∞, t > 0 t0 Constant area t1 under curve (constant mass) t2 t3 x Breakthrough So, what if we had Ci = 0 x > 0, t = 0 C0 = 1 x = 0, t ≥ 0 Ci = 0 x = ∞, t > 0 Then at some distance x, C/C0 we’d see Soil Physics 2010 Constant concentration C0 = 1 Ci = 0 Solute mass increases with time This is called a Breakthrough Curve t Another breakthrough curve C/C0 x t0 t t1 t2 t3 Soil Physics 2010 Diffusion with Convection Sir Geoffrey Taylor examined a “slug” of dye traveling in a tube of flowing water (early 1950s). t0 t1 t2 v The slug moved at the mean water velocity, and it spread out but remained symmetrical. This seemed remarkable to Taylor. Soil Physics 2010 t3 Why was this remarkable? Taylor knew that water flowing through a tube has a parabolic velocity profile. Water in the center flows at twice the mean water velocity. The velocity profile is not symmetrical, but the dye slug was symmetrical. Soil Physics 2010