Solution- homogenous mixture Solutesubstance being dissolved Solventthe dissolving medium Solubilitythe amount of solute that will dissolve in a given amount of solvent at a given temperature Can you filter a solution? No What is a suspension? Can you filter a suspension? Yes Saturated solution- contains the maximum amount of solute Unsaturated solutioncontains less than the maximum amount of solute, can dissolve more solute Supersaturated solutioncontains more than the maximum amount of solute, prepared by heating SUPERSATURATED SOLUTIONS Videohttps://www.youtube.com/watch?v=0wif FbGDv4I https://www.youtube.com/watch?v=mxO9rtVj oR4 Electrolyte- solution that will conduct electricity Nonelectrolytesolution that will not conduct electricity What type of compounds are electrolytes? ionic compounds, acids, bases What type of compounds are nonelectrolytes? covalent compounds What happens to ionic compounds when they are dissolved in water? break apart into ions Write the dissociation reaction for: NaCl(s) → NaCl(s) → Na+(aq) + Cl-(aq) KNO3(s) → KNO3(s) → K+(aq) + NO3-(aq) Al(NO3)3(s) → Al(NO3)3(s) → Al+3(aq) + 3 NO3-(aq) EXAMPLES OF SOLUTIONS Solid dissolved in a liquid Kool-Aid/sweet tea Gas dissolved in a liquid Coke Liquid dissolved in a liquid Vinegar Gas dissolved in a gas Air Solid dissolved in a solid Jewelry; metal alloys EFFECTS OF TEMPERATURE ON SOLUBILITY Solids dissolved in liquids – (Ex: sweet tea) solubility increases as the temperature increases Gases dissolved in liquids – (Ex: soda) solubility decreases as the temperature increases EFFECTS OF PRESSURE ON SOLUBILITY Gases only (Ex: soda) solubility increases as pressure increases SOLUBILITY CURVE LIKE DISSOLVES LIKE Polar compounds will dissolve polar compounds (and ionic) Nonpolar compounds will dissolve nonpolar compounds Alcohols will dissolve polar and nonpolar but NOT ionic. SALT DISSOLVING IN WATER Polar Solvents Nonpolar Solvents H2O CCl4 NH3 Oil Benzene (C6H6) Miscible – will mix (dissolve) Immiscible – will not mix VIDEO https://www.youtube.com/watch?v=JE4pwRD8t9Q ARE THE FOLLOWING MISCIBLE OR IMMISCIBLE? Oil and water? immiscible Oil and CCl4? miscible Water and CCl4? immiscible Oil and benzene? miscible UNITS OF CONCENTRATION Explain the difference between a concentrated and a dilute solution. Molarity (M) = What does 0.100 M HCl tell you? PRACTICE 1. Calculate the molarity of a solution if 3.00 moles of sugar are dissolved in 1.0 L of solution. 3.0 M PRACTICE 2. Calculate the molarity of a solution made by dissolving 125 g of C12H22O11 in 1.50 L of solution. 0.243 M PRACTICE 3. How many g of NaOH are contained in 1500. ml of a 0.330 M solution? 19.8 g DILUTION Adding water to a solution will dilute the solution and the molarity _____________but the # of moles of solute ________ M1V1 = M2V2 PRACTICE 1. What volume of 10.0 M NaOH is needed to prepare 1000. ml of a 0.100 M NaOH solution? 10.0 ml PRACTICE 2. What is the molarity of an acid solution if 12.5 ml of a 6.00 M solution is diluted to a final volume of 500. ml? 0.15 M PRACTICE 3. If 100 ml of water are added to 50 ml of a 12 M HCl solution, what is the molarity of the diluted solution? 4.0 M PERCENT BY MASS % solute = g solute g solution x 100 PRACTICE 1. Calculate the % of sugar in a solution made by dissolving 25.0 g of sugar in 100. g of water. 20.0 % PRACTICE 2. How many g of sugar are contained in 325 g of a solution that is 8.55 % sugar? 27.8 g PRACTICE 3. How many grams of solution are needed to have 36.5 g of sugar in a solution that is 15.0 % sugar? 243 g SOLUTION STOICHIOMETRY 1. What volume of 0.100 M HCl is needed to neutralize 25.0 ml of a 0.350 M NaOH solution? CONT. 2. Pb(NO3)2 + 37.5 ml 0.500 M 2 KCl → 2KNO3 + PbCl2 28.0 ml M=? 3. Ba(NO3)2 + Na2SO4 → BaSO4 + 2NaNO3. How many grams of BaSO4 are produced by the reaction of 43.7 ml of 0.650 M Ba(NO3)2? 4. How many grams of Ag2CrO4 are produced by reacting 75.5 ml of 0.100 M AgNO3 according to the equation: 2 AgNO3 + K2CrO4 → Ag2CrO4 + 2KNO3 NET IONIC EQUATIONS Precipitation reactions – two solutions are mixed and form a precipitate (solid) To determine what forms a precipitate use the solubility rules in your packet. Soluble – dissolves in water, exists as ____________ (aq) Ex: KBr Insoluble – does not dissolve, remains a _____________ (s) PRECIPITATES SOLUBLE OR INSOLUBLE? 1. KNO3 ____________ soluble 2. MgCl2 _____________ soluble 3. PbCl2 _______________ insoluble 4. K3PO4 ____________ soluble SOLUBLE OR INSOLUBLE? 5. Ca3(PO4)2 __________ insoluble 6. BaSO4 _____________ insoluble 7. Cu(C2H3O2)2 ___________ soluble 8. PbCrO4 _______________ insoluble WRITING NET IONIC EQUATIONS 1. Pb(NO3)2 + ZnCl2 → Pb+2(aq) + 2 Cl- (aq) → PbCl2(s) CONT 2. CuCl2 + K2CrO4 → Cu+2(aq) + CrO4-2(aq) → CuCrO4(s) CONT. 3. Ba(NO3)2 + Na2SO4 → Ba+2(aq) + SO4-2(aq) → BaSO4(s) CONT. 4. NaOH + CuCl2 → Cu+2(aq) + 2OH- → Cu(OH)2(s) CONT. 5. KNO3 + NaCl → No Reaction (NR)