Sheet 5 HEAT TREATMENT OF METALS 1. "Steel is made hard by quenching." List at least three requirements that must be met to justify this statement. 2. Using the Fe-C phase diagram (figure 1) and the isothermal transformation diagram for 1080 steel (figure 2), give the microstructure present in a thin strip of the 1080 steel after each step of the following heat treatments: (a) 800˚C for 1 hour Quench into lead at 700˚C, hold for 15 minutes. Quench into lead at 500˚C, hold for 1 minute. Water quench. (b) 700˚C for 6 hours and water quench. (c) 800˚C for 1 hour, quench into molten salt at 260˚C, hold for 1 minute, and then air cool. (d) 800˚C for 1 hour and water quench. Why would treatment (c) give better mechanical properties than treatment (d)? 3. Match the suitable heat treatment procedures with the alloys given below and briefly explain the purposes of each procedure: Alloys Heat Treatment 1020 1050 1080 A96061 G3500 homogenisation anneal normalising full anneal quenching and tempering ageing 4. Why is it preferable to precipitation-harden alloys by first quenching to a low temperature and then reheating to the ageing temperature rather than quenching directly to the ageing temperature? 5. Can low carbon steels be age-hardened? Can low carbon steels be quench hardened? How are low carbon steels strengthened? 1 Figure 1: Fe - Fe3C Phase Diagram Figure 2: Isothermal Transformation diagram for a 1080 steel 6: The kinetics of the austenite-to-pearlite transformation obey the Avrami relationship. Using the fraction transformed–time data given here, determine the total time required for 95% of the austenite to transform to pearlite: 7: Using the isothermal transformation diagram for a 1.13 wt% C steel alloy, determine the final microstructure (in terms of just the microconstituents present) of a small specimen that has been subjected to the following time–temperature treatments. In each case assume that the specimen begins at 920 oC and that it has been held at this temperature long enough to have achieved a complete and homogeneous austenitic structure. (a) Rapidly cool to 250 oC, hold for 103 s, then quench to room temperature. (b) Rapidly cool to 775 oC, hold for 500 s, then quench to room temperature. (c) Rapidly cool to 400 oC, hold for 500 s, then quench to room temperature. (d) Rapidly cool to 700 oC, hold at this temperature for 105 s, then quench to room temperature. 2 8: The Figure shows the continuous cooling transformation diagram for a 0.35 wt% C iron–carbon alloy. Make a copy of this figure and then sketch and label continuous cooling curves to yield the following microstructures: (a) Fine pearlite and proeutectoid ferrite (b) Martensite (c) Martensite and proeutectoid ferrite (d) Coarse pearlite and proeutectoid ferrite (e) Martensite, fine pearlite, and proeutectoid ferrite 9: Copper-rich copper–beryllium alloys are precipitation hardenable. After consulting the portion of the phase diagram, do the following: (a) Specify the range of compositions over which these alloys may be precipitation hardened. (b) Briefly describe the heat-treatment procedures (in terms of temperatures) that would be used to precipitation harden an alloy having a composition of your choosing, yet lying within the range given for part (a). 3 10: Rank the following iron–carbon alloys and associated microstructures from the hardest to the softest: (a) 0.25 wt% C with coarse pearlite, (b) 0.80 wt% C with spheroidite, (c) 0.25 wt% C with spheroidite, and (d) 0.80 wt% C with fine pearlite. Justify this ranking. 11: For a eutectoid steel, describe isothermal heat treatments that would be required to yield specimens having the following Brinell hardnesses: (a) 180 HB, (b) 220 HB, and (c) 500 HB. 4