Molecules and Compounds: Nomenclature Compounds vs. Elements Compound 1: Table Salt Properties: Soluble crystals, stable, edible Elements (Components) • Sodium – shiny, reactive, poisonous • Chlorine – pale yellow gas, reactive, poisonous Compound 2: Table sugar Properties: sweet, soluble crystal Elements (Components) : • Carbon – pencil or diamonds • Hydrogen – flammable gas • Oxygen – a gas in air 2 Law of Constant Composition Pure substances have constant composition all samples of a pure substance contain the same elements in the same percentages (ratios): Water (H: 11%, O: 89%), Table salt (Na: 39%, Cl: 61%), Sugar mixtures have variable composition: Air, Seawater, Concrete, Rocky road ice cream, Coke 3 Why do Compounds Show Constant Composition • the smallest piece of a compound is called a molecule: Water molecule, Sugar molecule • every molecule of a compound has the same number and type of atoms. Water molecule: 2 Hydrogen atom + 1 Oxygen atom; Sugar molecule: 12 Carbon atom + 22 Hydrogen atom + 11 Oxygen atom every sample of the compound will have the same ratio of the elements 4 Chemical Formula Chemical formula: describe the compound by describing the number and type of each atom in the simplest unit of the compound molecules or ions (Table salt: Cl+, Na-) • Element represented by its letter symbol: H instead of hydrogen; Na instead of Sodium • #Atoms of each element: the right of the element as a subscript, H2O (unless if there is only one atom, the 1 subscript is not written) • Polyatomic groups (multiple atoms in group, example: CO3) are placed in parentheses if more than one 5 From Composition to Chemical Formula water = H2O \ two atoms of hydrogen and 1 atom of oxygen table sugar = C12H22O11 \12 atoms of C, 22 atoms of H and 11 atoms O 6 Classifying Pure Substances Element • Atomic: consists of single atoms (Metals, Noble gases) • Molecular: consists of multi-atom molecules (O2, N2, Cl2, etc) Compound • Molecular: consists of molecules made of only nonmetals (CO2, H2O) • Ionic: consists of cations (Na+) and anions (Cl-) 7 Elements and Compounds 8 Classify each of the following: Element atomic/molecular Compound molecular/ionic • • • • • • aluminum, Al = atomic element aluminum chloride, AlCl3 = ionic compound chlorine, Cl2 = molecular element acetone, C3H6O = molecular compound carbon monoxide, CO = molecular compound cobalt, Co = atomic element 9 Molecular Elements Certain elements occur as 2 atom molecules • Rule of 7’s there are 7 common diatomic elements find the element with atomic number 7, N make a figure 7 by going over to Group 7A, then down don’t forget to include H2 VIIA H2 N2 7 O2 F2 Cl2 Br2 I2 10 Molecular Elements = Metal = Metalloid H = Nonmetal N O F Cl Br I Molecular Compounds • two or more nonmetals • smallest unit is a molecule • Common examples: H2O • CO2 (as in soda and dry ice) • NH3 (as in Windex), • Table sugar C11H22O11 12 Ionic Compounds Ions: Metals (Cation Mx+) and Nonmetals (Anion Ny-) • No individual molecules!! • have a 3-dimensional array of cations and anions made of formula units: NaCl, MgO • Na+ Cl- Na+ Cl- Na+ Cl• Cl- Na+ Cl- Na+ Cl- Na+ • Na+ Cl- Na+ Cl- Na+ Cl- 13 Binary Molecular Compounds: Two Nonmetals (such as CO2) 1. Name first element in formula first use the full name of the element 2. Name the second element in the formula with an -ide as if it were an anion, however, remember these compounds do not contain ions! 3. Use a prefix in front of each name to indicate the number of atoms a) Never use the prefix mono- on the first element 14 Subscript - Prefixes • 1 = mono-; not used on first nonmetal • 2 = di• 3 = tri• 4 = tetra- • • • • • 5 = penta6 = hexa7 = hepta8 = octadrop last “a” if name begins with vowel 15 Exceptions when Naming Molecular Compounds of course, water Other common exceptions: • NH3: ammonia (as in Windex) • H2S: hydrogen sulfide • HCl: hydrogen chloride (same for HX, where X = halogen) • CH4: methane (as in natural gas) • H2O2: hydrogen peroxide 16 Example – Naming Binary Molecular BF3 1. Is it one of the common exceptions? H2O, NH3, CH4, C12H22O11 = No! 2. Identify Major Class B = is a nonmetal because it is on the right side of the PT F = is a nonmetal because it is on the right side of the PT \ Molecular 3. Identify the Subclass 2 elements \ Binary Molecular 17 Example – Naming Binary Molecular BF3 4. Name the first element boron 5. Name the second element with an –ide fluorine fluoride 6. Add a prefix to each name to indicate the subscript monoboron, trifluoride 7. Write the first element with prefix, then the second element with prefix Drop prefix mono from first element boron trifluoride 18 Practice: Naming Molecular Compounds • • • • • • • CO ClO3 SO2 P2O5 N2O4 IF7 SF6 19 Key to Naming Molecular Compounds • • • • • • • CO ClO3 SO2 P2O5 N2O4 IF7 SF6 carbon monoxide chlorine trioxide sulfur dioxide diphosphorus pentoxide dinitrogen tetroxide iodine heptoxide sulfur hexafluoride 20 Ionic Compounds • Made of Cation (+) and Anion (-) • Name: Cation Anion example: NaCl Sodium Chloride Cation: Type I metal Type II metal Polyatomic ion: ammonium NH4+ Anion: Nonmetal: Chloride Cl-, Oxide O2Polyatomic ion: SO42- , OH- , NO321 Metal Cations: Type I Type I (Groups IA, IIA, AZA) only have one possible charge Groups IA, IIA, Ag+, Zn2+, Al3+ Charge by position on the Periodic Table IA = +1, IIA = +2, Ag+ (IB), Zn2+(IIB) Al3+(IIIA) How do you know a metal cation is Type II? its not Type I !!! 22 Metal Cations: Type II Type II: Metal ions that are other than Type I Common Examples: Fe2+/3+, Cu+/2+, Cr3+/6+, Mn2+/4+, Mn2+/4+, Pb2+/4+, Sn2+/4+, etc ) have more than one possible charge determine charge by charge on anion How do you know a metal cation is Type II? its not Type I !!! 23 Metal Cations: Type I vs. Type II = Type I Metal = Type II Metal Al Zn Ag Monatomic Nonmetal Anion (An-) • How much is the charge? the position on the Periodic Table • Name of the anion: change ending on the element name to –ide 4A = -4 5A = -3 6A = -2 7A = -1 C4- = carbide N3- = nitride O2- = oxide F- = fluoride Si4- = silicide P3- = phosphide S2- = sulfide Cl- = chloride 25 Net charge of Ionic Compound =0 • Net charge = Positive charge from cation(s) + Negative charge from Anion(s) = 0 • Example: Compound Al2(SO4)3, the Net charge = 2 x (+3) + 3 x (-2) = +6 - 6 = 0 26 Name of Ionic Compounds • Name: Cation Anion: Sodium Chloride Cation: Type I metal = metal name : Na+ => Sodium, Mg2+ => Magnesium Type II metal = metal name(charge): Fe3+ Iron(III), Cu2+ Copper(II) Polyatomic ion = name of polyatomic ion, NH4+ => Ammonium Anion: Nonmetal = stem of nonmetal name + ide, Chloride, Oxide Polyatomic ion = name of polyatomic ion, SO42- => Sulfate, OH- => Hydroxide, NO3- => Nitrate 27 Type I Binary Ionic Compounds Binary: only two kinds of ions in one UNIT Example: MgO, CaCl2 • Metal listed first in formula & name 1. Metal Cation Nonmetal Anion 2. Cation name <= Metal name: Magnesium, Calcium 3. Nonmetal anion <= Nonmetal name ends with –ide: Oxide, Chloride 28 Example – Naming Binary Ionic, Type I Metal CsF 1. Is it one of the common exceptions? H2O, NH3, CH4, C12H22O11 No! 2. Identify Major Class Cs = is a metal because it is on the left side of the PT F = is a nonmetal because it is on the right side of the PT Ionic 3. Identify the Subclass 2 elements, \ Binary Ionic 4. Is the metal Type I or Type II Cs is in Group IA, \ Type I 29 Example – Naming Binary Ionic, Type I Metal CsF 5. Identify cation and anion Cs = Cs+ because it is Group 1 F = F- because it is Group 7 6. Name the cation Cs+ = cesium 7. Name the anion F- = fluoride 8. Full name: Cation name first, Anion name last cesium fluoride 30 Type II Binary Ionic Compounds Metal listed first in formula & name 1. Metal cation Nonmetal anion 2. metal cation Metal(Roman Numeral): to indicate its charge. Iron(II), Copper(I) determine charge from anion charge Common Type II cations in Table 5.5 3. Nonmetal anion Nonmetal name ended with –ide: Chloride, Oxide Example: Iron(II) chloride, Copper(I) oxide 31 How to find the charge on Type II metal ions? • Example: Name Compound Fe2(SO4)3 Since the sum of all charges equals zero, the charge on iron ions are unknown and sulfate each has –2 charge, then we have 2 x Fe + 3 x (-2) = 0 Fe = +3, each iron ion has a charge of +3 Name: iron(III) sulfate Key: knowing the charge on ANIONs! 32 Example – Naming Binary Ionic, Type II Metal CuCl 1. Is it one of the common exceptions? H2O, NH3, CH4, C12H22O11 = No! 2. Identify Major Class Cu = is a metal because it is on the left side of the PT Cl = is a nonmetal because it is on the right side of the PT \ Ionic 3. Identify the Subclass 2 elements, \ Binary Ionic 4. Is the metal Type I or Type II Cu is not in Group IA, IIA, or (Al, Ga, In) \ Type II 33 Example – Naming Binary Ionic, Type II Metal CuCl 5. Identify cation and anion Cl = Cl- because it is Group 7 Cu = Cu+ to balance the charge 6. Name the cation Cu+ = copper(I) 7. Name the anion Cl- = chloride 8. Write the cation name first, then the anion name copper(I) chloride 34 Practice: Naming Ionic compounds • • • • • • • HgF2 CuI2 CaCl2 Fe2O3 SnCl4 Mg3N2 Ag2S 35 Naming Ionic compounds Hints: find type II ion charge from anion • • • • • • • HgF2 : Two F- = -2 Hg = +2 CuI2 : Two I- = -2Cu -2 = +2 CaCl2 : both fixed charges Fe2O3 : Three O2- = -6 Fe = +3 SnBr4 : Four Br- = -4 Sn = +4 Mg3N2 : both fixed charges Ag2S : both fixed charges 36 Answer key: names of ionic compounds • • • • • • • HgF2 = Mercury(II) fluoride CuI2 = copper(II) iodide CaCl2 = calcium chloride Fe2O3 = Iron(III) oxide SnBr4 = tin(IV) bromide Mg3N2 = magnesium nitride Ag2S = silver sulfide 37 Polyatomic Ions symbol of the polyatomic ion called nitrate symbol of the polyatomic ion called sulfate Mg(NO3)2 CaSO4 compound called magnesium nitrate compound called calcium sulfate implied “1” subscript on magnesium parentheses to group two NO3’s implied “1” subscript on calcium no parentheses for one SO4 38 Polyatomic Ions: Nitrate NO3-, Sulfate SO42subscript indicating two NO3 groups no subscript indicating one SO4 group Mg(NO3)2 CaSO4 compound called magnesium nitrate compound called calcium sulfate implied “1” subscript on nitrogen, total 2 N stated “3” subscript on oxygen, total 6 O implied “1” subscript on sulfur, total 1 S stated “4” subscript on oxygen, total 4 O 39 Polyatomic Anions: -ATE ions CO32- NO3- carbonate nitrate SiO32- PO43- SO42- ClO3- silicate phosphate sulfate chlorate AsO43- SeO42- BrO3- arsenate selenate bromate IO3iodate 40 Periodic Pattern of Polyatomic Ions -ate groups IIIA 3BO3 IVA VA VIA VIIA 2CO3 NO3 2SiO3 3PO4 2SO4 ClO3 3AsO4 2SeO4 BrO3 2TeO 4 IO3 41 Patterns for Polyatomic Ions 1. elements in the same Group form similar polyatomic ions same number of O’s and same charge ClO3- = chlorate (-1 charge) BrO3- = bromate (-1 charge) 2. if the polyatomic ion starts with H, the name adds hydrogen- prefix before name and add 1 to the charge CO32- = carbonate \ HCO3-1 = hydrogen carbonate 42 Patterns for Polyatomic Ions -ate ion chlorate = ClO3- • -ate ion + 1 O same charge, per- prefix perchlorate = ClO4- • -ate ion – 1 O same charge, -ite suffix chlorite = ClO2- • -ate ion – 2 O same charge, hypo- prefix, -ite suffix hypochlorite = ClO43 Polyatomic Anions: -ite, hypo- -ite, (-ate), per- -ate ClOhypochlorite NO2- PO33- SO32- ClO2- nitrite phosphite sulfite chlorite NO3- PO43- SO42- ClO3- nitrate phosphate sulfate chlorate ClO4perchlorate44 -ATE/-ITE ions in Our Lives ClO(bleach) NO2- PO33- SO32- ClO2- (preserve meat) (plant medicine) (wine, oxygen buster) (bleach, disinfect) NO3- PO43- SO42- ClO3- (plaster, car battery, sea salt) (older pyrotechnics) (fertilizer, explosives) (bone/teeth, fertilizer, soda) ClO4(pyrotechnics, solid fuel rocket) 45 Polyatomic Ions to Remember Name Formula Name Formula acetate C2H3O2– hypochlorite ClO– carbonate CO32– chlorite ClO2– chlorate ClO3– perchlorate ClO4– sulfate SO42– HSO4– hydrogen carbonate (aka Bicarbonate) HCO3 hydroxide OH– nitrate NO3– nitrite NO2– Hydrogen sulfate (aka Bisulfate) permanganate MnO4– sulfite SO32– chromate CrO42– Hydrogen sulfite (aka Bisulfite) HSO3– cyanide CN– dichromate Cr2O7 ammonium NH4+ – 2– 46 Other Polyatomic Ions in Our Lives C2H3O2– In vinegar as acetic acid CO32– Soda drink HCO3– Baking soda, baking power, acid spill neutralizer OH– In liquid plumber/Drano as NaOH MnO4– Disinfectant, “aging” for movie making CrO42– Chrome plating (faucet, etc.) CN– Highly Poisonous; Plant seeds; blue pigment NH4+ Fertilizer; metabolic waste from animals 47 Other Polyatomic Ions in Our Lives ClO(bleach) NO2- PO33- SO32- ClO2- (preserve meat) (plant medicine) (wine, oxygen buster) (bleach, disinfect) NO3- PO43- SO42- ClO3- (plaster, car battery, sea salt) (older pyrotechnics) (fertilizer, explosives) (bone/teeth, fertilizer, soda) ClO4(pyrotechnics, solid fuel rocket) 48 Compounds Containing Polyatomic Ions • • • • Type I metal + Polyatomic ion: NaNO3 Type II metal(charge) + Polyatomic ion : CuSO4 Polyatomic cation + Nonmetal ion (-ide): NH4Cl Polyatomic cation + Polyatomic ion: (NH4)2SO4 Important!: If, and only if, more than ONE polyatomic ions are present in a formula, use parenthesis and subscript to indicate the number of polyatomic ions 49 Example – Naming Ionic with Polyatomic Ion Na2SO4 1. Is it one of the common exceptions? H2O, NH3, CH4, C12H22O11 = No! 2. Identify Major Class Na = is a metal because it is on the left side of the PT SO4 = is a polyatomic ion \ Ionic 3. Identify the Subclass compound has 3 elements \ Ionic with Polyatomic Ion 4. Is the metal Type I or Type II Na is in Group IA, \ Type I 50 Example – Naming Ionic with Polyatomic Ion Na2SO4 5. Identify the ions Na = Na+ because in Group 1 SO4 = SO42- a polyatomic ion 6. Name the cation Na+ = sodium (Type I) 7. Name the anion SO42- = sulfate 8. Write the name of the cation followed by the name of the anion sodium sulfate 51 Example – Naming Ionic with Polyatomic Ion Fe(NO3)3 1. Is it one of the common exceptions? H2O, NH3, CH4, C12H22O11 = No! 2. Identify Major Class Fe = is a metal because it is on the left side of the PT NO3 = is a polyatomic ion because it is in ( ) \ Ionic 3. Identify the Subclass there are 3 elements \ Ionic with Polyatomic Ion 4. Is the metal Type I or Type II Fe is not in Group IA, IIA, or (Al, Ga, In) \ Type II 52 Example – Naming Ionic with Polyatomic Ion Fe(NO3)3 5. Identify the ions NO3 = NO3- a polyatomic ion Fe = Fe+3 to balance the charge of the 3 NO3-1 6. Name the cation Fe+3 = iron(III) (Type II) 7. Name the anion NO3- = nitrate 8. Write the name of the cation followed by the name of the anion iron(III) nitrate 53 Practice: Naming Ionic compounds • • • • • • • Hg2SO4 CuClO3 Zn(NO3)2 FeCO3 Sn(SO3)2 CoPO4 Al(ClO4)3 54 Hints: Naming Ionic compounds • • • • • • • Hg2SO4 : charge of sulfate = -1 CuClO3 : charge of chlorate = -1 Zn(NO3)2 charge of nitrate = -1 FeCO3 : charge of carbonate = -2 Sn(SO3)2: charge of sulfite = -1 CoPO4 : charge of phosphate = -3 Al(ClO4)3 : charge of perchlorate = -1 55 Keys: Naming Ionic compounds • • • • • • • Hg2SO4 : mercury(I) sulfate CuClO3 : copper(I) chlorate Zn(NO3)2 zinc nitrate FeCO3 : iron(II) carbonate Sn(SO3)2: tin(IV) sulfite CoPO4 : cobalt(III) phophate Al(ClO4)3 : aluminum perchlorate 56 Acids • Contain H+ cation and anion • Hydrogen (H) as first element in formula • Binary acids (HnX) have H+ cation and nonmetal anion • Oxyacids (HnXOm) have H+ cation and polyatomic anion 57 Naming Acids All names have acid at end • Binary Acids (HnX) = hydro prefix + stem of the name of the nonmetal + ic suffix Example: HCl (Hydrochloric acid) • Oxyacids (HnXOm : H2CO3 , H2SO4) if polyatomic ion ends in –ate = name of polyatomic ion with –ic suffix : H2SO4 (Sulfuric acid); H2CO3 (Carbonic acid); HNO3 (Nitric acid); H3PO4 (Phosphoric acid) if polyatomic ion ends in –ite = name of polyatomic ion with –ous suffix 58 Naming Binary Acids – HF 1. First of all, it is binary acid HX 2. Identify the anion F F-, fluoride because Group 7A 2. Name the anion with an –ic suffix F- = fluoride fluoric 3. Add a hydro- prefix to the anion name hydrofluoric 4. Add the word acid to the end hydrofluoric acid 59 Naming Oxyacids: H2SO4 1. Identify the anion SO4 = SO42- = sulfate 2. If the anion has –ate suffix, change it to –ic. If the anion has –ite suffix, change it to -ous SO42- = sulfate sulfuric 3. Write the name of the anion followed by the word acid sulfuric acid (kind of an exception, to make it sound nicer!) 60 Practice: Naming Acids first: what is the anion? • • • • • • • HNO3 HClO3 HBr H2CO3 H2SO3 H3PO4 HClO4 nitrate chlorate bromide carbonate sulfite phosphate perchlorate 61 Practice: Naming Acids • • • • • • • HNO3 nitrate nitric acid HClO3 chlorate chloric acid HBr bromide hydrobromic acid H2CO3 carbonate carbonic acid H2SO3 sulfite sulfurous acid H3PO4 phosphate phosphoric acid HClO4 perchlorate perchloric acid 62 Formula-to-Name Flow Chart 63 Review: Naming Compounds • • • • • • • • CuSO3 AgClO N2O5 H2S FeI2 Sn(NO3)4 Ba3(PO4)2 (NH4)2S 1. Common exceptions? H2O, NH3, CH4, C12H22O11 2. Identify as Molecular or Ionic? 3. Identify • • Binary molecular Type I or II metal ion 64 Review: Naming Compounds • • • • • • • • CuSO3 AgClO N2O5 H2S FeI2 Sn(NO3)4 Ba3(PO4)2 (NH4)2S copper(II) sulfite silver hypochlorite dinitrogen pentoxide hydrosulfuric acid iron(II) iodide tin(IV) nitrate barium phosphate ammonium sulfide 65 Write Chemical Formula using the charge of known ions • Example: Compound between Ca2+ and PO43- , the number of ions of each needs to be 3 and 2, so that the combined charge = 3 x (+2) + 2 x (-3) = 0 Therefore the formula for the compound is Ca3(PO4)2 66 Write Chemical Formula using the charge of known ions “Criss-Cross-Simplify”: • The charge of an ion turns into the subscript (the number) of the counterpart ion Pb4+ O2- Pb2O4 • Since the subscripts in an ionic compound represents the RATIO among the ions, the subscripts need to be simplified when there is common denominator Pb2O4 PbO2 67 Practice: Writing formulas (I) • • • • • • • copper(II) chloride aluminum oxide magnesium phosphide iron(II) bromide lead(II) sulfide zinc iodide sodium nitride 68 Hints for Writing formulas (I): Charges on Cations and Anions • • • • • • • copper(II) chloride: Cu2+ and Claluminum oxide: Al3+ and O2magnesium phosphide : Mg2+ and P3iron(II) bromide : Fe2+ and Brlead(II) sulfide : Pb2+ and S2zinc iodide : Zn2+ and Isodium nitride : Na+ and N369 Key for Writing formulas (I): use criss-cross-reduce • • • • • • • copper(II) chloride aluminum oxide magnesium phosphide iron(II) bromide lead(II) sulfide zinc iodide sodium nitride CuCl2 Al2O3 Mg3P2 FeBr2 FeS ZnI2 Na3N 70 Practice: Write Chemical Formulae • • • • • • • Chromium(II) Chloride Cesium phosphate Lead(II) oxide Zinc nitrate Iron(III) sulfite Strontium nitride Ammonium carbonate 71 Key: Write Chemical Formulae • • • • • • • Chromium(II) Chloride Cesium phosphate Lead(II) oxide Zinc nitrate Iron(III) sulfite Strontium nitride Ammonium carbonate CrCl2 Cs3PO4 PbO Zn(NO3)2 Fe3(SO3)2 Sr3N2 (NH4)2CO3 72 Practice: Writing formulas (I) • • • • • • • • copper(I) sulfate aluminum chlorate magnesium phosphate iron(II) carbonate lead(II) acetate zinc sulfite sodium nitrite Nitrogen gas 73 Hints for Writing formulas (I): Charges on Anions • • • • • • • • copper(I) sulfate: -2 for sulfate aluminum chlorate: -1 for chlorate magnesium phosphate: -3 for phosphate iron(II) carbonate : -2 for carbonate lead(II) acetate: -1 for acetate zinc sulfite : -2 for sulfite sodium nitrite: -1 for nitrite Nitrogen gas: atomic or molecular element? 74 Key: Writing formulas (I) • • • • • • • • copper(I) sulfate: Cu2SO4 aluminum chlorate: Al(ClO3)3 magnesium phosphate: Mg3(PO4)2 iron(II) carbonate : FeCO3 lead(II) acetate: Pb(C2H3O2)2 zinc sulfite : ZnSO3 sodium nitrite: NaNO2 Nitrogen gas: N2 75 More on Writing formulae • • • • • • • • copper(II) sulfate aluminum perchlorate hydroiodic acid iron(III) bromide Diphosphorus pentoxide lead(IV) nitride zinc carbonate helium gas 76 Key: Writing formulae • • • • • • • • • copper(II) sulfate CuSO4 aluminum perchlorate Al(ClO4)3 hydroiodic acid HI iron(III) bromide FeBr3 Diphosphorus pentoxide P2O5 lead(IV) nitride Pb3N4 zinc carbonate ZnCO3 ammonium nitrite NH4NO2 helium gas He 77