Aim: What is Titration? Do Now: Complete and balance the following neutralization reactions: Neutralization: When _____________ and ______________ solutions are mixed, the ____ of the acid and the _____ of the base combine to form __________. The _________ of the acid and the _____________ of the base come together to form a _________. This is a simple ______________________________ reaction. One mole of _____ ions exactly neutralizes one mole of _____ ions. _________ + _________ _________ + ___________ 1. Hydrochloric acid is neutralized by sodium hydroxide. 2. Sulfuric acid is added to potassium hydroxide. 3. Nitric acid and calcium hydroxide undergo a neutralization reaction. Titration: __________________________________________________ __________________________________________________________ Formula: Titration Procedure: (Unknown base concentration) 1. Put a certain volume of the base into a ______________. 2. Place a certain volume of standardized solution acid with some _______________________ indicator into an Erlenmeyer flask. 3) Add the base to the acid _______________ until the _______________ just begins to turn color. 4) Record the _______________ of the base necessary to _______________ the acid. 5) Plug all known values into the formula and solve for MB. Equivalence Point _________________ occurs at the equivalence point when the moles ______ = moles _______ Endpoint The endpoint occurs when the ________________ change color. The best indicators give an endpoint close to the equivalence point. Example: If 20.0 mL of 1.5 M HCl is neutralized by 35.0 mL of NaOH. What is the molarity of the base? Titration Practice 1. How many milliliters of a 2.5M HCl solution are required to exactly neutralize 1500mL of a 5.0M NaOH solution? 2. How many milliliters of a .2M HCl solution are required to neutralize 100mL of a .4M KOH solution? 3. How many mL of a .100M NaOH solution are required to neutralize 20.0mL of a .200M HCl solution? Monoprotic vs. Diprotic vs. Triprotic Monoprotic Acids: Diprotic Acids: Triprotic Acids: Each mole of Each mole of diprotic Each mole of triprotic monoprotic acid acid produces ____ acid produces ____ produces ____ mole of mole of H+ ions. mole of H+ ions. H+ ions. Example: Example: Example: We need to modify the titration equation when dealing with ___________ and ___________ acids. Let Let nA = moles of H+ produced per mole of acid. For HCl nA = _______ For H2SO4 nA = _______ For H3PO4 nA = _______ Let nB = moles of OH- produced per mole of base. For Ca(OH)2 nB = _______ For Al(OH)3 nB = _______ Titration equation for diprotic and triprotic acids: Practice: 1) 50.0 mL of 2.0 M NaOH neutralizes 25.0 mL of HCl. What is the concentration of the HCl solution? 2) 50.0 mL of 1.5 M H2SO4 neutralizes a 2.0 M sample of NaOH. What volume of NaOH was neutralized? Aim: What is Hydrolysis? Strong Acids Weak Acids Strong Bases Weak Bases Strong Acid + Strong Base ________________ Strong Acid + Weak Base _________________ Weak Acid + Strong Base _________________ Weak Acid + Weak Base __________________ General Equation: Salt + Water Acid + Base Examples: Complete the equations for each hydrolysis reaction. Determine whether the following solutions will be acidic, basic, or neutral. 1. NaCl(aq) + H2O 2. KC2H3O2(aq) + H2O 3. NaF(aq) + H2O 4. NH4Cl + H2O 5. AlCl3(aq) + H2O