STOICHIOMETRY CHEMISTRY MS. MATTSON STOICHIOMETRY • Stoichiometry • the mole-mass relationship between reactants and products. • Molecular Mass • measured in atomic mass units (a.m.u.) • Review: Calculate the molecular mass of chloroethane C2H5Cl. • 64.5 a.m.u. STOICHIOMETRY • Mole • A unit that refers to the number of molecules or ions that take part in a chemical reaction. • Molar Mass • One mole is equal to the molecular mass in grams. • Ex: C2H5Cl = 64.5 a.m.u. = 1 mole = 64.5 grams • Potassium (K) has molecular mass 39.1 a.m.u. • What is 1 mole of potassium in grams? • 39.1 grams STOICHIOMETRY • Molecular Mass (a.m.u.) = Molar Mass (g) = 1 mole • Activity 1 • Given molecule A in grams show the equation that would convert grams of A to moles of A. • Given the moles of molecule B show the equation that would convert moles of B to grams of B. STOICHIOMETRY • Problem 1 • Convert 15.0 grams of C2H4 to moles of C2H4. • 0.536 moles • Convert 0.536 moles of HCl to grams of HCl. • 19.6 grams STOICHIOMETRY • Molecular Mass (a.m.u.) = Molar Mass (g) = 1 mole • Activity 2 • Given the reaction 2A + 3B A2B + B2 show the equation that would convert the grams of A into the grams of B that are required to fulfill the reaction. • Grams to moles to moles to grams! STOICHIOMETRY • Problem 2 • Sodium hypochlorite (NaOCl) is best known as household bleach. It is prepared by reacting sodium hydroxide (NaOH) with chlorine Cl2: 2NaOH + Cl2 NaOCl + NaCl + H2O • How many grams of NaOH are needed to react with 25.0 g of Cl2? • 28.2 g NaOH STOICHIOMETRY • Problem 3 • Aspirin is prepared by a reaction of salicylic acid (C7H6O3) with acetic anhydride (C4H6O3) according to the following equation: C7H6O3 + C4H6O3 C9H8O4 + CH3COOH Salicylic acid Acetic anhydride Aspirin 138.1 g 102.1 g 180.2 g • How many grams of acetic anhydride are needed to react with 4.50 g of salicylic acid? • 3.33 g C7H6O3 • How many grams of aspirin will result? • 5.87 g C9H8O4 STOICHIOMETRY • Problem 4 • In preparation of iron from hematite Fe2O3 reacts with carbon: Fe2O3 + C Fe + CO2 How many grams of carbon are needed to react with 525 g of hematite? 59.2 g C STOICHIOMETRY • Problem 5 Magnesium metal burns in oxygen to form magnesium oxide, MgO2. Write and balance an equation for this reaction. 2Mg + O2 2MgO2 How many grams of Mg(MM 24.3g) are needed to react with 25.0 g of O2 (MM 32.0g)? 38.0g Mg How many grams of MgO2 (MM 40.3) will result? 63.0 g MgO2 How many grams of O2 are needed to react with 25.0 g of Mg? 16.5 g O2 How many grams of MgO2 will result? 41.5 g MgO2