P h a s e C h a n g e I n s t r uc ti o n a l C a s e : A s er i e s o f s t u de n t -c e nt er e d s c i e nc e l es s o ns Lesson 3 Phase Change Stations Summary Students will rotate to different stations observing phase changes and recording their observations of states of matter and whether heat is being absorbed or released. Before moving to the next station, students place a post-it with the station number on one of six posters each labeled with one of the following phase changes: melting, freezing, condensation, vaporization, sublimation, or deposition. Objective(s) Suggested Timeline One to two 50-minute class periods Students explain the different ways matter can change states. Identify whether heat is being absorbed or released in particular phase changes. Materials Teacher Background Knowledge 9 sodium acetate heat packs (enough for each group of 4) 9 sticky notes for each student (one for each lab station) Coconut oil Isopropyl “rubbing” alcohol Dry ice – broken into pieces Ice chest and newspapers for storing dry ice Gloves for handling dry ice Ice pick or screwdriver for breaking pieces of dry ice Candle Quarter Cold can and room temperature can of soda 4 beakers Popsicle sticks 2 small trays 4 hot plates 2 watch glasses Frayer card Phase changes can be classified as either endothermic, in which a system absorbs energy from its surroundings, or exothermic, in which a system releases energy to its surroundings. In each case, the “system” is the substance undergoing the phase change. The endothermic phase transitions are melting (solid to liquid; also known as fusion), vaporization (liquid to gas), and sublimation (solid to gas). In each of these transitions, energy, in the form of heat, is going into breaking intermolecular attractions. Solids have the strongest intermolecular attractions, followed by liquids, and then, finally, by gases, in which intermolecular attractions are so small that they are often ignored. The final state of the substance has weaker attractions between the particles than the initial state. The exothermic phase transitions are essentially the opposites of the endothermic ones: freezing (liquid to solid), condensation (gas to liquid), and deposition (gas to solid). This lesson features examples of all six phase changes so that students can compare and contrast them readily. Additionally, students see these phase changes with substances other than water, i.e. the freezing of wax. Students may encounter difficulties in classifying the processes as endothermic and exothermic. This is often because they incorrectly define the “system” in the problem. For example, the vaporization of alcohol is an endothermic process; it takes energy to break the intermolecular attractions between alcohol molecules so that they can enter the vapor phase. Frayer Card Phase Change Instructional Case Lesson 3 Page 2 of 5 Lesson 3 Phase Change Stations Prior Knowledge Teacher Background Knowledge (continued) In grades 3-5, students have learned that moving objects contain energy. The faster the object moves, the more energy it has. When alcohol evaporates from our skin, we feel cold. That is because we are the “surroundings”; the alcohol is the “system.” The alcohol is absorbing energy from us, so its vaporization is endothermic. Students often recognize endothermic processes more readily than exothermic processes because they associate them with the presence of a specific heat source, whereas the heat released in an exothermic reaction is diffuse and not seen as a specific quantity. For example, they may know vaporization as endothermic, but not think of condensation as exothermic. Therefore, it may help to guide students when unsure if a process is endothermic or exothermic to try classifying the opposite process first. Students learned in the previous lesson that liquids and gases move faster at higher temperatures and solids expand. They also learn that there is no increase in mass when temperature increases. Possible Modifications: The number of stations may be reduced, but there should be at least one station for each of the six phase changes. Additional optional stations could be a “Drinking bird” apparatus (evaporation), solid iodine (sublimation), or distillation apparatus (vaporization and condensation). Prep 1. Obtain dry ice the night before or morning of and store in freezer wrapped in newspaper. Around the room, hang posters labeled with the following terms and descriptions: Melting (solid to liquid), Freezing (liquid to solid), Vaporization (liquid to gas); Condensation (gas to liquid), Sublimation (solid to gas), Deposition (gas to solid) 2. Prepare the following stations: Station #1 Coconut oil (melting) Place watch glass on warm hotplate. Provide a container of coconut oil with a popsicle stick for placing on watch glass. Station #2 Watch glass (condensation) Place watch glass on beaker of water on hotplate. Station #3 Evaporating alcohol in hand (vaporization) Provide dropper bottle of alcohol. Station #4 Dry ice (sublimation) dry ice in tray. Station #5 Cooling wax (freezing) Light candle, and provide popsicle stick and paper for placing wax. Station #6 Quarter on dry ice (deposition) Provide quarter and dry ice in tray. Station#7 Boiling water (vaporization) Boil water on hotplate. Station #8 Hot pack (freezing) Provide sodium acetate hot packs, and have hot water for “recharging” packs Station #9 Cold soda and room temperature can of soda (condensation) Provide can of cold soda. 3. After each class period, the sodium acetate hot packs will need to be “recharged” (melted) by putting them in hot water on a hot plate, removing them from the hot water, and letting them cool for several minutes. This creates a supersaturated solution that will turn solid (freeze) when the disk is clicked starting the crystallization process of the dissolved sodium acetate. You should have enough sodium acetate packets ready for each lab team each period. Be sure to instruct students to use only one per lab team so there are enough for all lab teams each period 4. Give each lab group 9 sticky notes. Page 3 of 5 Lesson 3 Phase Change Stations Standards 12 NGSS Performance Expectations: This lesson supports students in progressing toward the NGSS Performance Expectation. MS-PS 1-4: Develop a model that predicts and describes changes in particle motion, temperature, and state of a pure substance when thermal energy is added or removed. Emphasis is on qualitative molecular-level models of solids, liquids, and gases to show that adding or removing thermal energy increases or decreases kinetic energy of the particles until a change of state occurs. Examples of models could include drawings and diagrams. Examples of particles could include molecules or inert atoms. Examples of pure substances could include water, carbon dioxide, and helium. MS-PS 1-5: Develop and use a model to describe how the total number of atoms does not change in a chemical reaction and thus mass is conserved. Emphasis is on law of conservation of matter and on physical models or drawings, including digital forms that represent atoms. Assessment Boundaries: Assessment does not include the use of atomic masses, balancing symbolic equations, or intermolecular forces. In this lesson… Science and Engineering Practices Analyzing and Interpreting Data: Analyze and interpret data to determine similarities in findings. Observe patterns between the different phase changes. Analyze and interpret data to provide evidence for the phenomena of phase change. 1 Disciplinary Core Ideas Cross Cutting Concepts PS3.A: Definitions of Energy Cause and Effect The term “heat” as used in everyday language refers both to thermal energy (the motion of atoms or molecules within a substance) and the transfer of that thermal energy from one object to another. Heat is referred to the energy transferred due to the temperature difference between two objects. Observe the changes that occur when different materials are heated and cooled. Observe the relationship between temperature and phase change Energy and Matter Use the information about the relationship of phase change and temperature to assess whether heat energy has been absorbed or released. The transfer of energy can be tracked through each phase change. NGSS Lead States. 2013. Next Generation Science Standards: For States, By States. Washington, D.C.: The National Academies Press. 2 National Governors Association Center for Best Practices, Council of Chief State School Officers Title: Common Core State Standards (insert specific content area if you are using only one) Publisher: National Governors Association Center for Best Practices, Council of Chief State School Officers, Washington D.C. Copyright Date: 2010 Page 4 of 5 Lesson 3 Phase Change Stations In this lesson… CCSS Mathematics CCSS English-Language Arts n/a RST 6-8.9 Compare and contrast the information gained from the experiments with the different materials and substances. Compare/contrast with information gained from reading a text on the same topic. Lesson Station 1: 1. Establish connection to previous lesson i.e. “Yesterday we looked at the characteristics of solids, liquids, and gases. Now we are going to look at what happens when changing between phases (solid, liquid, or gas).” 2. Have students rotate between stations. They will need about 5 minutes per station to record their observations, discuss which two states they are observing, decide which phase change they are observing and explain their rationale. They then label their sticky notes with the station number and place the sticky note on the appropriate poster. Sticky notes should form a bar graph on each poster, with sticky notes of the same station number placed on top of the other. 3. After students have rotated through each station, debrief as a class. Ask for volunteers to explain why they classified stations as they did. Possible Questions: Which station(s) were the most difficult to figure out? Why? Why do phase changes take place? What phase changes were similar or related in some way? How? In what phase changes was heat being released? Absorbed? 4. Hand out Frayer model cards. Complete one or two as models for the class, and have groups continue to complete a Frayer card for each phase change process. Page 5 of 5 Lesson 3 Phase Change Stations Potential Pitfalls Understand that heat (or more correctly, energy) is always absorbed or released in a phase change even if the addition or removal of heat is not felt. The reusable sodium acetate heat packs, for example, absorb heat when “recharged” in hot water and release heat when clicking of the metal disk initiates the freezing process (solid sodium acetate crystals forming). Students will likely be challenged with the idea that freezing released heat. An in-depth discussion of the observations made at different stations will be beneficial in clarifying this for students. Example: “If melting is the opposite of freezing, and a substance is absorbing “heat” when it melts, what happens when a substance freezes? Which station clearly demonstrated heat being released in the freezing process? (hot packs).” Or, “Why might we not feel the heat being released when water freezes? (there is less heat released). Why does an ice cube feel cold when we touch it? (It is absorbing heat from our hand).” It is important that students spend time thinking through that ice feeling cold does not contradict a release of “heat” (energy) in the freezing process, since these are two different things. Additionally, although scientists correctly use “heat” as a verb, we feel it is okay at this point in student understanding to use “heat” as noun since students may not have yet been introduced to the term energy. Technically, however, it is energy that is transferred in a phase change. Heat is a transfer of energy.