GONDWANA BASINSPOTENTIAL STORAGE SITE FOR CO2 By G. Mukhopadhyay Geological Survey of India CARBON SEQUESTRATION CAPTURE TRANSPORTATION INJECTION OF CO2 INTO FAVORABLE SITES POST INJECTION MONITORING Overview of Geological Storage Options Produced oil or gas Injected CO2 Stored CO2 Basalt Deep seated coal seam as a a sink of CO2 with enhanced CBM recovery Depleted oil and gas reservoirs Deep saline aquifers- onshore Enhanced oil and gas recovery Deep saline aquifers- offshore FIELD EXPERIENCE- US 1. 2. 3. 4. 5. 6. 7. 8. Allison CO2-ECBM Pilot Location- San Juan basin Producer well—16 Injector well—4 Average depth to top coal - 3100 feet Permeability 100md Initial pressure – 1650 psi Temp. – 160oF OBSERVATION 1. CO2 injection improved methane recovery from 77% to 95% of OGPI 2. Ratio of injected CO2 to produced CH4-3:1 FIELD EXPERIENCE- CANADA 1. Alberta Research Council 2. Location- Fenn BIG Valley, Alberta Province 3. Producer well—1 4. Injector well—1 OBSERVATION 1. injectivity improves with continued CO2 injection and methane production FIELD EXPERIENCE- JAPAN 1. 2. 3. 4. Operated by JCOAL Location- Yubari site, Ishikari Coalfield Producer well—1 Injector well—1 OBSERVATION 1. Gradual increase of injection rate –may be due to decrease in effective stress near injection well area. 2. 90% of injected CO2 stored in coal seams 3. Gas production increase with CO2 injection, and dropped after injection was stopped- indicating ECBM effect 92° 96° m 68° 76° 72° m m 84° 80° m m 88° m 92° m 100 96° m 0 m 100 k m m 36° m 36° COALFIELDS AND LIGNITE OCCURRENCES OF INDIA 1 %Srin agar 2 3 4 500 0 500 km Kilometers m 32° 1 28°m Itanagar Sim la % Gangtok Chan digarh % 28° 24 6 m 28° New Del hi % 8 5 6 12 10 7 13 18 14 17 15 11 9 16 21 19 22 20 24 23 25 28 27 26 29 30 31 32 33 34 2 1 8 3 4 Gan gtok 25 % Jai pur % 24 % Itanagar Dispur 6 5 7 26 Lucknow 8 % Di spur 22 Patna % 20 21 24° % 9 % 35 10 18 17 % 15 14 12 11 13 16 10 Im phal % 22 m 24° 38 39 37 41 40 45 42 47 48 43 51 44 46 49 50 51 63 61 59 60 42 37 % Agartala 28 29 38 40 35 17 21 Im phal 16 % 65 75 % 13 18 Cal cu tta % 53 52 67 54 74 68 Tertiary Coalfields 20° 73 72 # Lignite Occurr ences % 3. Ma kum 4. D illi - Jey por e 5. Tiru % Mum bai 6. B or ja n # 1. Nichaho m Baram ul a 2. Nagbal 36. Jali pa 37. Lakhpat 3, 4. Firozpur Sh al ig an ga 5. Khari 38. Dhedadi 39. P ranpur # # # # # 6. Gangashahr 40. Kaiyari 7, 8. Sarup Desar 9. Kol ayat 41. P anandhro 42. Akhrim ota # # # Gond wana Coalfields 70 % 68 67 69 # # 43. Fu lradam # 44. Um arsar 45. M udia # # 13. M an dal Charn an 46. M ata No Madh 14. Raneri 15. Hira Ki Dhani 47. Jul arai 48. Waghapadar # # # # # # # % # # # # # 16. Lal amdesar 17. Bar S ing hsar 49. Lefri # # # 18. P alana # 50. Haml a 51. Nanaratad ia # # # 19. Kasnau 12°20. Kuchera # # 52. Lakhanka Kharsal ia 21. Nim bri 53. Bhuri 54. S hah V astan 22. M arw ar Chapri 23. Butati 55. Ratnagiri 56. Nil eswaram 24. M erta Road 57. M ad ayi # # # # # # 25. Hansiyas 26. Gangard a # # 60. Jayamkond a Chol ap uram 61. Lal pettai 62. S rim ushnam 30. Nagarda 63. Neyvel i Sou th 31. Nim la 64. Bhuban giri 65. Neyvel i East 8° 32. Bharka 33. Botiya 34. Hami r j i ki Dhani 35. Kapurdi Chen nai % % # # # 63 62 66 65 60 64 61 59 58 66. Bahur Trivandrum % 67, 68, 69. Elu ru - Raj am un 70. Dom ra m 72° # # 56 57 58. Warkala 59. M an nargudi 27. Lam ba Jatan 28. M okal a 29. I ndawar # Bang al ore # # # 22. Singrima ri 52. 23. Abor H ills 53. 24. Daphla H ills 54. 25. Aka H ills 55. 26. Dar je eling 56. 27. Rajma ha l 57. 28. Birbhum 58. 29. Ta ngsuli 59. 30. Kundait Ka riah 60. 31. Saharjuri 61. 32. Jainti 62. 33-3 4. Giridih 63. 35. Raniga nj 64. 36. Bar jor a 65. 37. Jharia 66. 38. East Bok aro 67. 39. We st Boka ro 68. 40. Ram ga rh 69. 41. North Kar anpur a 70. 42. South K ar anpur a 71. 43. Chope 72. 44. Itk hori 73. 45. Aur anga 74. 46. Hutar 75. 47. Daltonga nj 76. 48-4 9-50 . Tatapa ni-Ra mkola 77. 51. Singrauli 78. Korar Uma ria Johilla Sohagpur Sonhat-J hilim ili Bisra mpur La khanpur Panchba hini Dhama munda Korea garh Chir im iri Sendur ga rh Has do-Ar and Korba Mand- Raigarh Ib River Ta lc he r Godava ri Yelle ndu Wa rdha Bander Umr er Kam pte e Pench K anhan Pathakhe ra Ta wa Mohpani # # # # # # % 24° 7. Tuen Sa ng 8. J ha nzi-D is ai 69 Hyderabad 55 # 10. Gura 11. Chaneri 12. Bithno k m 20° 1. Miao-bum 2. N amc hik - Na mphuk Bhu baneswar 71 # m 12. Pynur sia 13. Cherr apunji m 84° Tertiary Coalfields 1. Miao-bum 2. Namchik-Namphuk 3. Makum 4. Dilli-Jeypore 5. Tiju 6. Borjan 7. Tuen Sang 8. Jhanzi-Disai 9. Koilajan 10. Diphu 11. Bapung 12. Pynursla 13. Cher rapunji 14. Laitryngew 15. Maw synr am 16. Maw long Shella 17. Langrin 18. Balphakram-Pendenggru 19. West Darangiri 20. Rongr enggri 21. Siju m 24° 14. La itr ynge w # # # 15. Mawsy nr am 16. Mawlong S he lla Gondwana Coalfields # # # # # # # # # 17. La ngrin Calcutta 18. Balpha kr am - Pendenggru 19. We st Da ranggir i 22. 23. 24. 25. % 20. Rongr enggri 21. Siju 79. Kalak ot - Mahoga la m 12° Singrim ari Abor Hills Daphla Hills Aka Hills # m # # 50 0 # 0 50 0 kmK ilo m e te r s m 88° 84° m 92° # # # # 80° # # 84° m # 88° m m # 26 Tertiary coalfields # Luc know m 8° # # % # m 80° % m 16° # m 76° Agartala Aizawl 9. K oilajan 10. Diphu 11. Bapung Kohim a Shillong 11 % 15 14 12 Shillong 19 % 36 66 20 Aizawl # 70 58 64 76 39 45 41 46 57 62 55 78 77 32 27 34 33 31 30 44 43 47 50 56 54 % % 48 49 52 53 Bho pal Gan dhin agar 9 Koh im a % Shi llo ng 19 5 7 23 36 2 3 4 % 25 % 16° m28° 23 79 32° m 88° m 92° # # # # # # # 22 Patna # # Bangladesh % # # # # # # # # # 27 51 47 24° m 52 Bhopa l 53 % 56 33 41 39 42 40 38 45 57 32 34 37 61 60 31 28 30 35 29 m24° Calcutta % 66 Jamalganj 65 76 75 67 74 68 73 72 Bhuba ne sw ar % 20° 71 m 69 Hydera ba d % 70 16 ° m m 80 ° Barapukuria Dighipara 36 58 64 63 77 48 46 59 62 78 Lower Gondwana Coalfields 55 54 49 50 44 43 22 . S i n g ri ma r i 26 . D a rj e e lin g 27 . R a jm a h a l 28 . B i rb h u m 29 . T a n gs u li 30 . K u n d a it K a r ia h 31 . S a h a r ju ri 32 . J a in ti 33 ,3 4 . G i ri d ih m 84 ° 51 . 52 . 53 . 54 . 55 . 56 . 57 . 58 . 59 . 60 . 61 . 62 . 63 . 64 . 65 . 66 . 67 . 68 . 69 . 70 . 71 . 72 . 73 . 74 . 75 . 76 . 77 . 78 . S i n g ra u li Korar U m a ri a J o hi la S i h a gp u r S o n h a t-J h il im il i B i sr a m pu r L a kh a n p u r 20° P a n c hb a h in i m D h a m am u n d a K o r e a ga r h C h ir im i ri S e n d u rg a r h H a sd o - A ra n d Korba M a n d -R a ig a r h Ib R iv e r T a lch e r G od a v ar i Y e l le n d u W a rd h a Bander U m re r K a m p te e P e n c h- K a n h a n P a th a kh e r a T a wa M o h p a ni 35 . R a n ig a n j 36 . B a r jo r a 37 . J h ar ia 38 . E a s t B o ka ro 39 . W e st B o k ar o 40 . R a m g ar h 41 . N o rth K a r a n p ur a 42 . S o u th K a r an p u r a 43 . C h o p e 44 . Itk h or i 45 . A u r a n ga 46 . H u ta r 47 . D a lto n g a n j 48 ,4 9 ,5 0 . Ta ta p a n i- Ra m k ol a m 88 ° m16° Coal Resource base Proved 99.06 b.t 257b. t. (up to 1200m depth) Proved Indicated Inferred 39% Inferred 38.14 b.t 49% 12% 16% Indicated 120.18 b.t Power grade coal: 155.8 b. t. (60%) (up to 1200m depth) 36% 48% 7% 42% Quality-wise break-up of Non-coking coal 51% 250 (87%) 200 160 140 224.08 155.81 120 150 100 80 100 50 0 60 40 (12.6%) 20 32.35 Coking 0.94 Non-Coking High sulphur 35.67 32.5 0 Superior Power grade Ungraded Indian coal resource is expressed in terms of : Depth Range from surface 156.6 (in billion tonnes) 160 140 120 100 67.6 80 60 18.9 14.2 40 20 0 0 – 300m 0 – 600m 300m – 600m 600m – 1200m Jharia CF only Resource up to 1200m depth considered for National Inventory. COALFIELDS OF INDIA RAJMAHAL – BIRBHUM MASTER BASIN RANIGANJ BASIN WARDHA –PRANHITA – GODAVARI BASIN Important geological locales for storage 1. large aerial extent. 2. Coal seams ( > 50m) occur beyond 1.0 Km depth. 3. Thick Cap rock. CBM 4. Close proximity with the thermal power stations and other industrial activities. blocks are allotted in these coalfields. LITHOSTRATIGRAPHY OF SOME GONDWANA BASINS OF INDIA Godavari 0.0 Km Deccan Trap Chikiala Kota Damodar Rajmahal Supra-Panchet Rajmahal Trap Dubrajpur Panchet Up. Kamthi 2.0 Km Panchet Maleri Raniganj Raniganj Md. Kamthi Barren Measures Lr. Kamthi 4.0 Km Barakar Barren Measures Barakar Barakar Talchir Talchir SEAL ROCK Barren Measures Talchir COAL SEAM A RCM-9 888.83 Salanpur-A Seam(61.97m) 967.75m B Chalbalpur-Mahismura GEOLOGICAL SECTION ALONG A - B RCM-9 PROJECTED BOREHOLE RCM -9 Barakar coal occur beyond 1200m 888.83 61.97 m 967.75m 2500m A RCM-9 Area having Coal seams below 1200m B Prognosticated coal resource below 1200m depth – 30BT (Area700sq km;Av. Coal thicness – 30m) GENERALISED STRATIGRAPHIC SUCCESSION OF DEEPER PART OF RANIGANJ BASIN ( A CASE HISTORY OF MULTI-LAYER TRAP AND RESERVOIR ROCKS) 0 Km SUPRAPANCHET (coarse clastic) 600m PANCHET (Intercalated shale-sandstone) 600m 1 Km RANIGANJ (coal bearing sand-dominated) upto 1100m Barren Measures (shale dominated -upto 90%) 800m Barakar (coal bearing sand-dominated) upto 800m 2.5 Km CAP ROCK CO2 storage capacity – 600 MT RESERVOIR ROCK COAL SEAMS TALCHIR FORMATION Pachami DPD-2 GEOLOGICAL MAP OF RAJMAHALBIRBHUM COALFIELDS GEOLOGICAL MAP OF RAJMAHAL AND BIRBHUM COALFIELDS JHARKHAND AND WEST BENGAL 87°00' 87°10' 87°20' 87°30' 87°40' 87°50' 10 88°00' 0 10 km 25°20' 25°20' Pirpainti RS. Sahibganj Kahalgaon Bara 25°10' 25°10' Mahagama HURA Phulberia 25°00' Rajmahal RS. 25°00' Simra Berhait Barharwa Hansdiha 24°50' 24°50' Pakur 24°40' 24°40' URMAPAHARITOLA Amrapara 24°30' 24°30' Gopikandar 24°20' CHAUDHARGARIAPANI Katikund Ongoing blocks Completed blocks Proposedblock Saldaha Dumka 24°10' Alluvium Rajmahal Formation Upper Gondwanas Lower Gondwanas Metamorphics 87°00' 87°10' 24°20' SAHARPURJAMARPANI LEGEND Rampurhat KULKULIDANGALSITASAL BORTALAMATHURAPUR RAMPURMALLARPUR 87°20' 87°30' 24°10' Fatehpur Khargram 87°40' 87°50' 88°00' 755.10 64.04 m Trap thickness increases generally towards east Maximum Trap thickness recorded –370m in southeastern part of the basin 940.45m TECTONIC MAP OF RAJMAHAL BASIN ( EASTERN PART ) 88° 50 0 0 50 0 kmK ilo m e te r s 80° 84° m 88° m m 26 Luc know % 26° 22 Patna % CDN-40 27 51 47 24° m 52 Purnia Bhopa l 53 % 55 54 56 44 43 48 46 45 32 34 33 41 39 42 40 57 59 62 63 61 60 78 77 49 50 38 37 31 28 30 35 29 m24° 36 58 64 Calcutta % 66 65 76 Raiganj Kathar 75 Y Dinajpu r 67 74 68 73 72 Bhuba ne sw ar % 20° 71 m 69 Hydera ba d % 70 1500m 16 ° m m 80 ° 22 . S i n g ri ma r i 26 . D a rj e e lin g 27 . R a jm a h a l 28 . B i rb h u m 29 . T a n gs u li 30 . K u n d a it K a r ia h 31 . S a h a r ju ri 32 . J a in ti 33 ,3 4 . G i ri d ih m 84 ° 51 . 52 . 53 . 54 . 55 . 56 . 57 . 58 . 59 . 60 . 61 . 62 . 63 . 64 . 65 . 66 . 67 . 68 . 69 . 70 . 71 . 72 . 73 . 74 . 75 . 76 . 77 . 78 . S i n g ra u li Korar U m a ri a J o hi la S i h a gp u r S o n h a t-J h il im il i B i sr a m pu r L a kh a n p u r 20° P a n c hb a h in i m D h a m am u n d a K o r e a ga r h C h ir im i ri S e n d u rg a r h H a sd o - A ra n d Korba M a n d -R a ig a r h Ib R iv e r T a lch e r G od a v ar i Y e l le n d u W a rd h a Bander U m re r K a m p te e P e n c h- K a n h a n P a th a kh e r a T a wa M o h p a ni 35 . R a n ig a n j 36 . B a r jo r a 37 . J h ar ia 38 . E a s t B o ka ro 39 . W e st B o k ar o 40 . R a m g ar h 41 . N o rth K a r a n p ur a 42 . S o u th K a r an p u r a 43 . C h o p e 44 . Itk h or i 45 . A u r a n ga 46 . H u ta r 47 . D a lto n g a n j 48 ,4 9 ,5 0 . Ta ta p a n i- Ra m k ol a m16° m 88 ° Sahibganj 25° X HURA Murshidabad 88° INDEX Alluvium Rajmahal Trap Lower Gondwana Metamorphics Borehole GEOLOGICAL SECTION ALONG X – Y IN RAJMAHAL BASIN X Y CDN - 40 Tertiary Dubrajpur 25m 50m Panchet 64.04 m 755.10 1 Km 940.45m 653m 1220m Raniganj Reservoir Area 3000sq km (appx) Av. Coal thickness 30m Barren Measures Barakar Prognosticated Resources – 135 B 2 Km 0 Km 3 Km Talchir CO2 storage capacity 5000 MT 150 Km Ramagundem GENERALISED STRATIGRAPHIC SUCCESSION OF GODAVARI BASIN 0 Km DECCAN TRAP- upto 250m ( A CASE HISTORY OF DOUBLE-LAYER TRAP AND RESERVOIR ROCKS) GANGARAMPUR / CHIKIALA –sand dominated- 150m KOTA –mostly sand dominated500m UPPER KAMTHI coarse clastic dominated- 600m MALERI / MIDDLE KAMTHI –mud dominated - upto 700m 2 Km LOWER KAMTHI – sand dominated BARREN MEASURES-intercalated sand-mud-upto 500m Barakar (coal- Sand bearing sand-dominated) upto 350m BARAKAR dominated 350m TALCHIR –sand-mud intercalation- upto 500m 4 Km Area 300sq km Av. Coal thickness 5m Prog. Resource 20 BT CO2 storage capacity 800MT CAP ROCK RESERVOIR ROCK BARAKAR COAL SEAMS TALCHIR FORMATION 3 2 Coal basin Reservoir area(sq km) Av. Coal (m) Resource Capacity (BT) (MT) Raniganj 700 30 30 600 Rajmahal 3000 30 135 5000 Godavari 3000 5 20 800 Total 6700 185 6400 COAL WING OF GSI WITH ITS RICH AND ROBUST GEOSCIENTIFIC DATABASE ( SURFACE AND SUBSURFACE) ON ALL COAL BASINS OF INDIA AND HAVING ADEQUATE EXPERTISE IN FIELD AND LABORATORY STUDIES IS CAPABLE TO DELINEATE THE SUITABLE SITES FOR CO2 STORAGE IN DEEP SEATED UNMINABLE COAL SEAMS AND ASSOCIATED PERMEABLE AND IMPERMEABLE ROCKS CONSIDERING ALL GEOLOGICAL FACTORS Collaborative work to be performed by coal wing, GSI; CMFRI and Foreign Agencies/Institutions NATURE OF WORKS • DELINEATION OF BASIN WISE AREAS WITH COAL RESOURCE OCCURING BELOW 1200m DEPTH • DETAILED STUDY OF FAULT AND FRACTURE PATTERN • COAL PETROGRAPHY INCLUDING DETAILED STUDY OF CLEAT PATTERN • PHYSICOCHEMICAL CHARACTER OF ROCKS • PHYSICO-MECHANICAL PROPERTIES OF COAL • DESORPTION OF CH4 AND SORPTION OF CO2 CHARACTER OF COAL